Citation: ZHAO Yan, XU Dongyu, LIN Haoxue, CHEN Xiaoyan, CHEN Zeyong. Determination of three ester compounds in gasoline by two-dimensional gas chromatography[J]. Chinese Journal of Chromatography, ;2014, 32(6): 662-665. doi: 10.3724/SP.J.1123.2014.01045 shu

Determination of three ester compounds in gasoline by two-dimensional gas chromatography

1.
Shenzhen Academy of Metrology and Quality Inspection, Shenzhen 518131, China

Corresponding author: XU Dongyu,
Received Date: 27 January 2014
Available Online: 8 April 2014
Fund Project: 国家标准编制计划项目(20131689-T-469). (20131689-T-469)

A simple and efficient method based on the technique of packed column switching-back flushing was established for the analysis of the ester compounds (including ethyl acetate, sec-butyl acetate, dimethyl carbonate) in gasoline. With the use of a non-polar pre-column, we successfully separated the components in gasoline by back flushing out components heavier than n-octane, while the lighter components and the ester compounds were flushed into a polar analytical column. In this method, external standard method was applied for quantification. As a result, good linear relationships existed among the three ester compounds in the range of 50 mg/L to 50000 mg/L. The linear correlation coefficients (r²) for ethyl acetate, sec-butyl acetate and dimethyl carbonate were 0.99999, 1.00000 and 0.99995, respectively. The relative standard deviations (RSDs) of standard samples in six continuous tests were within 1.0%. The recoveries were between 98.7% and 107.9%. The detection limit of the method (S/N=3) was 5 mg/L. No pretreatment was needed. This method is simple, accurate, quick as well as efficient, and can be used as an ideal method for the analysis of the ester compounds in gasoline.
- two-dimensional gas chromatography,
- ethyl acetate,
- sec-butyl acetate,
- dimethyl carbonate,
- gasoline
1. [1]
  [1] Chen X Y. China Petroleum and Chemical Industry Standards and Quality (陈先银. 中国石油和化工标准与质量), 2013(12): 261
2. [2]
  [2] Yao H J, Yang Y Q, Chang X L, et al. Materials Review (姚海军, 杨永青, 常新林, 等. 材料导报), 2009, 23(14): 442
3. [3]
  [3] SH/T 0663-1998
4. [4]
  [4] Wang G L, Li C H, Pei X D, et al. Petroleum Processing and Petrochemical (王国良, 李朝恒, 裴旭东, 等. 石油炼制与化工), 2003, 34(9): 40
5. [5]
  [5] Zhang Z Z, Yang X H, Wang C M, et al. Shandong Chemical Industry (张在忠, 杨晓宏, 王春梅, 等. 山东化工), 2009, 38(11): 37
6. [6]
  [6] Gu T, Yu H M, Tian S B. Petrochemical Technology & Application (谷涛, 于海明, 田松柏. 石化技术与应用), 2005, 23(1): 5
7. [7]
  [7] Dong J. Shandong Chemical Industry (董君. 山东化工), 2013, 42(5): 63
8. [8]
  [8] Lu W Z, Long Y C, Li J, et al. Acta Petrolei Sinica: Petroleum Processing Section (陆婉珍, 龙义成, 黎洁, 等. 石油学报:石油加工), 1997, 13(3): 40
9. [9]
  [9] Gao Z R, Li J W, Wang C. Petrochemical Technology (高枝荣, 李继文, 王川. 石油化工), 2013, 42(2): 230
10. [10]
  [10] Zhang X M, Zhang L H, Zhang Y K. Chinese Journal of Chromatography (张祥民, 张丽华, 张玉奎. 色谱), 2012, 30(3): 222
11. [11]
  [11] Li L, Wu C M, Chen J H, et al. Chinese Journal of Chromatography (李亮, 吴春梅, 陈健航, 等. 色谱), 2010, 28(7): 724
12. [12]
  [12] Li J W, Li W, Wang C. Chinese Journal of Chromatography (李继文, 李薇, 王川. 色谱), 2013, 31(11): 1134
13. [13]
  [13] SH/T 0713-2002
14. [14]
  [14] Wang H W, Miao H, Zhu D Q, et al. Chinese Journal of Chromatography (王涵文, 苗虹, 朱道乾, 等. 色谱), 2002, 20(3): 207
15. [15]
  [15] Xu G W, Shi X Z. Chinese Journal of Chromatography (许国旺, 石先哲. 色谱), 2011, 29(2): 97
16. [16]
  [16] Wang H W, Miao H, Guan Y F, et al. Chinese Journal of Analytical Chemistry (王涵文, 苗虹, 关亚风, 等. 分析化学), 2002, 30(8): 1012
1. [1]
  Shuying Zhu , Shuting Wu , Ou Zheng . Improvement and Expansion of the Experiment for Determining the Rate Constant of the Saponification Reaction of Ethyl Acetate. University Chemistry, 2024, 39(4): 107-113. doi: 10.3866/PKU.DXHX202310117
2. [2]
  Ruitong Zhang , Zhiqiang Zeng , Xiaoguang Zhang . Improvement of Ethyl Acetate Saponification Reaction and Iodine Clock Reaction Experiments. University Chemistry, 2024, 39(8): 197-203. doi: 10.3866/PKU.DXHX202312004
3. [3]
  Jiaojiao Yu , Bo Sun , Na Li , Cong Wen , Wei Li . Improvement of Classical Organic Experiment Based on the “Reverse-Step Optimization Method”: Taking Synthesis of Ethyl Acetate as an Example. University Chemistry, 2025, 40(3): 333-341. doi: 10.12461/PKU.DXHX202405177
