Citation: WANG Yue, HE Yi-Jin, QIAO Chen-Xi, HAO Yi, ZHANG Jun-Jie, LYU Dong-Mei, GAO Rui-Xia. Preparation of Cochineal Hyperbranched Magnetic Adsorbent with High Adsorption Performance and Its Application in Environmental Water[J]. Chinese Journal of Analytical Chemistry, ;2023, 51(2): 259-268. doi: 10.19756/j.issn.0253-3820.221361 shu

Preparation of Cochineal Hyperbranched Magnetic Adsorbent with High Adsorption Performance and Its Application in Environmental Water

1.
School of Chemistry, Xi'an Jiaotong University, Xi'an 710049, China;
2.
School of Pharmacy, Xi'an Jiaotong University, Xi'an 710061, China

Corresponding author: GAO Rui-Xia, ruixiagao@mail.xjtu.edu.cn
Received Date: 19 July 2022
Revised Date: 29 August 2022

Fund Project: Reusability

The cochineal hyperbranched polyglycidyl ether magnetic adsorbents (Fe₃O₄-HPG) were synthesized for adsorption of cochineal with glycidyl ether as functional monomer, cochineal as target, and Fe₃O₄ as carrier by a simple and ingenious synthesis method for the first time. The physical and chemical properties of the materials were characterized by transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and vibrating sample magnetometer (VSM). These results showed that Fe₃O₄-HPG had uniform particle size, good magnetism, and stable crystal structure. At the same time, the kinetic adsorption, thermodynamic adsorption, and reusability of Fe₃O₄-HPG were investigated. The prepared materials had high adsorption capacity (106.06 mg/g), fast adsorption rate (60 min) and good reusability (Adsorption efficiency of 95.8% after reusing for 8 times). Moreover, combined with high performance liquid chromatography, the Fe₃O₄-HPG as adsorbents were successfully used to specifically recognize and detect cochineal in environmental water with recoveries over 94.6%.
- Reusability,
- Magnetic separation,
- Hyperbranched adsorbent,
- Cochineal,
- High adsorption performance
1. [1]
2. [2]
3. [3]
4. [4]
  TAKAHASHI E, MARCZYLO T H, WATANABE T, NAGAI S, HAYATSU H, NEGISHI T. Mutat. Res. Fundamental Mol. Mech. Mutagenesis, 2001, 480:139-145.
5. [5]
6. [6]
  YAMAGUCHI H, MASUDA T. J. Agric. Food Chem., 2011, 59(18):9770-9775.
7. [7]
  PETRUCI J F S, PEREIRA E A, CARDOSO A A. J. Agric. Food Chem., 2013, 61(9):2263-2267.
8. [8]
  SCHLEE C, MARKOVA M, SCHRANK J, LAPLAGNE F, SCHNEIDER R, LACHENMEIER D W. J. Chromatogr. B, 2013, 927:223-226.
9. [9]
  CRESCENZI C, BAYOUDH S, CORMACK P A G, KLEIN T, ENSING K. Anal. Chem., 2001, 73(10):2171-2177.
10. [10]
11. [11]
12. [12]
13. [13]
  WANG Y, ZHAO W, GAO R, HUSSAIN S, HAO Y, TIAN J, CHEN S, FENG Y, ZHAO Y, QU Y. J. Hazard. Mater., 2022, 424:127216.
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
  ZHANG R Y, LI Q, LI J, ZHOU W Q, YE P L, GAO Y, MA G H, SU Z G. Mater. Sci. Eng., C, 2012, 32(8):2628-2633.
19. [19]
20. [20]
  ZHU W, PENG H, LUO M, YU N, XIONG H, WANG R, LI Y. Food Chem., 2018, 261:87-95.
21. [21]
  HE Y, CHENG Z, QIN Y, XU B, NING L, ZHOU L. Mater. Lett., 2015, 151:100-103.
22. [22]
  CUI Y, KANG W W, QIN L, MA J H, LIU X G, YANG Y Z. Chem. Eng. J., 2020, 397:1125480.
23. [23]
  TIAN X, GAO R, WANG Y, HE Y, HUSSAIN S, HEINLEIN J, TIAN J, PFEFFERLE L D, TANG X, TANG Y. Green Chem., 2021, 23(10):3623-3632.
24. [24]
  ASIEH A, NAJMEDIN A, SANAEISHOAR H, ELHAM T. Polycyclic Aromat. Compd., 2022, DOI:10.1080/10406638.2022.2036776.
