Citation: MA Lili, JIA Li, ZHOU Xinran, LIU Yan, FAN Xiaojing, PAN Canping. Analysis of aldicarb and its metabolites in ginger using ultra performance liquid chromatography-tandem mass spectrometry coupled with multiplug filtration clean up with multiwalled carbon nanotubes[J]. Chinese Journal of Chromatography, ;2014, 32(6): 635-639. doi: 10.3724/SP.J.1123.2014.02016 shu

Analysis of aldicarb and its metabolites in ginger using ultra performance liquid chromatography-tandem mass spectrometry coupled with multiplug filtration clean up with multiwalled carbon nanotubes

MA Lili ¹ ,
JIA Li ¹ ,
ZHOU Xinran ¹ ,
LIU Yan ^1,, ,
FAN Xiaojing ¹ ,
PAN Canping ²

1.
1. Beijing Center for Physical and Chemical Analysis, Beijing Engineering Research Center of Food Safety Analysis, Beijing 100089, China;

Corresponding author: LIU Yan,
Received Date: 17 February 2014
Available Online: 17 April 2014
Fund Project: 北京市财政资金项目(PXM2013_178305_000004,PXM2013_178305_000005,PXM2013_178305_000009). (PXM2013_178305_000004,PXM2013_178305_000005,PXM2013_178305_000009)

A simple and rapid pretreatment procedure was developed for the simultaneous determination of aldicarb and its metabolites, aldicarb sulfone and aldicarb sulfoxide, in ginger. The samples were extracted with acetonitrile, and then cleaned up with multiplug filtration using multiwalled carbon nanotubes (MWCNTS). The eluate was dried with nitrogen gas at room temperature, and redissolved in an acetonitrile-water (5:95, v/v) mixture, then quantified by ultra performance liquid chromatography coupled with electrospray ionization tandem mass spectrometry (UPLC-ESI-MS/MS) operated in positive multiple reaction monitoring (MRM) mode. A linear relationship was achieved in the range of 0.5-200 μg/L for the peak areas to the mass concentrations of the target compounds with the linear correlation coefficients (r²) higher than 0.99. The recoveries at three spiked levels of 2, 20 and 200 μg/kg were in the range from 71.4% to 89.8% with the relative standard deviations (RSDs, n=6) from 0.7% to 13.2% under the selected conditions. The limits of quantification (LOQ, S/N=10) of aldicarb, aldicarb sulfone, and aldicarb sulfoxide in ginger were 1.0, 2.0 and 1.0 μg/kg, respectively. The results demonstrate that the developed method is rapid, cost-effective, and can meet the requirements of the multiple pesticide residue analysis. The method is applicable to determine aldicarb and its metabolites in ginger.
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