Citation: PENG Can-Wei, WANG Li, CHEN Shou-Hui. Two-dimensional Lamellar Porphyrin-based Covalent-Organic Framework Modified Electrode for Highly Sensitive Detection of Mercury Ions in Sewage[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(3): 356-364. doi: 10.19756/j.issn.0253-3820.210582 shu

Two-dimensional Lamellar Porphyrin-based Covalent-Organic Framework Modified Electrode for Highly Sensitive Detection of Mercury Ions in Sewage

College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China

Corresponding author: CHEN Shou-Hui, csh2k@jxnu.edu.cn
Received Date: 23 June 2021
Revised Date: 29 October 2021

Fund Project: Supported by the National Natural Science Foundation of China (Nos.21765009, 21964010, 21465014, 21665012) and the Postgraduate Innovation Fund Project of Jiangxi Provincial Department of Education.

A two-dimensional porphyrin-based covalent-organic framework (TAPP-TPAL-COF) was prepared by the amine-aldehyde condensation reaction of terephthalaldehyde (TPAL) and 5,10,15,20-tetrakis (4-aminobenzene) porphyrin (TAPP). TAPP-TPAL-COF was porous two-dimensional nanosheets with quadrilateral topological structure and planar conjugated π bonds. The material had π-π conjugate interaction with the glassy carbon electrode, making the material stably immobilized on the surface of the electrode. The porous structure of TAPP-TPAL-COF was conducive to the transmission of mercury ions (Hg²⁺), and the four N atoms in the porphyrin ring served as Hg²⁺ coordination sites to enrich Hg²⁺ in the solution on the electrode surface, improving the sensitivity of the sensor. An Hg²⁺ electrochemical sensor was thus constructed via TAPP-TPAL-COF. The linear range of the sensor was 10.9 nmol/L-17.5 μmol/L, the limit of detection was 3.3 nmol/L (S/N=3), and the sensitivity was 111.5 μA·L/(μmol·cm²). It took only 250 s to get the current response signals. The sensor presented good stability, high sensitivity, wide linear range, low detection limit and fast response, providing an optional solution for real-time detection of heavy metal ions in water samples.
- Mercury ion（Ⅱ）,
- Covalent-organic framework,
- Two-dimensional lamellar porphyrin,
- Electrochemical sensor,
- Differential pulse stripping voltammetry,
- Sewage analysis
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