Citation: WANG Qiang-Ming, JIANG Cheng, ZHAO Ji-Hua, FANG Jian. Preparation of Prussian Blue Analogues-derived SnCoO_x Hollow Nanocubes and Study on Performance of Electrochemical Detection of Clozapin[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(3): 392-404. doi: 10.19756/j.issn.0253-3820.210608 shu

Preparation of Prussian Blue Analogues-derived SnCoO_x Hollow Nanocubes and Study on Performance of Electrochemical Detection of Clozapin

College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: ZHAO Ji-Hua, FANG Jian,
Received Date: 5 July 2021
Revised Date: 29 December 2021

Fund Project: Supported by the National Natural Science Foundation of China (Nos.21773097, 21403098).

Cobalt oxide, as a transition metal oxide, is widely used in the field of electrochemical sensors and electrocatalysis due to its unique properties. Moreover, metal doping is the main methods to improve the electrochemical performance of electrochemical sensors. In this work, hollow porous SnCoO_x nanocubes were prepared by pyrolysis of Sn-doped CoCo-Prussian blue analogues (PBA), and then SnCoO_x/graphite felt (GF) composite electrode was prepared by fixing SnCoO_x on GF ultrasonically. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), transmission electron microscope (TEM) and electrochemical method were applied to characterize the structure, morphology and electrochemical performance of electrode materials. The composite electrode exhibited excellent electrocatalytic activity for detection of clozapine (CLZ). The electrocatalytic rate constant was k_cat=1.04×10⁵L/(mol·s), the linear detection range was 0.01-100 μmol/L, the sensitivity was 6.02 (A·L)/mol, and the limit of detection (LOD, S/N=3) was 0.7 nmol/L. The SnCoO_x/GF electrode as an electrochemical sensor for detecting CLZ had perfect anti-interference property, strong stability and practicality, which provided a feasible method for electrochemical detection of CLZ.
- CoCo-Prussian blue analogues,
- Pyrolysis,
- Metal oxide,
- Electrochemical detection
1. [1]
  CARTER C J. Schizophr. Res., 2006, 86(1-13):1-14.
2. [2]
  MASHHADIZADEH M H, AFSHAR E. Electrochim. Acta, 2013, 87(9):816-823.
3. [3]
  STARK A, SCOTT J. Aust. NZ. J. Psychiat., 2012, 46(9):816-825.
4. [4]
  KANE J, HONIGFELD G, SINGER J, MELTZER H. Arch. Gen. Psychiatry, 1988, 45(9):789-796.
5. [5]
  VARDAKOU I, DONA A, PISTOS C, ALEVISOPOULOS G, ATHANASELIS S, MARAVELIAS C, SPILIOPOULOU C. J. Chromatogr. B:Anal. Technol. Biomed. Life Sci., 2010, 878(25):2327-2332.
6. [6]
  CHOONG E, RUDAZ S, KOTTELAT A, GUILLARME D, VEUTHEY J L, EAP C B. J. Pharm. Biomed. Anal., 2009, 50(5):1000-1008.
7. [7]
  WASCHGLER R, HUBMANN M, CONCA U P, MOLL W, KÖNIG P. Int. J. Clin. Pharmacol. Ther., 2002, 40(12):554-559.
8. [8]
  MERCOLINI L, BUGAMELLI F, KENNDLER E, BONCOMPAGNI G, FRANCHINI L, RAGGI M A. J. Chromatogr. B:Anal. Technol. Biomed. Life Sci., 2007, 846(1):273-280.
9. [9]
  JIN W, XU Q, LI W. Electrophoresis, 2000, 21(7):1415-1420.
10. [10]
  TAHA E A, SOLIMAN S M, ABDELLATEF H E, AYAD M M. Microchim. Acta, 2002, 140(3-4):175-182.
11. [11]
  SHUKLA R P, BEN-YOAV H. ADV. Healthcare Mater., 2019, 8(15):1900462.
12. [12]
  HERNÁNDEZ L, GONZÁLEZ E, HERNÁNDEZ P. Analyst, 1988, 113(11):1715-1718.
13. [13]
