Citation: DING Yi, DIAO Quan, LIU Dong, LIU An-fei, JIAO Ming-li, ZHU Gen-xing. Synthesis of Graphene Quantum Dots and Application in Gas Sensing[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(4): 495-505. doi: 10.19756/j.issn.0253-3820.210843 shu

Synthesis of Graphene Quantum Dots and Application in Gas Sensing

DING Yi ¹ ,
DIAO Quan ^1,, ,
LIU Dong ² ,
LIU An-fei ¹ ,
JIAO Ming-li ^1,, ,
ZHU Gen-xing ¹

1.
School of Materials & Chemical Engineering, Zhongyuan University of Technology, Zhengzhou 450007, China;2 School of Agricultural Equipment Engineering, Jiangsu University, Zhenjiang 212013, China

Corresponding author: DIAO Quan, JIAO Ming-li,
Received Date: 17 November 2021
Revised Date: 20 January 2022

Fund Project: Supported by the National Natural Science Foundation of China (Nos. 61703446, 51973246)

Graphene quantum dots(GQDs), as a kind of zero-dimensional carbon nano material, not only have excellent properties of graphene, but also have quantum confinement effect and boundary effect. GQDs with different nano-size can be obtained by various preparation methods. The surface of GQDs has abundant functional groups, which can be further functionalized by compounding with other materials to meet the detection requirements of different gases and broaden its application range in gas sensing. In this review, the preparation methods of GQDs and their applications in gas sensing are introduced. In addition, the application prospect and development direction of GQDs in gas sensing are also prospected.
- Graphene quantum dots,
- Synthesis methods,
- Gas sensors,
- Review
1. [1]
  YAN Y, GONG J, CHEN J, ZENG Z, HUANG W, PU K, LIU J, CHEN P. Adv. Mater., 2019, 31(21):1808283.
2. [2]
  ABBAS A, MARIANA L T, PHAN A N. Carbon, 2018, 140:77-99.
3. [3]
  GHAFFARKHAH A, HOSSEINI E, KAMKAR M, SEHAT A A, DORDANIHAGHIGHI S, ALLAHBAKHSH A,VAN DER KUUR C, ARJMAND M. Small, 2022, 18(2):2102683.
4. [4]
  ZHENG X T, ANANTHANARAYANAN A, LUO K Q, CHEN P. Small, 2015, 11(14):1620-1636.
5. [5]
6. [6]
  CHEN W, LI F, OOI P C, YE Y, KIM T W, GUO T. Sens. Actuators, B, 2016, 222:763-768.
7. [7]
  ABBASABADI M K, ZAND H R E, KHODABAKHSHI S, GHOLAMI P, RASHIDI A. Res. Chem. Intermed.,2021, 47(6):2279-2296.
8. [8]
9. [9]
10. [10]
  MENG Q N, CUI J N, TANG Y F, HAN Z H, ZHAO K, ZHANG G J, DIAO Q. Ceram. Int., 2019, 45(3):4103-4107.
11. [11]
  DIAO Q, YIN Y N, ZHANG X M, LI J, JIAO M L, CAO J, QIN Q, YANG K, ZHU G X, XU X M. Funct. Mater.Lett., 2020, 13(3):2050013.
12. [12]
  HAO M, ZENG W, LI Y Q, WANG Z C. Rare Metals, 2021, 40(6):1494-1514.
13. [13]
  HAKIMI M, SALEHI A, BOROUMAND F A. IEEE Sens. J., 2016, 16(16):6149-6154.
14. [14]
  LU J, YANG J X, WANG J, LIM A, WANG S, LOH K P. ACS Nano, 2009, 3(8):2367-2375.
15. [15]
  PENG J, GAO W, GUPTA B K, LIU Z, ROMERO-ABURTO R, GE L, SONG L, ALEMANY L B, ZHAN X, GAO G,VITHAYATHIL S A, KAIPPARETTU B A, MARTI A A, HAYASHI T, ZHU J J, AJAYAN P M. Nano Lett., 2012,12(2):844-849.
16. [16]
  PAN D, ZHANG J, LI Z, WU M. Adv. Mater., 2010, 22(6):734-738.
17. [17]
  WONGRAT E, NUENGNIT T, PANYATHIP R, CHANLEK N, HONGSITH N, CHOOPUN S. Sens. Actuators, B,2021, 326:128983.
18. [18]
  HUANG H, YANG S, LI Q, YANG Y, WANG G, YOU X, MAO B, WANG H, MA Y, HE P, LIU Z, DING G, XIE X.Langmuir, 2018, 34(1):250-258.