25. [25]
  ATTALLAH O A, AL-GHOBASHY M A, NEBSEN M, SALEM M Y. ACS Sustainable Chem. Eng., 2016, 5(1):133-145.
26. [26]
  EZZATI R. Chem. Eng. J., 2020, 392:123705.
27. [27]
  HAMEEDAT F, HAWAMDEH S, ALNABULSI S, ZAYED A. Molecules, 2022, 27(6):1807.
1. [1]
  Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013
2. [2]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
3. [3]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
4. [4]
  Jianan Zhang , Mengzhen Xu , Jiamin Liu , Yufei He . 面向“双碳”目标的脱氯吸附剂开发研究型综合实验设计. University Chemistry, 2025, 40(6): 248-255. doi: 10.12461/PKU.DXHX202408068
5. [5]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
6. [6]
  Shuhong Xiang , Lv Yang , Yingsheng Xu , Guoxin Cao , Hongjian Zhou . Selective electrosorption of Cs(Ⅰ) from high-salinity radioactive wastewater using CNT-interspersed potassium zinc ferrocyanide electrodes. Acta Physico-Chimica Sinica, 2025, 41(9): 100097-0. doi: 10.1016/j.actphy.2025.100097
7. [7]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
8. [8]
  Yang ZHOU , Lili YAN , Wenjuan ZHANG , Pinhua RAO . Thermal regeneration of biogas residue biochar and the ammonia nitrogen adsorption properties. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1574-1588. doi: 10.11862/CJIC.20250032
9. [9]
  Yanyan Zhao , Zhen Wu , Yong Zhang , Bicheng Zhu , Jianjun Zhang . Enhancing photocatalytic H₂O₂ production via dual optimization of charge separation and O₂ adsorption in Au-decorated S-vacancy-rich CdIn₂S₄. Acta Physico-Chimica Sinica, 2025, 41(11): 100142-0. doi: 10.1016/j.actphy.2025.100142
10. [10]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
11. [11]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
12. [12]
  Kun JIANG , Yutong XUE , Kelin LIU , Miao WANG , Tongming SUN , Yanfeng TANG . CeVO₄ hollow microspheres: Fabrication and adsorption performance for dyes. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2229-2236. doi: 10.11862/CJIC.20250223
13. [13]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
14. [14]
  Wenjuan SHI , Yuke LU , Xiuyuan LI , Lei HOU , Yaoyu WANG . Mg(Ⅱ) metal-organic frameworks based on biphenyltetracarboxylic acid: Synthesis and CO₂ adsorption and catalytic conversion performance. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2455-2463. doi: 10.11862/CJIC.20250220
15. [15]
  Wenlong Wang , Wentao Hao , Lang He , Jia Qiao , Ning Li , Chaoqiu Chen , Yong Qin . Bandgap and adsorption engineering of carbon dots/TiO₂ S-scheme heterojunctions for enhanced photocatalytic CO₂ methanation. Acta Physico-Chimica Sinica, 2025, 41(9): 100116-0. doi: 10.1016/j.actphy.2025.100116
16. [16]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
17. [17]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
18. [18]
  Changjie Yin , Boyu Wang , Dantong Qiao , Huimin Li . Polymer Comprehensive Experimental Design: Preparation and Properties of Repeatable Processing Styrene Butadiene Rubber Materials under the “Dual Carbon” Strategy. University Chemistry, 2025, 40(11): 221-232. doi: 10.12461/PKU.DXHX202412046
19. [19]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-0. doi: 10.3866/PKU.WHXB202312007
20. [20]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(4212)
HTML views(277)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142