  FARHADI K, KARIMPOUR A. Anal. Sci., 2007, 23(4):479-483.
14. [14]
  MANJUNATHA J G, SWAMY B E K, MAMATHA G P, GILBERT O, SHERIGARA B S. Der Pharma Chem., 2011, 3(2):236-249.
15. [15]
  ATTASA S A. Int. J. Electrochem. Sci., 2009, 4(1):20-29.
16. [16]
  ZHAO Y, CHEN S, SUN B, SU D, HUANG X, LIU H, YAN Y, SUN K, WANG G. Sci. Rep., 2015, 5:7629.
17. [17]
  SALIMI A, HALLAJ R. J. Solid State Electrochem., 2012, 16(3):1239-1246.
18. [18]
  LI X, LIU L, DONG X, ZHAO G, LI Y, MIAO J, FANG J, CUI M, WEI Q, CAO W. Biosens. Bioelectron., 2019, 126(11):448-454.
19. [19]
  WANG Y G, ZHAO G H, LI X J, LIU L, CAO W, WEI Q. Biosens. Bioelectron., 2018, 101:290-296.
20. [20]
  DONG X, ZHAO G, LIU L, LI X, WEI Q, CAO W. Biosens.Bioelectron., 2018, 110:201-206.
21. [21]
  YANG J, LIU H, MARTENS W N, FROST R L. J. Phys. Chem. C, 2010, 114(1):111-119.
22. [22]
  SALIMI A, MAMKHEZRI H, HALLAJ R, SOLTANIAN S. Sens. Actuators, B, 2008, 129(1):246-254.
23. [23]
  YAN N, HU L, LI Y, WANG Y, ZHONG H, HU X, CHEN Q. J. Phys. Chem. C, 2012, 116(12):7227-7235.
24. [24]
  XU J, LI F, WANG D, NAWAZ M H, AN Q, HAN D, NIU L. Biosens. Bioelectron., 2019, 123:25-29.
25. [25]
  LU Z, ZHONG J, ZHANG Y, SUN M, ZOU P, DU H, WANG X, RAO H, WANG Y. J. Alloys Compd., 2020, 858(20):1016-1027.
26. [26]
  LI X N, YUAN L Z, WANG J H, JIANG L H, RYKOV A I, NAGY D L, BOGDAN C, AHMED M A, ZHU K Y, SUN G Q, YANG W S. Nanoscale, 2016, 8(4):2333-2342.
27. [27]
  WANG Q, ZHAO J, TRICARD S, FANG J. J. Alloys Compd., 2021, 860:158176.
28. [28]
  ROUQUEROL F, ROUQUEROL J, SING K. Chemical Thermodynamics, Academic Press, 1999:77-84.
29. [29]
  KRUK M, JARONIEC M. Chem. Mater., 2001, 13(10):3169-3183.
30. [30]
  PARK M, KOMARNENI S. Microporous Mesoporous Mater., 1998, 25(1):75-80.
31. [31]
  BRUNAUER S, EMMETT P H,TELLER E. J. Am. Chem. Soc., 1938, 60(2):309-319.
32. [32]
  CHEN W, GHOSH D, CHEN S. J. Mater. Sci., 2008, 43(15):5291-5299.
33. [33]
  ABED M, GHASEMI B, OVEISI H, HABIBOLAHZADEH A, ZIRAK M. Mater. Sci. Eng. C, 2021, 264(1):114926-114935.
34. [34]
  MORETTI G, GERVAIS C. J. Raman Spectrosc., 2017, 49(7):1198-1204.
35. [35]
  JIANG X, ZHANG L, WANG T, WAN Q. J. Appl. Phys., 2009, 106(10):104316.
36. [36]
  ZHAO S, LI C, LIU J, LIU N, QIAO S, HAN Y, HUANG H, LIU Y, KANG Z. Carbon, 2015, 92(3):64-73.
37. [37]
  DEVI R K, MUTHUSANKAR G, GOPU G, BERCHMANS L. Colloids Surf., A, 2020, 598:124825.
38. [38]
  XUN S, XU Y, HE J, JIANG D, YANG R, LI D, CHEN M. J. Alloys Compd., 2019, 806(7):1097-1104.
39. [39]
  GUO L, CHEN F, XIE N, WANG C, KOU X, SUN Y, MA J, LIANG X, GAO Y, LU G. J. Colloid Interface Sci., 2018, 528(5):53-62.
40. [40]
  SUPRAJA P, TRIPATHY S, VANJARI S R K, SINGH V, SINGH S G. Biosens. Bioelectron., 2019, 141:111441.
41. [41]
  LV Y K, LI Y Y, ZHOU R H, PAN Y P, YAO H C, LI Z J. ACS Appl. Mater. Interfaces, 2020, 12(30):34245-34253.
42. [42]
  TAMMARI E, NEZHADALI A, LOTFI S, VEISI H. Sens. Actuators, B, 2017, 241(11):879-886.
43. [43]
  LU Z, ZHONG J, ZHANG Y, SUN M, ZOU P, DU H, WANG X, RAO H, WANG Y. J. Alloys Compd., 2021, 858(20):1016-1027.
44. [44]
  WANG L, MENG T, FAN Y, CHEN C, GUO Z, WANG H, ZHANG Y. J. Colloid Interface Sci., 2018, 524(4):1-7.
45. [45]
  SHUKLA R P, CAZELLES R, KELLY D L, BEN-YOAV H. Talanta, 2020, 209:120560.
46. [46]
