Citation: XU Yu-Hao, WEI Sheng-Nan, WANG Yue-Kun, XIONG Chen-Yu, XIE Yong, HAN Ming-Jie, WANG Ri, BIAN Chao, XIA Shan-Hong. Electrochemical Sensor Based on Boron-Doped Diamond Electrode for Determination of Phosphate[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(6): 889-898. doi: 10.19756/j.issn.0253-3820.221039 shu

Electrochemical Sensor Based on Boron-Doped Diamond Electrode for Determination of Phosphate

XU Yu-Hao ^1,2 ,
WEI Sheng-Nan ^1,2 ,
WANG Yue-Kun ^1,2 ,
XIONG Chen-Yu ^1,2 ,
XIE Yong ^1,2 ,
HAN Ming-Jie ^1,2 ,
WANG Ri ^1,2 ,
BIAN Chao ^1,, ,
XIA Shan-Hong ^1,,

1.
State Key Laboratory of Transducer Technology, Aerospace Information Research Institute, Chinese Academy of Sciences, Beijing 100190, China;
2.
School of Electronic, Electrical and Communication Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: BIAN Chao, XIA Shan-Hong,
Received Date: 20 January 2022
Revised Date: 2 April 2022

Fund Project: Supported by the National Key Research and Development Program of China(No. 2020YFB2009003).

Phosphorus is an important indicator in surface water quality standards. Excessive phosphate can lead to eutrophication, so it is necessary to develop an accurate and sensitive method for detection of phosphate in water. In this work, an electrochemical sensor based on boron-doped diamond electrode was developed to achieve sensitive detection of phosphate in water through electrochemical reduction of phosphomolybdate. The sensor achieved excellent performances in detection of phosphate, including wide detection range, high sensitivities(0.301 nA·L/μmol in the range of 0.4-5.0 μmol/L, and 97 nA·L/μmol in the range of 5.0-80.0 μmol/L), and low limit of detection(0.1 μmol/L). Meanwhile, the electrochemical sensor showed good anti-interference ability for phosphate detection, and the recoveries of phosphate in tap and lake water sample were 93.8%-104.5%. Compared with standard spectrophotometry, the electrochemical detection process was environmentally friendly with less usage of reagents. The sensor displayed excellent catalytic properties for detection of phosphate without electrode modification, and had potential for long-term online monitoring of phosphate.
- Phosphate detection,
- Boron-doped diamond electrode,
- Electrochemical sensors
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