Citation: LI Haifang, YANG Hongyun, ZHANG Ying, WANG Peilong, LIN Jin-Ming. Dispersive solid phase microextraction of vanillins in milk using magnetic nanoparticles of ferroferric oxide/carbon nanotubes combining with high performance liquid chromatography analysis[J]. Chinese Journal of Chromatography, ;2014, 32(4): 413-418. doi: 10.3724/SP.J.1123.2013.11015 shu

Dispersive solid phase microextraction of vanillins in milk using magnetic nanoparticles of ferroferric oxide/carbon nanotubes combining with high performance liquid chromatography analysis

1.
1. Department of Chemistry, Tsinghua University, Beijing 100084, China;

Corresponding author: LIN Jin-Ming,
Received Date: 6 November 2013
Available Online: 15 January 2014
Fund Project: 高等学校博士学科点专项科研基金项目(20110002110052)；国家“211工程”项目“高等学校仪器设备和优质资源共享系统”(CERS-1-75). (20110002110052)；国家“211工程”项目“高等学校仪器设备和优质资源共享系统”(CERS-1-75)

Magnetic nanoparticles of ferroferric oxide/carbon nanotubes (Fe₃O₄/CNTs) were synthesized by chemically bonding single-walled carbon nanotubes (SWCNTs) to the Fe₃O₄ nanoparticles. The pretreated carboxyl SWCNTs were modified on the surface of amino-functioned Fe₃O₄ nanoparticles through the cross-linking reaction between 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide (EDC) and N-hydroxysuccinimide (NHS). The synthesized Fe₃O₄/CNTs nanoparticles presented high super paramagnetic property and good dispersion ability, and were considered as good candidate adsorbents for dispersive solid phase microextraction. In this work, the synthesized Fe₃O₄/CNTs nanoparticles were applied to the extraction of vanillin additives, which was combined with high performance liquid chromatography (HPLC) analysis. The rapid and efficient preconcentration of vanillin and ethyl vanillin from different milk samples were successfully obtained with the detection limits of 10 μg/L and satisfactory recoveries of more than 92%. The results indicated that Fe₃O₄/CNTs magnetic nanoparticles were good pretreatment alternatives for the concentration of vanillin additives in milk products.
- magnetic nanoparticles,
- ferroferric oxide,
- single-walled carbon nanotubes (SWCNTs),
- high performance liquid chromatography (HPLC),
- vanillin additives,
- milk
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