Citation: LI Jiwen, LI Wei, WANG Chuan. Characterization of C₅-C₇ alkenes in gasoline from methanol to olefins process using gas chromatography-mass spectrometry[J]. Chinese Journal of Chromatography, ;2013, 31(11): 1134-1139. doi: 10.3724/SP.J.1123.2013.05047 shu

Characterization of C₅-C₇ alkenes in gasoline from methanol to olefins process using gas chromatography-mass spectrometry

1.
SINOPEC Shanghai Research Institute of Petrochemical Technology, Shanghai 201208, China

Corresponding author: LI Jiwen,
Received Date: 27 May 2013
Available Online: 4 July 2013
Fund Project: 中国石油化工集团公司科技攻关项目(项目号:19). (项目号:19)

Gas chromatography-mass spectrometry (GC-MS) qualitative characterization of C₅-C₇ alkenes in gasoline from methanol to olefins (MTO) was investigated in detail. It showed that the retention indices of 49 alkenes, 11 alkadienes and 9 cycloalkenes, a total of 69 C₅-C₇ isomeric alkenes were determined and qualitatively confirmed. The retention indices of all C₅-C₇ alkenes in MTO gasoline were measured on polydimethylsiloxane as the stationary phase. According to the library of retention indices by GC-MS characterization, the contents of C₅-C₇ alkenes in MTO gasoline were analyzed by GC and characterized by its composition of hydrocarbon categories. The results of quantitative analysis showed that the composition of MTO gasoline mainly consisted of C₅-C₇ alkenes, and a small amount of alkadienes and cycloalkenes. The contents of alkanes and cycloalkanes existed in MTO gasoline were very low. The study of the composition is helpful for the comprehensive application of MTO gasoline.
- gas chromatography (GC),
- mass spectrometry (MS),
- alkenes,
- gasoline,
- methanol to olefins (MTO)
1. [1]
  [1] Liu H X, Xie Z K, Zhang C F, et al. Natural Gas Chemical Industry (刘红星, 谢在库, 张成芳, 等. 天然气化工), 2002, 27(3): 49
2. [2]
  [2] Liu G Y, Tian P, Xia Q H, et al. J Nat Gas Chem, 2012, 21(4): 431
3. [3]
  [3] Dong Y H. Chemical Engineering & Equipment (董宇涵. 化学工程与装备), 2010(3): 136
4. [4]
  [4] Wang G, Tang Y, Xue Z X. Liaoning Chemical Industry (王庚, 唐煜, 薛振欣. 辽宁化工), 2011, 40(7): 735
5. [5]
  [5] Wu X Z. Shenhua Technology (吴秀章. 神华科技), 2011, 9(4): 70
6. [6]
  [6] Zhang D M. Chemical Industry (张东明. 化学工业), 2012, 30(6): 12
7. [7]
  [7] Kong F G, Zhang J Y. Chemical Intermediate (孔凡贵, 张婧元. 化工中间体), 2012(11): 13
8. [8]
  [8] Fu R N. Chinese Journal of Chromatography (傅若农. 色谱), 2009, 27(5): 584
9. [9]
  [9] Guo K, Zhou J, Liu Z L. Chinese Journal of Chromatography (郭琨, 周建, 刘泽龙. 色谱), 2012, 30(2): 128
10. [10]
  [10] Xue H F, Geng Z J, Qin P, et al. Petrochemical Technology & Application (薛慧峰, 耿占杰, 秦鹏, 等. 石化技术与应用), 2011, 29(4): 362
11. [11]
  [11] Soják L, Addová G, Kubinec R, et al. J Chromatogr A, 2002, 947: 103
12. [12]
  [12] Ramns O, stermark U, Petersson G. Chromatographia, 1994, 38(3/4): 222
13. [13]
  [13] Liu Y R, Yang H Y. Chinese Journal of Chromatography (刘颖荣, 杨海鹰. 色谱), 2003, 21(1): 1
14. [14]
  [14] Liu Y R, Yang H Y. Chinese Journal of Chromatography (刘颖荣, 杨海鹰. 色谱), 2003, 21(2): 97
15. [15]
  [15] Zhang Z L, Yang H Y, Wang H D. Chinese Journal of Chromatography (张自力, 杨海鹰, 王皓东. 色谱), 1997, 15(4): 341
16. [16]
  [16] Tang J G, Leng Z G. Analytical Instrumentation (唐建光, 冷志光. 分析仪器), 2009(3): 22
17. [17]
  [17] Leng Z G. Journal of Instrumental Analysis (冷志光. 分析测试学报), 1999, 18(3): 43
18. [18]
  [18] Leng Z G, Wang L, Cheng S H. Petroleum Processing and Petrochemicals (冷志光, 王莉, 成世红. 石油炼制与化工), 2000, 31(4): 64
1. [1]
