Citation: DAI Shou-Hui, ZHAO Hua-Lin, WANG Min, Charles S. Wang, CHAI Ting-Ting, YANG Shu-Ming, QIU Jing. Determination of Polychlorinated Biphenyls Enantiomers in Lotus Root and Sediment by Chiral Gas Chromatography-Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry, ;2012, 40(11): 1758-1763. doi: 10.3724/SP.J.1096.2012.20523 shu

Determination of Polychlorinated Biphenyls Enantiomers in Lotus Root and Sediment by Chiral Gas Chromatography-Mass Spectrometry

DAI Shou-Hui ^1,2 ,
ZHAO Hua-Lin ^1,2 ,
WANG Min ^1,2 ,
Charles S. Wang ³ ,
CHAI Ting-Ting ^1,2 ,
YANG Shu-Ming ^1,2 ,
QIU Jing ^1,2,,

1.
¹ Institute of Quality Standard & Testing Technology for Agro-Products, Key Laboratory of Agro-product Quality and Safety, Chinese Academy of Agricultural Sciences, Beijing 100081, China;

Corresponding author: QIU Jing,
Received Date: 20 May 2012
Available Online: 23 July 2012
Fund Project: 本文系国家自然科学基金(No. 20907073)资助项目 (No. 20907073)

An enantioselective method was developed for separation and determination of six chiral polychlorinated biphenyls (PCBs) including PCB 91, 95, 136, 149, 176 and 183 in lotus root, stem, leaf and sediment by GC-MS. After optimizations of instrumental parameters for enantiomeric separation and investigations of sample preparations including accelerated solvent extraction (ASE) parameters, extraction solvents and cleanup methods, PCBs enantiomers were extracted from samples by ASE with n-hexane/acetone (1:1, V/V) at 100℃ and 10.3 MPa for 10 min. The extracts were orderly sulphonated by sulfuric acid, purified by Florisil solid phase extraction column, reconstituted with isooctane after being concentrated, and respectively detected by GC-MS with Chirasil-Dex and BGB-172 columns. For all PCBs enantiomers, good linearities were obtained in the concentration range of 0.5-100 μg/L, and recoveries of spiked samples at 0.25, 2.5 and 25 μg/kg levels were 82.8%-117.0% with relative standard deviations (RSD) of 1.5%-13.6%. Limits of detection (LOD) and limits of quantification (LOQ) were 0.01-0.02 μg/kg and 0.025-0.04 μg/kg, respectively. The real samples analysis showed that chiral PCBs were not detected in lotus roots from markets, but higher concentrations were found in lotus root and sediment from contaminated area. The concentrations of PCB 91-2, PCB 95-1 and (+)- PCB 136 in lotus root, stem and leaf were respectively higher than those of their enantiomers, while no significant differences between two enantiomers of PCB 149, 176 and 183.
- Polychlorinated biphenyls,
- Enantiomer,
- Gas chromatography-mass spectrometry,
- Accelerated solvent extraction,
- Lotus root,
- Sediment
1. [1]
  1 PENG Yan-Chao, HUANG Gen-Hua, SUN Min. China New Technologies and Products, 2010, (3): 23-24
2. [2]
  彭艳超, 黄根华, 孙敏. 中国新技术新产品, 2010, (3): 23-24
3. [3]
  2 SHI Yong-Fu, LIN Hong, HUANG Dong-Mei, GONG Qian, CAI You-Qiong, WANG Yuan, QIAN Bei-Lei. Chinese J. Anal. Chem., 2010, 38(9): 1345-1348
4. [4]
  史永富, 林洪, 黄冬梅, 龚倩, 蔡友琼, 王媛, 钱蓓蕾. 分析化学, 2010, 38(9): 1345-1348
5. [5]
  3 Kaiser K L E. Environ. Pollut., 1974, 7(2): 93-101
6. [6]
  4 Püttmann M, Mannschreck A, Oesch F, Robertson L. Biochem. Pharmacol., 1989, 38(8): 1345-1352
7. [7]
  5 Rodman L E, Shedlofsky S I, Mannschreck A, Püttmann M, Swim A T, Robertson L W. Biochem. Pharmacol., 1991, 41(6): 915-922
8. [8]
  6 Determination of polychlorobiphenyls (PCBs) in feed-Gas chromatography. National Standards of the People's Republic of China. GB/T 8381.8-2005
9. [9]
  饲料中多氯联苯的测定-气相色谱法. 中华人民共和国国家标准. GB/T 8381.8-2005
10. [10]
  7 LI Li-Jun, WANG Na, WANG Hai-Jiao, SONG Li-Hua. Chinese J. Anal. Lab., 2009, 28(12): 4-7
11. [11]
  李丽君, 王娜, 王海娇, 宋丽华. 分析实验室, 2009, 28(12): 4-7
12. [12]
  8 HU En-Yu, YANG Li-Li, WANG Mei-Fei, MU Ying-Feng. The Administration and Environmental Monitoring, 2010, 22(1): 44-48
13. [13]
  胡恩宇, 杨丽莉, 王美飞, 母应锋. 环境监测管理技术, 2010, 22(1): 44-48
14. [14]
  9 Warner N A, Wong C S. Environ. Sci. Technol., 2006, 40(13): 4158-4164
15. [15]
  10 Wong C S, Lau F, Clark M, Mabury S A, Muir D C G. Environ. Sci. Technol., 2002, 36 (6): 1257-1262
16. [16]
  11 Ross M S, Verreault J, Letcher R J, Gabrielsen G W, Wong C S. Environ. Sci. Technol., 2008, 42(19): 7181-7186
17. [17]
  12 Zhai G S, Hu D F, Lehmler H J, Schnoor J L. Environ. Sci. Technol., 2011, 45(6): 2308-2316
18. [18]
  13 Hardt I H, Wolf C, Gehrcke B, Hochmuth D H, Pfaffenberger B, Hühnerfuss H. J. High Resolut. Chromatogr., 1994, 17(12): 859-864
19. [19]
  14 Wong C S, Garrison A W. J. Chromatogr. A, 2000, 866(2): 213-220
20. [20]
  15 HE Xiao-Qing, LI Gong-Ke, XIONG Guo-Hua, ZHANG Zhan-Xia. Chinese J. Anal. Chem., 2000, 28(1): 26-30
21. [21]
  何小青, 李攻科, 熊国华, 张展霞. 分析化学, 2000, 28(1): 26-30
22. [22]
  16 Karasali H, Balayiannis G, Anagnostopoulos H, Hourdakis A. Bull. Environ. Contam. Toxicol., 2005, 75(2): 257-263
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