Citation: WANG Bingling, ZHANG Xiaoling, ZHANG Qi, LU Xiaomei, CUI Yuan, ZHANG Zhengdong. Determination of 39 polychlorinated biphenyls in indoor dust using ultrasonic extraction and gas chromatography-tandem mass spectrometry[J]. Chinese Journal of Chromatography, ;2014, 32(1): 74-80. doi: 10.3724/SP.J.1123.2013.09007 shu

Determination of 39 polychlorinated biphenyls in indoor dust using ultrasonic extraction and gas chromatography-tandem mass spectrometry

1.
1. Department of Hygienic Analysis and Detection of School of Public Health, Nanjing Medical University, Nanjing 211166, China;

Corresponding author: ZHANG Xiaoling,
Received Date: 6 September 2013
Available Online: 13 November 2013
Fund Project: 国家自然科学基金面上项目(81072268) (81072268)江苏省自然科学基金面上项目(BK2010535) (BK2010535)江苏省博士后基金(1001017C) (1001017C)

A method for the determination of 39 polychlorinated biphenyls (PCBs) in indoor dust was developed. A vacuum cleaner was used for gathering the house dust. N-Hexane-dichloromethane (1:1, v/v) was added and the extraction was performed in an ultrasonic bath. The supernatant was concentrated and then 0.1 mL n-hexane-dichloromethane (1:1, v/v) was added. Gas chromatography-tandem mass spectrometry (GC-MS/MS) in selected-reaction monitoring (SRM) mode has been investigated for the determination of the 39 PCBs congeners in indoor dust. The 39 PCBs had highly efficient separation within 30 min and showed good linearity in the range of 0.1-100 μg/L with the correlation coefficients of 0.9910-0.9999. The spiked recoveries were 57.2%-120.3%. The intra-day relative standard deviations (RSDs) were between 0.3% and 24.7%, while the inter-day RSDs were between 0.6% and 29.9%. This method has good linearity, high sensitivity, high accuracy and precision. Also, it is simple, rapid and low solvent consumption. The low chemical background interference allowed it to be used in more complex matrices.
- gas chromatography-tandem mass spectrometry (GC-MS/MS),
- polychlorinated biphenyls (PCBs),
- indoor dust
1. [1]
  [1] Chen Z F, Zhu J, Zhou Y K. Analysis and Evaluation of Environmental Hormone. Beijing: Chemical Industry Press (陈正夫, 朱坚, 周亚康. 环境激素的分析与评价. 北京: 化学工业出版社), 2004: 48
2. [2]
  [2] Pentti N, Heli L, Antti H, et al. Chemosphere, 2013, 91(2): 131
3. [3]
  [3] Liu B B, Chen J F, Zhang Y. Journal of Environment and Health (刘贝贝, 陈剑峰, 张勇. 环境与健康杂志), 2009, 26(1): 90
4. [4]
  [4] Nama E M, Michèle B, Nathalie H G, et al. Regul Toxicol Pharm, 2012, 64(1): 161
5. [5]
  [5] Zhang X L, Wang B L, Lu X M, et al. Chinese Journal of Chromatography (张晓玲, 王炳玲, 陆晓梅, 等. 色谱), 2012, 30(12): 1241
6. [6]
  [6] Li L, Huang J, Cao X J, et al. Pollution Control Technology (黎莉, 黄晶, 曹旭静, 等. 污染防治技术), 2011, 24(2): 16
7. [7]
  [7] Chen M Y, Zhang X L, Yu L H, et al. Journal of Instrumental Analysis (陈满英, 张秀蓝, 余乐洹, 等. 分析测试学报), 2012, 31(6): 651
8. [8]
  [8] Liu J W, Wang L, An C X, et al. Rock and Mineral Analysis (刘金巍, 王磊, 安彩秀, 等. 岩矿测试), 2011, 30(5): 611
9. [9]
  [9] Li Q, Xia J, Bai Y K, et al. Journal of Chinese Mass Spectrometry Society (李强, 夏静, 白彦坤, 等. 质谱学报), 2012, 33(5): 295
10. [10]
  [10] Zhao Y G, Wang Y F, Shi J W, et al. Chinese Journal of Health Laboratory Technology (赵永纲, 王玉飞, 施家威, 等. 中国卫生检验杂志), 2010, 20(12): 3094
11. [11]
  [11] Wang Y, Yu Z Q, Luo X F, et al. Chinese Journal of Analytical Chemistry (汪洋, 于志强, 罗湘凡, 等. 分析化学), 2012, 40(8): 1187
12. [12]
  [12] Liu Y, Ji X L, Ma J, et al. Research of Environmental Sciences (刘洋, 冀秀玲, 马静, 等. 环境科学研究), 2011, 24(5): 482
13. [13]
  [13] Li C, Yu Y X, Zhang D P, et al. China Environmental Science (李琛, 余应新, 张东平, 等. 中国环境科学), 2010, 30(4): 433
14. [14]
  [14] Ren M, Peng P A, Zhang S K, et al. Chinese Journal of Analytical Chemistry (任曼, 彭平安, 张素坤, 等. 分析化学), 2007, 35(2): 176
15. [15]
  [15] Fan L, Huang S H, Tian T, et al. Journal of Guangxi Academy of Sciences (范磊, 黄素华, 田霆, 等. 广西科学院学报), 2012, 28(4): 249
16. [16]
  [16] Ma L S, Zhu X P, Zheng G M, et al. Chinese Journal of Veterinary Drug (马丽莎, 朱新平, 郑光明, 等. 中国兽药杂志), 2011, 45(6): 22
17. [17]
  [17] Na W, De Y K, Zheng J S, et al. J Chromatogr B, 2012, 898: 38
18. [18]
  [18] Ricklund N, Kierkegaard A, McLachlan M S. Chemosphere, 2008, 73(11): 1799
19. [19]
  [19] Sánchez-Brunete C, Miguel E, Tadeo J L. Talanta, 2006, 70(5): 105l
20. [20]
  [20] Ran Y, Sun K. Environmental Pollution, 2007, 148(2): 529
21. [21]
  [21] Wang D D, Huang W H, Yang L Q. Journal of Instrumental Analysis (王丹丹, 黄卫红, 杨岚钦. 分析测试学报), 2011, 30(8): 912
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