Citation: ZHOU Jian-Hong, LIU Zhang, LING Yu-Lin, ZENG Bo-Ping, ZHANG Heng, DENG Ke-Qin. Bismuth Oxyiodide-Bismuth Hybridized with Short Carbon Nanotubes as Cathode Photoelectrochemical Sensing Platform for Determination of Chlorpyrifos[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(2): 253-262. doi: 10.19756/j.issn.0253-3820.210758 shu

Bismuth Oxyiodide-Bismuth Hybridized with Short Carbon Nanotubes as Cathode Photoelectrochemical Sensing Platform for Determination of Chlorpyrifos

1.
College of Biological and Agricultural Science and Technology, Zunyi Normal University, Zunyi 563006, China;
2.
School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China;
3.
College of Resources and Environment, Zunyi Normal University, Zunyi 563006, China

Corresponding author: ZHOU Jian-Hong, DENG Ke-Qin,
Received Date: 22 September 2021
Revised Date: 17 December 2021

Fund Project: Supported by the Rural Revitalization Project Launched in 2021 (Nos.Qian-Jiao-He KY-Zi [2012]017-18, [2012]017-10), the Doctor Introduction Fund Project of Zunyi Normal University (Nos.ZunshiBS[2020] 02, Zunshi BS[2021] 07) and the Talent Base for Environmental Protection and Mountain Agricultural in Chishui River Basin

A bismuth oxyiodide-bismuth/short carbon nanotube (BiOI-Bi/s-CNTs) composite was prepared by hybridization of short carbon nanotubes (s-CNTs) with bismuth oxyiodide-bismuth (BiOI-Bi). The morphological analysis by scanning electron microscopy (SEM) showed that the prepared BiOI-Bi/s-CNTs consisted of s-CNTs loaded with nanoparticles and a large number of microspheres.Besides, the transient photocurrent displayed that the BiOI-Bi/s-CNTs had excellent photoelectrochemical performance. Thus, a novel cathodic photoelectrochemical method was developed for detection of chlorpyrifos (CPF) with BiOI-Bi/s-CNTs as photocathode and K₃[Fe(CN)₆] as photoelectron acceptor on the basis of that CPF chelated on the cathode surface and quenched the photocurrent signal. The CPF concentration in the range of 4.0 pg/mL-10.0 ng/mL was positively correlated with the quenched photocurrent, and the detection limit was estimated to be 1.89 pg/mL. The recoveries of CPF in real cabbage and Chinese cabbage were 90.0%-108.0%. This work provided a more specific and sensitive method for determination of CPF.
- Short carbon nanotubes,
- Bismuth oxyiodide,
- Photocathode,
- Photoelectron acceptor,
- Chlorpyrifos
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