Citation: CHENG Ya-Di, GAO Jian-Xiong, WANG Huan-Lei, HUANG Ming-Hua. Structure Analysis of Perovskite Oxides and Research Progress on Their Electrocatalytic Hydrogen Evolution Reaction[J]. Chinese Journal of Analytical Chemistry, ;2021, 49(6): 952-962. doi: 10.19756/j.issn.0253-3820.210452 shu

Structure Analysis of Perovskite Oxides and Research Progress on Their Electrocatalytic Hydrogen Evolution Reaction

1.
School of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China;
2.
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, China

Corresponding author: HUANG Ming-Hua, huangminghua@ouc.edu.cn
Received Date: 21 April 2021
Revised Date: 14 May 2021

Fund Project: Supported by the National Natural Science Foundation of China (No.21775142) and the QIBEBT and Dalian National Laboratory for Clean Energy, CAS (No.DICP&QIBEBT UN201809).

Electrochemical water splitting, a highly-efficient and environment-friendly technology has been considered as one of the most promising methods for hydrogen production. However, a large overpotential is generally required to achieve the current density for industrial water electrolysis. As a result, it is highly desirable to develop high-performance and cost-effective hydrogen evolution reaction (HER) electrocatalysts for the widespread application of water splitting. Perovskite oxides have emerged as a new category of nonprecious metal catalysts for electrocatalytic HER due to their low cost, abundant compositions and flexible structures. In this review, the HER mechanism in alkaline environment is briefly elaborated. Then, the research progress of perovskite oxides in HER is reviewed. Moreover, the strategies (ion doping, heterostructure engineering, morphology and structure regulation, etc.) for promoting HER performance are discussed and analyzed. Finally, the remaining challenges faced by perovskite HER electrocatalysts and the future prospects are put forward.
- Perovskite oxides,
- Electrocatalyst,
- Hydrogen evolution reaction,
- Alkaline medium,
- Review
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1.
沈阳化工大学材料科学与工程学院沈阳 110142