Citation: LI Shan, CHEN Zhen, LIU Chang-Jie, JIN Jiao, WANG Han, HU Jun, MA He, SHI Jia-Liang, REN Qian, CHENG Yu-Peng, LIU You-Jiang, CHEN Chi-Lai. Rapid Detection of Hydrogen Sulfide Gas at Ambient Humidity Based on Nafion-High-Field Asymmetric Waveform Ion Mobility Spectrometry Technology[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(6): 924-931. doi: 10.19756/j.issn.0253-3820.221019 shu

Rapid Detection of Hydrogen Sulfide Gas at Ambient Humidity Based on Nafion-High-Field Asymmetric Waveform Ion Mobility Spectrometry Technology

LI Shan ^1,2 ,
CHEN Zhen ^1,2 ,
LIU Chang-Jie ¹ ,
JIN Jiao ^1,2 ,
WANG Han ^1,2 ,
HU Jun ^1,2 ,
MA He ^1,2 ,
SHI Jia-Liang ³ ,
REN Qian ³ ,
CHENG Yu-Peng ^1,2 ,
LIU You-Jiang ^1,, ,
CHEN Chi-Lai ^1,,

1.
Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, China;
2.
University of Science and Technology of China, Hefei 230026, China;
3.
INOPEC Beijing Yanshan Company, Beijing 102500, China

Corresponding author: LIU You-Jiang, CHEN Chi-Lai,
Received Date: 12 January 2022
Revised Date: 21 March 2022

Fund Project: Supported by the National Natural Science Foundation of China(Nos. 61871367, 41805017), the Youth Innovation Promotion Association of Chinese Academy of Sciences(No. 2013213), the Fundamental Research Funds for the Central Universities(No. WK5290000002), and the Chinese Academy of Sciences Hefei Institute of Material Science Double Innovation Fund(No. KY-2021-SC-05).

High-field asymmetric waveform ion mobility spectrometry(FAIMS) is a fast and sensitive field detection technology, but the detection of polar substances using FAIMS is easily affected by humidity. Based on that nafion tube could selectively and quickly filter water gas, a nafion-FAIMS technology was proposed for rapid detection of environmental hydrogen sulfide(H₂S) gas under ambient humidity in this work. The self-made nafion-FAIMS device was used to study the stability of nafionFAIMS in detection of H₂S under different humidity conditions, the separation and identification ability of H₂S in the presence of typical environmental interferents, the linearity and the detection limit. The results showed that when the relative humidity was 5%-50%, the relative standard deviations(RSDs) of peak position and peak height of H₂S spectrum were less than 0.4% and 0.2%, respectively, which were 10 times and 250 times smaller than that of single FAIMS, showing high recognition and quantitative stability. When the dispersion voltage was 1200 V, the relative deviation of peak height and peak position between benzene and H₂S mixed gas spectrum and single substance were only 0.7% and 2%, indicating the adaptability of nafion-FAIMS to mixture detection. The signal linearity reached 98% in the H₂S concentration range of 0.08-0.46 mg/m³, and the detection limit was 0.04 mg/m³.
- Hydrogen sulfide,
- High-field asymmetric waveform ion mobility spectrometry,
- Humidity,
- Field detection
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