Citation: ZHANG Ming, TANG Fangliang, YU Yayun, CHEN Feng, XU Jianfen, YE Yonggen. Simultaneous determination of sixteen perfluorinated organic compounds in surface water by solid phase extraction and ultra performance liquid chromatography with electrospray ionization tandem mass spectrometry[J]. Chinese Journal of Chromatography, ;2014, 32(5): 472-476. doi: 10.3724/SP.J.1123.2014.01042 shu

Simultaneous determination of sixteen perfluorinated organic compounds in surface water by solid phase extraction and ultra performance liquid chromatography with electrospray ionization tandem mass spectrometry

1.
Hangzhou Environmental Monitoring Central Station, Hangzhou 310007, China

Corresponding author: TANG Fangliang,
Received Date: 24 January 2014
Available Online: 27 March 2014
Fund Project: 杭州市社会发展科研攻关项目(20130533B02) (20130533B02)杭州市环境保护科技项目(2013HZHB002). (2013HZHB002)

A high-throughput detection method has been developed for the determination of sixteen perfluorinated organic compounds (PFCs) in surface water by solid phase extraction-ultra performance liquid chromatography coupled with electrospray ionization tandem mass spectrometry (SPE-UPLC-ESI-MS/MS). The water samples were concentrated and purified through WAX solid phase extraction cartridges. The UPLC separation was performed on an ACQUITY UPLC^TM BEH C₁₈ column utilizing a gradient elution program of methanol (containing 2 mmol/L ammonium acetate) and water (containing 2 mmol/L ammonium acetate) as the mobile phases at a flow rate of 0.4 mL/min. The MS/MS detection was performed under negative electrospray ionization (ESI^-) in multiple reaction monitoring (MRM) mode. Good linearities were observed in the range of 0.5-100 μg/L or 1.0-100 μg/L with correlation coefficients from 0.9987 to 0.9999. The limits of detection (LODs) for the sixteen perfluorinated organic compounds were in the range of 0.06-0.46 ng/L. The recoveries ranged from 67.6% to 103% with the relative standard deviations between 2.94% and 12.0%. This method was characterized by high sensitivity and precision, extensive range and high speed, and can be applied for the analysis of PFC contaminants in surface water.
1. [1]
  [1] Paul A G, Jones K C, Sweetman A J. Environ Sci Technol, 2009, 43(2): 386
2. [2]
  [2] Ahrens L, Shoeib M, Harner T, et al. Environ Sci Technol, 2011, 45(19): 8098
3. [3]
  [3] Prevedouros K, Cousins I, Buck R, et al. Environ Sci Technol, 2006, 40(1): 32
4. [4]
  [4] Rayne S, Forest K. J Environ Sci Health Part A, 2009, 44: 1145
5. [5]
  [5] Ahrens L. J Environ Monit, 2011, 13(1): 20
6. [6]
  [6] Lau C, Anitole K, Hodes C, et al. Toxicol Sci, 2007, 99: 366
7. [7]
  [7] Giesy J P, Naile J E, Khim J S, et al. Rev Environ Contam Toxicol, 2010, 202: 1
8. [8]
  [8] Eschauzier C, Beerendonk E, Scholte-Veenendaal P, et al. Environ Sci Technol, 2012, 46(3): 1708
9. [9]
  [9] Peng S Y, Yan L J, Zhang J, et al. Chinese Journal of Chromatography (彭思远, 严丽娟, 张洁, 等. 色谱), 2012, 30(2): 123
10. [10]
  [10] United Nations Environment Programme (UNEP ). UNEP-POPS-COP.4-SC-4-17. Listing of Perfluorooctane Sulfonic Acid, Its Salts and Perfluorooctane Sulfonyl Fluoride//Stockholm Convention on Persistent Organic Pollutants. 2009/5: COP.4, Geneva. (2009-05-09). http://chm.pops.int/Convention/Pressrelease/ COP4Geneva8May2009/tabid/542/language/en-US/Default.aspx
11. [11]
  [11] Chen C L, Wang T Y, Lü Y L, et al. Environmental Science (陈春丽, 王铁宇, 吕永龙, 等. 环境科学), 2011, 32(4): 1073
12. [12]
  [12] Chen J, Wang L L, Zhu H D. Environmental Science (陈静, 王琳玲, 朱湖地, 等. 环境科学), 2012, 33(8): 2586
13. [13]
  [13] Zhang W, Zhang Y T, Taniyasu S, et al. Environ Pollut, 2013, 176: 10
14. [14]
  [14] Peng R, Cheng X Y, Zhang K R. Sichuan Environment (彭蓉, 程小艳, 张克荣. 四川环境), 2008, 27(3): 97
15. [15]
  [15] Wang L B, Lü G, Liu S C, et al. Chinese Journal of Analysis Laboratory (王利兵, 吕刚, 刘绍从, 等. 分析试验室), 2007, 26(2): 94
16. [16]
  [16] Zhao X F, Li Y, Zhang H J, et al. Chinese Journal of Chromatography (赵晓峰, 李云, 张海军, 等. 色谱), 2010, 28(5): 435
17. [17]
  [17] Zhang M, Tang F L, Chen F, et al. Chinese Journal of Chromatography (张明, 唐访良, 陈峰, 等. 色谱), 2012, 30(1): 51
18. [18]
  [18] Zheng H, Hu G C, Xu Z C, et al. Journal of Agro-Environment Science (郑海, 胡国成, 许振成, 等. 农业环境科学学报), 2013, 32(4): 778
19. [19]
  [19] Zhang T, Sun H W, Alder Alfredo C, et al. Chinese Journal of Chromatography (章涛, 孙红文, Alder Alfredo C, 等. 色谱), 2010, 28(5): 498
20. [20]
  [20] Zhang P, Shi Y L, Cai Y Q, et al. Chinese Journal of Analytical Chemistry (张萍, 史亚利, 蔡亚岐, 等. 分析化学), 2007, 35(7): 969
21. [21]
  [21] Wang C X, Guo D H, Li B, et al. Journal of Hygiene Research (王传现, 郭德华, 李波, 等. 卫生研究), 2007, 36(6): 727
22. [22]
  [22] Li X, Chen J H, Cheng H Y, et al. Environmental Chemistry (李鑫, 陈军辉, 程红艳, 等. 环境化学), 2012, 31(6): 896
23. [23]
  [23] US EPA. Title 40: Part 136, Appendix B to Part 136. (1986-06-30). http://www.gpo.gov/fdsys/pkg/CFR-2011-title40-vol23/pdf/CFR-2011-title40-vol23-part136-appB.pdf
24. [24]
  [24] US EPA. Provisional Health Advisories for Perfluorooctanoic Acid (PFOA) and Perfluorooctane Sulfonate (PFOS). (2009-01-15). http://water.epa.gov/action/advisories/drinking/upload/2009_01_15_criteria_drinking_pha-PFOA_PFOS.pdf
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