Citation: YUN Huan, LIU Xin, WANG Jing, YAN Hua, CUI Fengyun, ZHANG Zhaohui. Rapid screening and confirming carcinogenic banned azo colorants in textiles by high performance liquid chromatography-linear ion trap/orbitrap high-resolution mass spectrometry[J]. Chinese Journal of Chromatography, ;2013, 31(9): 845-849. doi: 10.3724/SP.J.1123.2013.01031 shu

Rapid screening and confirming carcinogenic banned azo colorants in textiles by high performance liquid chromatography-linear ion trap/orbitrap high-resolution mass spectrometry

1.
Technology Center of Beijing Entry-Exit Inspection and Quarantine Bureau, Beijing 100026, China

Corresponding author: YUN Huan,
Received Date: 22 January 2013
Available Online: 8 March 2013
Fund Project: 国家质检总局科研项目(2010IK104,2012IK145). (2010IK104,2012IK145)

A method of high performance liquid chromatography-linear ion trap/orbitrap high-resolution mass spectrometry (HPLC-LTQ/Orbitrap MS) was used to screen and confirm banned azo colorants in textiles rapidly. The analytes were reduced to carcinogenic aromatic amines with sodium dithionite in citrate buffer solution. The reduced solution was extracted by diatomite, and loaded onto an Acquity UPLC BEH C18 column (50 mm×2.1 mm, 1.7 μm)with a gradient elution of methanol and 0.1%(v/v) methane acid aqueous solution, and finally detected by linear ion trap/orbitrap high-resolution mass spectrometry in positive ESI mode. In mass spectrometry method, the MS spectrum of high-resolution and the collision induced dissociation (CID) spectrum of data-dependent scan mode were used for screening analysis and conformation, respectively. The calibration curves showed a good linearity in the range of 0.05-2.00 mg/L, and the correlation coefficients (r) were higher than 0.99. By detecting spiked samples, the limits of quantification were 0.08 mg/kg for all the residues and the recoveries were in the range of 65.5%-111.5% with the relative standard deviations (RSDs) between 0.87% and 2.49%. The results indicate that the method is simple, rapid, sensitive and suitable for the qualitative and quantitative analysis of carcinogenic aromatic amines in textiles.
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沈阳化工大学材料科学与工程学院沈阳 110142