Citation: TENG Ke-Guo, GAO Jing, YANG Li-Li, YU Quan, WANG Xiao-Hao. Development and Application of Self-aspiration Hollow Needle Corona Discharge Ionization Source[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(8): 1143-1149. doi: 10.19756/j.issn.0253-3820.221094 shu

Development and Application of Self-aspiration Hollow Needle Corona Discharge Ionization Source

TENG Ke-Guo ¹ ,
GAO Jing ¹ ,
YANG Li-Li ² ,
YU Quan ^1,, ,
WANG Xiao-Hao ¹

1.
Division of Advanced Manufacturing, Shenzhen International Graduate School, Tsinghua University, Shenzhen 518055, China;
2.
Measurement Technology and Instrumentation Key Lab of Hebei Province, Yanshan University, Qinhuangdao 066004, China

Corresponding author: YU Quan, yu.quan@sz.tsinghua.edu.cn
Received Date: 23 February 2022
Revised Date: 25 April 2022

Fund Project: Supported by the National Natural Science Foundation of China (No.21775085), the Key Research and Development Program of Hebei Province, China (No.19275509D) and the Fundamental Research Program of Shenzhen, China (No.JCYJ20180508152013054).

A self-aspiration corona discharge ionization source was constructed for detection of volatile organic compounds (VOCs). This source had a simple structure that used the tip of a syringe needle to generate the corona discharge. In addition, the hollow needle could also be used as the introduction pathway for the gaseous sample, which allowed the gas to pass through the corona zone efficiently to improve the ionization efficiency. The needle tip was placed in a sealed chamber that was directly connected to the sampling interface of the mass spectrometer. This design could not only utilize the pumping capability of the instrument for self-aspiration sampling, but also avoid the influence of ambient factors on the ionization process. Moreover, the developed hollow needle corona discharge (HNCD) source could be used with a syringe cylinder to facilitate the collection, storage and automatic injection of gas samples. The experimental test results showed that the HNCD source had various merits, including easy operation, fast response and good stability. The detection limit of aniline acquired using this device was at nL/L level, which showed a good application prospect.
- Corona discharge,
- Self-aspirating injection,
- Mass spectrometry,
- Volatile organic compounds,
- Syringe
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