Citation: FAN Jia-Min, GONG Qiao-Juan, GONG Peng-Ni, ZHAO Xiao-Yan. Preparation and Properties of CoNi₂S₄ for Supercapacitor Electrode Material[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(1): 119-126. doi: 10.19756/j.issn.0253-3820.210524 shu

Preparation and Properties of CoNi₂S₄ for Supercapacitor Electrode Material

1.
College of Chemistry and Materials Science, Shanxi Normal University, Linfen 041000, China;
2.
Department of Applied Chemistry, Yuncheng University, Yuncheng 044000, China

Corresponding author: GONG Qiao-Juan, gqjuan@163.com
Received Date: 25 May 2021
Revised Date: 11 October 2021

Fund Project: Supported by the Key Research and Development Program of Shanxi Province, China (No.201803D121030).

As a new type of energy storage device, supercapacitors have been extensively studied due to their advantages such as high power density and long cycle life. Metal sulfide materials are often used as electrode materials for supercapacitors due to their high conductivity and good electrochemical performance. In this study, a one-step solvothermal method was used to prepare a CoNi₂S₄ material similar to the surface of broccoli with ethylene glycol as the solvent. The material had a synergistic effect of multiple ions during the Faraday redox reaction. The three-electrode test results showed that the material had good cycle stability and excellent charge and discharge performance. The specific capacitance was 2537 F/g at a current density of 1 A/g, and the specific capacitance retention rate was 88.2% after 5000 cycles. Compared with CoS, it had larger specific capacitance, specific surface area and better electrochemical performance. The assembled CoNi₂S₄//AC asymmetric supercapacitor had an energy density of 52.3 W/kg at a power density of 375 Wh/kg and a specific capacitance retention rate of 75.8% after 5000 cycles. The prepared CoNi₂S₄ was an excellent electrode material for supercapacitors.
- Cobalt nickel tetrasulfide,
- Cobalt sulfide,
- Supercapacitor,
- Electrode material
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Preparation and Properties of CoNi₂S₄ for Supercapacitor Electrode Material