Citation: YU Hui, YAO Yi-Chen, XU Xue-Zhe, WEI Na-Na, ZHAO Wei-Xiong, ZHANG Wei-Jun. Study on Atmospheric Ozone Photochemical Production Rate Based on In-situ Measurement of Peroxy Radical[J]. Chinese Journal of Analytical Chemistry, ;2023, 51(2): 287-295. doi: 10.19756/j.issn.0253-3820.221313 shu

Study on Atmospheric Ozone Photochemical Production Rate Based on In-situ Measurement of Peroxy Radical

YU Hui ^1,2 ,
YAO Yi-Chen ^1,2 ,
XU Xue-Zhe ¹ ,
WEI Na-Na ¹ ,
ZHAO Wei-Xiong ^1,, ,
ZHANG Wei-Jun ^1,3

1.
Anhui Institute of Optics and Fine Mechanics, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, China;
2.
Science Island Branch, Graduate School, University of Science and Technology of China, Hefei 230026, China;
3.
School of Environmental Science and Optoelectronics Technology, University of Science and Technology of China, Hefei 230026, China

Corresponding author: ZHAO Wei-Xiong, wxzhao@aiofm.ac.cn
Received Date: 2 June 2022
Revised Date: 29 August 2022

Fund Project: Supported by the National Natural Science Foundation of China (No. U21A2028), the National Research Program for Key Issues in Air Pollution Control, China (No. DQGG202117), the Youth Innovation Promotion Association, CAS (No. Y202089) and the HFIPS Director′s Fund (No. YZJJ202101).

Peroxy radicals (RO₂^* = RO₂ + HO₂) are key intermediates in the atmospheric oxidation of volatile organic compounds, and play a key role in the degradation of primary atmospheric pollution and the formation of secondary pollutants. It is of great significance to accurately measure the concentration of RO₂^* for understanding the atmospheric chemical reaction mechanism and the cause of atmospheric pollution. In this work, a broadband cavity enhanced absorption spectroscopy-chemically amplified peroxy radical instrument was used to measure the peroxy radical in-situ. Combined with the measurement of NO, the photochemical ozone production rate could be determined in real time. Observations were made in Huaibei city during summer 2021, to characterize ozone production. The results showed that the average peaking peroxy radical concentration was 75×10^-12(V/V), while the average ozone peaking production rate was 14×10^-12(V/V) in summer in Huaibei. The ozone production rate was more sensitive to the NO concentration changes. In addition, during the pollution period, the photochemical generation of ozone increased significantly, which made an important contribution to the local high concentration of O₃.
- Peroxyl radicals,
- Broadband cavity enhanced absorption spectroscopy,
- Chemical amplification,
- Field measurement,
- Ozone production rate
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