19. [19]
  SU J, ZHANG X, TONG X, WANG X, YANG P, YAO F, GUO R, YUAN C. Mater. Lett., 2020, 271:127806.
20. [20]
  LU J, YEO P S, GAN C K, WU P, LOH K P. Nat. Nanotechnol., 2011, 6(4):247-252.
21. [21]
  KACIULIS S, MEZZI A, SOLTANI P, PIZZOFERRATO R, CIOTTA E, PROSPOSITO P. Thin Solid Films, 2019,673:19-25.
22. [22]
  HOANG T T, PHAM H P, TRAN Q T. J. Nanomater., 2020, 2020:1-8.
23. [23]
  TANG L, JI R, LI X, TENG K S, LAU S P. Part. Part. Syst. Char., 2013, 30(6):523-531.
24. [24]
  SHEHAB M, EBRAHIM S, SOLIMAN M. J. Lumin., 2017, 184:110-116.
25. [25]
  DONG Y Q, SHAO J W, CHEN C Q, LI H, WANG R X, CHI Y W, LIN X M, CHEN G N. Carbon, 2012, 50(12):4738-4743.
26. [26]
  WANG Z, YU J, ZHANG X, LI N, LIU B, LI Y, WANG Y, WANG W, LI Y, ZHANG L, DISSANAYAKE S, SUIB S L, SUN L. ACS Appl. Mater. Interfaces, 2016, 8(2):1434-1439.
27. [27]
  LIN Q, CHEN H, CAO J, ZHANG J. ACS Omega, 2021, 6(38):24940-24948.
28. [28]
  ABBAS A, TABISH T A, BULL S J, LIM T M, PHAN A N. Sci. Rep., 2020, 10:21262.
29. [29]
  YEH T F, HUANG W L, CHUNG C J, CHIANG I T, CHEN L C, CHANG H Y, SU W C, CHENG C, CHEN S J,TENG H. J. Phys. Chem. Lett., 2016, 7(11):2087-2092.
30. [30]
  YE R, PENG Z, METZGER A, LIN J, MANN J A, HUANG K, XIANG C, FAN X, SAMUEL E L G, ALEMANY L B, MART A A, TOUR J M. ACS Appl. Mater. Interfaces, 2015, 7(12):7041-7048.
31. [31]
  KWON W, KIM Y H, LEE C L, LEE M, CHOI H C, LEE T W, RHEE S W. Nano Lett., 2014, 14(3):1306-1311.
32. [32]
33. [33]
  MENG F L, SHI X, YUAN Z Y, JI H Y, QIN W B, SHEN Y B, XING C Y. Sens. Actuators, B, 2022, 350:130867.
34. [34]
  LV Y K, LI Y Y, YAO H C, LI Z J. Sens. Actuators, B, 2021, 339:129882.
35. [35]
  HAKIMI M, SALEHI A, BOROUMAND F A, MOSLEH N. IEEE Sens. J., 2018, 18(6):2245-2252.
36. [36]
  PARVIZI R, AZAD S, DASHTIAN K, GHAEDI M, HEIDARI H. Sci. Rep., 2019, 9:3798.
37. [37]
  RAHIMI K, YAZDANI A. Mater. Lett., 2018, 228(OCT.1):65-67.
38. [38]
  ZHANG Y M, ZHAO J H, SUN H L, ZHU Z Q, ZHANG J, LIU Q J. Sens. Actuators, B, 2018, 266:364-374.
39. [39]
  LIU W, ZHOU X, XU L, ZHU S, YANG S, CHEN X, DONG B, BAI X, LU G, SONG H. Nanoscale, 2019, 11(24):11496-11504.
40. [40]
  ARUNRAGSA S, SEEKAEW Y, PON-ON W, WONGCHOOSUK C. Diamond Relat. Mater., 2020, 105:107790.
41. [41]
  BAI H, SHI G. Sensors, 2007, 7(3):267-307.
42. [42]
  GAVGANI J N, HASANI A, NOURI M, MAHYARI M, SALEHI A. Sens. Actuators, B, 2016, 229:239-248.
43. [43]
  LV Y K, LI Y Y, ZHOU R H, PAN Y P, YAO H C, LI Z J. ACS Appl. Mater. Interfaces, 2020, 12(30):34245-34253.
44. [44]
  ZHANG Y H, WANG C N, YUE L J, CHEN J L, GONG F L, FANG S M. Phys. E(Amsterdam, Neth.), 2021, 133:114807.
45. [45]
  CHEN Z, WANG D, WANG X, YANG J. Chin. Chem. Lett., 2020, 31(8):2063-2066.
46. [46]
  SHAO S F, KIM H W, KIM S S, CHEN Y Y, LAI M. Appl. Surf. Sci., 2020, 516:145932.
47. [47]
  CHU X F, DAI P, DONG Y P, SUN W Q, BAI L S, ZHANG W B. J. Mater. Sci.:Mater. Electron., 2017, 28(24):19164-19173.
48. [48]
  RAEYANI D, SHOJAEI S, AHMADI-KANDJANI S. Superlattices Microstruct., 2018, 114:321-330.
49. [49]
  RAEYANI D, SHOJAEI S, AHMADI-KANDJANI S. Mater. Res. Express, 2020, 7(1):015608.
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