  SHAHROKHIAN S, KAMALZADEH Z, HAMZEHLOEI A. Bioelectrochemistry, 2013, 90(10):36-43.
47. [47]
  QU S, PEI S, ZHANG S, SONG P. Mater. Lett., 2013, 102(3):56-58.
48. [48]
  CHEN Y, WANG Z, LIU S, ZHAO G. J. Hazard. Mater., 2021, 412:125174.
49. [49]
  LIU S, CHEN Y, WANG Y, ZHAO G. Anal. Chem., 2019, 91(12):7639-7647.
1. [1]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
2. [2]
  Yuanyuan JIANG , Fangfang TU , Yuhong ZHANG , Shi CHEN , Jiayuan XIANG , Xinhui XIA . Preparation and electrochemical properties of high-stability cathode prelithiation additive. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1101-1111. doi: 10.11862/CJIC.20240441
3. [3]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-0. doi: 10.3866/PKU.WHXB202407005
4. [4]
  Shijie Ren , Mingze Gao , Rui-Ting Gao , Lei Wang . Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(7): 2307040-0. doi: 10.3866/PKU.WHXB202307040
5. [5]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
6. [6]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . Performance and Electrochemical Asymmetry Optimization of Hydrogen Electrode Supported Reversible Solid Oxide Cell. Acta Physico-Chimica Sinica, 2025, 41(1): 100005-0. doi: 10.3866/PKU.WHXB202309037
7. [7]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
8. [8]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
9. [9]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . Rational Design of Bimetallic Oxide Anodes for Superior Li⁺ Storage. Acta Physico-Chimica Sinica, 2025, 41(3): 100021-0. doi: 10.3866/PKU.WHXB202311005
10. [10]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
11. [11]
  Ye Wang , Ruixiang Ge , Xiang Liu , Jing Li , Haohong Duan . An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol. Acta Physico-Chimica Sinica, 2024, 40(7): 2307019-0. doi: 10.3866/PKU.WHXB202307019
12. [12]
  Yongjian Zhang , Fangling Gao , Hong Yan , Keyin Ye . Electrochemical Transformation of Organosulfur Compounds. University Chemistry, 2025, 40(5): 311-317. doi: 10.12461/PKU.DXHX202407035
13. [13]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
14. [14]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
15. [15]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
16. [16]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
17. [17]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
18. [18]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO₂ Methanation of Derived Ni-Al₂O₃ Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002
19. [19]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
20. [20]
  Rongzhan LOU , Qiaoling KANG , Zhenchao BAI , Dongyun LI , Yang XU , Rui WANG , Qingyi LU . Research progress of sodium ion high entropy layered oxide cathode. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2411-2428. doi: 10.11862/CJIC.20250142

Get Citation

PDF

XML

Metrics

PDF Downloads(17)
Abstract views(1499)
HTML views(294)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Prussian Blue Analogues-derived SnCoOx Hollow Nanocubes and Study on Performance of Electrochemical Detection of Clozapin

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of Prussian Blue Analogues-derived SnCoO_x Hollow Nanocubes and Study on Performance of Electrochemical Detection of Clozapin