Citation: LI Yu-Wen, ZHAO Zhu-Yu, CAO Fang, ZHOU Yu-Chen, ZHOU Wei-Jing, YANG Xiao-Ying, YU Hao-Ran, ZHANG Yan-Lin. Passive Sampling of Atmospheric Ozone and Determination of Δ¹⁷O[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(5): 801-809. doi: 10.19756/j.issn.0253-3820.210798 shu

Passive Sampling of Atmospheric Ozone and Determination of Δ¹⁷O

LI Yu-Wen ^1,2 ,
ZHAO Zhu-Yu ^1,2 ,
CAO Fang ^1,2,, ,
ZHOU Yu-Chen ^1,2 ,
ZHOU Wei-Jing ^1,2 ,
YANG Xiao-Ying ^1,2 ,
YU Hao-Ran ^1,2 ,
ZHANG Yan-Lin ^1,2,,

1.
School of Applied Meteorology, Nanjing University of Information Science and Technology, Nanjing 210044, China;
2.
Atmospheric Environment Center, Joint Laboratory for International Cooperation on Climate and Environmental Change, Ministry of Education, Nanjing University of Information Science and Technology. Nanjing 210044, China

Corresponding author: CAO Fang, ZHANG Yan-Lin,
Received Date: 19 October 2021
Revised Date: 15 January 2022

Fund Project: Supported by the National Natural Science Foundation of China (Nos.41977305, 41977185), the Jiangsu Innovation & Entrepreneurship Team (2018), the Provincial Natural Science Foundation of Jiangsu Province, China (No.812 BK20180040) and the "333 Talent Project" of Jiangsu Province, China (No.RRA2020068).

As an air pollutant, tropospheric ozone (O₃) is also a precursor of atmospheric nitrate. Its oxygen isotope abnormal (Δ¹⁷O) can be used to trace atmospheric nitrate and other atmospheric chemical processes.This research was based on the passive sampling method, and the O₃ in the atmosphere was collected using a passive sampler coated with nitrite. The sampling period was one week. The atmospheric O₃ was converted into nitrate on the adsorption filter membrane, the remaining nitrite was removed by adding a certain concentration of sulfamic acid, and then the corresponding concentration of sodium hydroxide was added to neutralize the pH of the solution. Nitrate was converted into N₂O by the denitrifying bacteria method, and the produced N₂O entered the gold tube at 800℃ to be pyrolyzed into N₂ and O₂. The δ¹⁸O and δ¹⁷O values of oxygen were measured and converted to Δ¹⁷O (Δ¹⁷O=δ¹⁷O-0.52δ¹⁸O). With the help of international samples with known Δ¹⁷O values (USGS34 and USGS35), a Δ¹⁷O standard curve was established to convert the Δ¹⁷O of real nitrates, and finally converted to the value of Δ¹⁷O in atmospheric ozone. The research results showed that adding 0.5 mL of sulfamic acid (1 mol/L) to the reaction and shaking for 15 min could completely remove nitrite without affecting the isotope value of nitrate. The use of 99.999% sodium nitrite could better reduce the blank effect caused by nitrate in the drug, thereby reducing the impact on the isotope value. The content of nitrate generated by O₃ conversion should be higher than 6 μg of NO₃-N, and the standard deviation of Δ¹⁷O measured at this time was 0.29‰ (n=3). This method was used to analyze the passively collected O₃ samples in Nanjing spring, and the Δ¹⁷O value of O₃was 26.59‰±1.41‰, which was consistent with the actively collected value and similar to previous research results. Passive sampling method had many advantages such as low price, good portability and low energy consumption. Its isotope value measurement results showed that the passive sampling was a highly feasible sampling method and could be used in the study of atmospheric O₃ oxygen isotope abnormal values.
- Atmospheric ozone,
- Passive sampling,
- Nitrate,
- Abnormal values of oxygen isotope
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沈阳化工大学材料科学与工程学院沈阳 110142

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Passive Sampling of Atmospheric Ozone and Determination of Δ¹⁷O