Citation: CHEN Ying-Nan, CUI Jing-Song, LIU En-Hong, LIU Ao-Xue, HAN Ce, YANG Guo-Cheng. Electrochemical Performance Analysis of Heteroatom Modified Porous Iron, Cobalt-Nitrogen-Carbon Based Electrocatalyst toward Oxygen Reduction Reaction[J]. Chinese Journal of Analytical Chemistry, ;2020, 48(11): 1519-1525. doi: 10.19756/j.issn.0253-3820.201452 shu

Electrochemical Performance Analysis of Heteroatom Modified Porous Iron, Cobalt-Nitrogen-Carbon Based Electrocatalyst toward Oxygen Reduction Reaction

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School of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, China;
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Department of Chemistry and Applied Chemistry, Changji University, Changji 831100, China

Corresponding author: CHEN Ying-Nan, HAN Ce,
Received Date: 31 July 2020
Revised Date: 31 August 2020

Fund Project: This work was supported by the Educational Department of Jilin Province of China (No. JJKH20200651KJ).

The drawback of commercial Pt-based electrocatalysts, such as poor stability and high cost, is one of the major issues which limits the promotion of fuel cells and related green energy application. Therefore, developing the inexpensive alternative electrocatalysts for high-performance and stable oxygen reduction reaction (ORR) has become a research hotspot in the field of electrocatalysis. Herein, a series of heteroatom modified porous iron, cobalt-nitrogen-carbon based electrocatalysts were successfully fabricated by modifying the FeCo/NC by additional introduction of heteroatoms (B, P and F) in this work. The mechanism of ORR performance boosted by introduction of B, P and F was explored by combining well characterization of composition and morphology with rational electrochemical tests. The as-fabricated FeCo/NFC sample exhibited highly efficient ORR activity with the half-wave potential of 0.84 V, electron transfer number of 3.85 and HO₂^- yield of 7.61% at 0.5 V, which was comparable to those of commercial Pt/C. Meanwhile, the FeCo/NFC also displayed outstanding stability and methanol tolerance in alkaline electrolyte which demonstrated excellent application potential in the field of fuel cells as an alternative electrocatalyst for commercial Pt/C.
- Heteroatom modified,
- Transition metal-nitrogen-carbon,
- Oxygen reduction reaction,
- Electrocatalyst
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
1. [1]
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2. [2]
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3. [3]
  Xichen YAO , Shuxian WANG , Yun WANG , Cheng WANG , Chuang ZHANG . Oxygen reduction performance of self?supported Fe/N/C three-dimensional aerogel catalyst layers. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1387-1396. doi: 10.11862/CJIC.20240384
4. [4]
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5. [5]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
6. [6]
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7. [7]
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8. [8]
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9. [9]
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10. [10]
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11. [11]
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12. [12]
  Pengzi Wang , Wenjing Xiao , Jiarong Chen . Copper-Catalyzed C―O Bond Formation by Kharasch-Sosnovsky-Type Reaction. University Chemistry, 2025, 40(4): 239-244. doi: 10.12461/PKU.DXHX202406090
13. [13]
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14. [14]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
15. [15]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-0. doi: 10.1016/j.actphy.2025.100067
16. [16]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
17. [17]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
18. [18]
  Lele Feng , Xueying Bai , Jifeng Pang , Hongchen Cao , Xiaoyan Liu , Wenhao Luo , Xiaofeng Yang , Pengfei Wu , Mingyuan Zheng . Single-atom Pd boosted Cu catalysts for ethanol dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(9): 100100-. doi: 10.1016/j.actphy.2025.100100
19. [19]
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沈阳化工大学材料科学与工程学院沈阳 110142