Citation: WANG Hong, SU Xing-Song, ZHOU Fei, DUAN Guo-Tao. Preparation of Zinc Oxide Monolayer Porous Hollow Sphere Array and Its Ultra-Fast Response to NO₂ at Room Temperature under Ultraviolet Irradiation[J]. Chinese Journal of Analytical Chemistry, ;2022, 50(7): 1112-1121. doi: 10.19756/j.issn.0253-3820.201607 shu

Preparation of Zinc Oxide Monolayer Porous Hollow Sphere Array and Its Ultra-Fast Response to NO₂ at Room Temperature under Ultraviolet Irradiation

WANG Hong ^1,2,3 ,
SU Xing-Song ² ,
ZHOU Fei ² ,
DUAN Guo-Tao ^1,,

1.
Wuhan National Laboratory for Optoelectronics, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, China;
2.
CAS Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China;
3.
University of Science and Technology of China, Hefei 230026, China

Corresponding author: DUAN Guo-Tao, duangt@hust.edu.cn
Received Date: 16 October 2020
Revised Date: 25 January 2021

Fund Project: Supported by the National Key R&D Program of China (No.2020YFB2008701) and the National Natural Science Foundation of China (No.11674320).

By using monolayer polystyrene colloidal spheres as the template, ZnO array-film was in-situ synthesized on the plate electrodes for gas sensors by template-assisted hydrothermal method. Scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM) characterization results showed that the film was composed of ordered monolayer porous hollow spheres with pore size of about 4 nm. The gas-sensing performances of the prepared thin-film gas sensor were investigated. Under UV irradiation with a low optical radiation power (1.7 mW/cm²), the thin-film gas sensor based on ZnO monolayer hollow sphere array showed excellent NO₂-sensing performances with a detection limit of 0.098 mg/m³, and the sensing response toward 2.45 mg/m³ NO₂ gas could reach 5.7 with an ultra-fast response/recovery speed (3 s/5 s). With the finite difference time domain method, the local field intensity of the monolayer hollow sphere array-film was investigated, and it was found that the second-level response/recovery mechanism might be due to the relatively uniform local field intensity distribution of the monolayer hollow sphere array film.
- Zinc oxide,
- Monolayer,
- Hollow sphere array,
- Nitrogen dioxide,
- Ultra-fast response
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Zinc Oxide Monolayer Porous Hollow Sphere Array and Its Ultra-Fast Response to NO2 at Room Temperature under Ultraviolet Irradiation

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通讯作者: 陈斌, bchen63@163.com

Preparation of Zinc Oxide Monolayer Porous Hollow Sphere Array and Its Ultra-Fast Response to NO₂ at Room Temperature under Ultraviolet Irradiation