4. [4]
  Yukun Chang , Haoqin Huang , Baolei Wang . Preparation of Trans-Cinnamic Acid via “One-Pot” Protocol of Aldol Condensation-Hydrolysis Reaction: Recommending an Improved Organic Synthesis Experiment. University Chemistry, 2024, 39(4): 322-328. doi: 10.3866/PKU.DXHX202309095
5. [5]
  Haofan Niu , Yuhan Wu , Xinran Li , Longmei Li , Dong Wang , Yongce Zhang , Fengyu Liu , Wei Bai . 自驱动固体酸催化乙酸苄酯的合成. University Chemistry, 2026, 41(1): 1-8. doi: 10.12461/PKU.DXHX202505049
6. [6]
  Jiayi Yang , Jianxiu Hao , Huacong Zhou , Quansheng Liu . “Gorgeous Transformation” of Carbon Dioxide into Cyclic Carbonates: Catalyst Types and Roles. University Chemistry, 2026, 41(2): 178-189. doi: 10.12461/PKU.DXHX202502105
7. [7]
  Shiyi Chen , Jialong Fu , Jianping Qiu , Guoju Chang , Shiyou Hao . Waste medical mask-derived carbon quantum dots enhance the photocatalytic degradation of polyethylene terephthalate (PET) over BiOBr/g-C₃N₄ S-scheme heterojunction. Acta Physico-Chimica Sinica, 2026, 42(1): 100135-0. doi: 10.1016/j.actphy.2025.100135
8. [8]
  Ling Liu , Haibin Wang , Genrong Qiang . Curriculum Ideological and Political Design for the Comprehensive Preparation Experiment of Ethyl Benzoate Synthesized from Benzyl Alcohol. University Chemistry, 2024, 39(2): 94-98. doi: 10.3866/PKU.DXHX202304080
9. [9]
  Xiaofei Liu , He Wang , Li Tao , Weimin Ren , Xiaobing Lu , Wenzhen Zhang . Electrocarboxylation of Benzylic Phosphates and Phosphinates with Carbon Dioxide. Acta Physico-Chimica Sinica, 2024, 40(9): 2307008-0. doi: 10.3866/PKU.WHXB202307008
10. [10]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, 2024, 40(4): 2307004-0. doi: 10.3866/PKU.WHXB202307004
11. [11]
  Zixuan Zhao , Miao Fan . “Carbon” with No “Ester”: A Boundless Journey of CO₂ Transformation. University Chemistry, 2025, 40(7): 213-217. doi: 10.12461/PKU.DXHX202409040
12. [12]
  Jinghua Wang , Yanxin Yu , Yanbiao Ren , Yesheng Wang . Integration of Science and Education: Investigation of Tributyl Citrate Synthesis under the Promotion of Hydrate Molten Salts for Research and Innovation Training. University Chemistry, 2024, 39(11): 232-240. doi: 10.3866/PKU.DXHX202402057
13. [13]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
14. [14]
  Xiuyun Wang , Jiashuo Cheng , Yiming Wang , Haoyu Wu , Yan Su , Yuzhuo Gao , Xiaoyu Liu , Mingyu Zhao , Chunyan Wang , Miao Cui , Wenfeng Jiang . Improvement of Sodium Ferric Ethylenediaminetetraacetate (NaFeEDTA) Iron Supplement Preparation Experiment. University Chemistry, 2024, 39(2): 340-346. doi: 10.3866/PKU.DXHX202308067
15. [15]
  Lirui Shen , Kun Liu , Ying Yang , Dongwan Li , Wengui Chang . Synthesis and Application of Decanedioic Acid-N-Hydroxysuccinimide Ester: Exploration of Teaching Reform in Comprehensive Applied Chemistry Experiment. University Chemistry, 2024, 39(8): 212-220. doi: 10.3866/PKU.DXHX202312035
16. [16]
  Binbin Liu , Yang Chen , Tianci Jia , Chen Chen , Zhanghao Wu , Yuhui Liu , Yuhang Zhai , Tianshu Ma , Changlei Wang . Hydroxyl-functionalized molecular engineering mitigates 2D phase barriers for efficient wide-bandgap and all-perovskite tandem solar cells. Acta Physico-Chimica Sinica, 2026, 42(1): 100128-0. doi: 10.1016/j.actphy.2025.100128
17. [17]
  Yu Peng , Jiawei Chen , Yue Yin , Yongjie Cao , Mochou Liao , Congxiao Wang , Xiaoli Dong , Yongyao Xia . Tailored cathode electrolyte interphase via ethylene carbonate-free electrolytes enabling stable and wide-temperature operation of high-voltage LiCoO₂. Acta Physico-Chimica Sinica, 2025, 41(8): 100087-0. doi: 10.1016/j.actphy.2025.100087
18. [18]
  Yajin Li , Huimin Liu , Lan Ma , Jiaxiong Liu , Dehua He . Photothermal Synthesis of Glycerol Carbonate via Glycerol Carbonylation with CO₂ over Au/Co₃O₄-ZnO Catalyst. Acta Physico-Chimica Sinica, 2024, 40(9): 2308005-0. doi: 10.3866/PKU.WHXB202308005
19. [19]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
20. [20]
  Huanhuan XIE , Yingnan SONG , Lei LI . Two-dimensional single-layer BiOI nanosheets: Lattice thermal conductivity and phonon transport mechanism. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 702-708. doi: 10.11862/CJIC.20240281

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(497)
HTML views(52)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142