Citation: QIU Xiuzhen, GUO Huishi, CHEN Buqing. Determination of three phenolic compounds in water samples by solid phase extraction with microemulsion liquid chromatography[J]. Chinese Journal of Chromatography, ;2013, 31(8): 809-812. doi: 10.3724/SP.J.1123.2013.01029 shu

Determination of three phenolic compounds in water samples by solid phase extraction with microemulsion liquid chromatography

1.
College of Chemistry and Environmental Engineering, Shaoguan University, Shaoguan 512005, China

Corresponding author: GUO Huishi,
Received Date: 14 January 2013
Available Online: 22 March 2013
Fund Project: 教育部留学回国人员科研启动基金项目(第39批) (第39批)广东省自然科学基金项目(9151200501000008) (9151200501000008)

A method for the determination of phenol, bisphenol A (BPA), 2,4-dichlorophenol in water samples based on solid-phase extraction with microemulsion liquid chromatography(MELC) was established. The water sample was acidified, and then cleaned-up by a C18 solid-phase extraction cartridge. The separation was carried out on an Inertsil C18 (150 mm×4.6 mm, 5 μm) with a gradient elution using a microemulsion (consisting of 3.0% sodium dodecyl sulfate (SDS), 6.0% butyl alcohol, 0.8% n-heptane, 90.2% (water+0.5% acetic acid)) and acetonitrile as mobile phases at a flow rate of 1.0 mL/min and a detection wavelength of 280 nm. The detection limits (S/N=3) of phenol, BPA, 2,4-dichlorophenol were 0.74, 8.0, 8.0 μg/L, respectively. Good linearities were achieved for the target compounds over the range of 0.1-10 mg/L. The spiked recoveries of three phenolic compounds in blank water samples were 82.7%, 87.8%, 82.6% for phenol, BPA, 2,4-dichlorophenol respectively. The recoveries of target compounds in real water samples ranged from 85.7% to 113.2%. The developed method is simple, selective, sensitive and applicable for the analysis of environmental water samples.
- solid-phase extraction (SPE),
- microemulsion liquid chromatography (MELC),
- phenol,
- bisphenol A,
- 2,4-dichlorophenol
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沈阳化工大学材料科学与工程学院沈阳 110142