Citation: WANG Qiang-Ming, JIANG Cheng, ZHAO Ji-Hua, FANG Jian. Preparation of Prussian Blue Analogues-derived SnCoO_x Hollow Nanocubes and Study on Performance of Electrochemical Detection of Clozapin[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(3): 392-404. doi: 10.19756/j.issn.0253-3820.210608 shu

Preparation of Prussian Blue Analogues-derived SnCoO_x Hollow Nanocubes and Study on Performance of Electrochemical Detection of Clozapin

College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: ZHAO Ji-Hua, FANG Jian,
Received Date: 5 July 2021
Revised Date: 29 December 2021

Fund Project: Supported by the National Natural Science Foundation of China (Nos.21773097, 21403098).

Cobalt oxide, as a transition metal oxide, is widely used in the field of electrochemical sensors and electrocatalysis due to its unique properties. Moreover, metal doping is the main methods to improve the electrochemical performance of electrochemical sensors. In this work, hollow porous SnCoO_x nanocubes were prepared by pyrolysis of Sn-doped CoCo-Prussian blue analogues (PBA), and then SnCoO_x/graphite felt (GF) composite electrode was prepared by fixing SnCoO_x on GF ultrasonically. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), transmission electron microscope (TEM) and electrochemical method were applied to characterize the structure, morphology and electrochemical performance of electrode materials. The composite electrode exhibited excellent electrocatalytic activity for detection of clozapine (CLZ). The electrocatalytic rate constant was k_cat=1.04×10⁵L/(mol·s), the linear detection range was 0.01-100 μmol/L, the sensitivity was 6.02 (A·L)/mol, and the limit of detection (LOD, S/N=3) was 0.7 nmol/L. The SnCoO_x/GF electrode as an electrochemical sensor for detecting CLZ had perfect anti-interference property, strong stability and practicality, which provided a feasible method for electrochemical detection of CLZ.
- CoCo-Prussian blue analogues,
- Pyrolysis,
- Metal oxide,
- Electrochemical detection
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Prussian Blue Analogues-derived SnCoOx Hollow Nanocubes and Study on Performance of Electrochemical Detection of Clozapin

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通讯作者: 陈斌, bchen63@163.com

Preparation of Prussian Blue Analogues-derived SnCoO_x Hollow Nanocubes and Study on Performance of Electrochemical Detection of Clozapin