  Danqing Wu , Jiajun Liu , Tianyu Li , Dazhen Xu , Zhiwei Miao . Research Progress on the Simultaneous Construction of C—O and C—X Bonds via 1,2-Difunctionalization of Olefins through Radical Pathways. University Chemistry, 2024, 39(11): 146-157. doi: 10.12461/PKU.DXHX202403087
2. [2]
  Jingming Li , Bowen Ding , Nan Li , Nurgul . Application of Comparative Teaching Method in Experimental Project Design of Instrumental Analysis Course: A Case Study in Chromatography Experiment Teaching. University Chemistry, 2024, 39(8): 263-269. doi: 10.3866/PKU.DXHX202312078
3. [3]
  Wei Shao , Wanqun Zhang , Pingping Zhu , Wanqun Hu , Qiang Zhou , Weiwei Li , Kaiping Yang , Xisheng Wang . Design and Practice of Ideological and Political Cases in the Course of Instrument Analysis Experiment: Taking the GC-MS Experiment as an Example. University Chemistry, 2024, 39(2): 147-154. doi: 10.3866/PKU.DXHX202309048
4. [4]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
5. [5]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
6. [6]
  Hongling Yuan , Jialin Xie , Jiawei Wang , Jixiang Zhao , Jiayan Liu , Qing Feng , Wei Qi , Min Liu . Cyclic Olefin Copolymer (COC): The Agile Vanguard in the Realm of Materials. University Chemistry, 2024, 39(7): 294-298. doi: 10.12461/PKU.DXHX202311041
7. [7]
  Xunzhang Fan , Yuanjin Zhao , Shufang Luo , Aihua He . Karl Ziegler: A Pioneer in the Polyolefin Industry – Commemorating the 50th Anniversary of the German Chemist’s Passing. University Chemistry, 2024, 39(8): 389-394. doi: 10.3866/PKU.DXHX202312065
8. [8]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098
9. [9]
  Weina Wang , Lixia Feng , Fengyi Liu , Wenliang Wang . Computational Chemistry Experiments in Facilitating the Study of Organic Reaction Mechanism: A Case Study of Electrophilic Addition of HCl to Asymmetric Alkenes. University Chemistry, 2025, 40(3): 206-214. doi: 10.12461/PKU.DXHX202407022
10. [10]
  Yan Li , Xinze Wang , Xue Yao , Shouyun Yu . 基于激发态手性铜催化的烯烃E→Z异构的动力学拆分——推荐一个本科生综合化学实验. University Chemistry, 2024, 39(5): 1-10. doi: 10.3866/PKU.DXHX202309053
11. [11]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
12. [12]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036
13. [13]
  Zian Lin , Yingxue Jin . Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry (MALDI-MS) for Disease Marker Screening and Identification: A Comprehensive Experiment Teaching Reform in Instrumental Analysis. University Chemistry, 2024, 39(11): 327-334. doi: 10.12461/PKU.DXHX202403066
14. [14]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
15. [15]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
16. [16]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
17. [17]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
18. [18]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
19. [19]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
20. [20]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Cu基和Pt基甲醇水蒸气重整制氢催化剂研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-. doi: 10.1016/j.actphy.2025.100049

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(505)
HTML views(26)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Characterization of C5-C7 alkenes in gasoline from methanol to olefins process using gas chromatography-mass spectrometry

Metrics

通讯作者: 陈斌, bchen63@163.com

Characterization of C₅-C₇ alkenes in gasoline from methanol to olefins process using gas chromatography-mass spectrometry