Citation: WANG Hong-Liang, ZHAO Yue-Xia, YANG Lei, WU Jun-Fei, LI Jin-Song. Development of An In-Situ Analyzer for Rapid Measurement of Dissolved Iron, Manganese and Sulfide in Deep Sea[J]. Chinese Journal of Analytical Chemistry, ;2021, 49(12): 1977-1985. doi: 10.19756/j.issn.0253-3820.201379 shu

Development of An In-Situ Analyzer for Rapid Measurement of Dissolved Iron, Manganese and Sulfide in Deep Sea

1.
National Deep Sea Center, Qingdao 266237, China;
2.
School of Electrical and Mechanical Engineering, Qingdao University of Science and Technology, Qingdao 266061, China;
3.
School of Physics and Materials Science, Anhui University, Hefei 230601, China

Corresponding author: ZHAO Yue-Xia, zyx@ndsc.org.cn
Received Date: 17 July 2020
Revised Date: 21 June 2021

Fund Project: Supported by the National Key R&D Program of China (Nos.2016YFC0302201, 2016YFC0302204) and the National Natural Science Foundation of China (No.41306103).

Deep-sea in-situ chemical analyzer can obtain data with high frequency, which is very useful for scientific research and necessary for deep-sea transportation equipment. In this work, an in-situ analyzer was developed for automated determination of dissolved Fe, Fe, Mn and sulfide simultaneously in deep sea based on continuous flow analysis and spectrophotometric detection. The integrated system consisted of a pressure-resistant housing an oil-filled pressure-compensated vessel, and a self-developed hardware to control two multi-channel peristaltic pumps, four solenoid valves and a photoelectric acquisition module. Experimental conditions related to the analysis, including flow path module, spectrometric regent compositions and pH of buffer solution were evaluated and optimized. This deep-sea in-situ chemical analyzer was designed to work at the depth of 7000 m with a measuring frequency of 1 Hz, and showed a limit of detection as low as 0.013, 0.024, 0.014, and 0.012 μmol/L for dissolved Fe, Fe, Mn and sulfide, respectively. The calibration curves prepared in standard solutions were consistent over the linear range of 0.1-60, 0.2-100, 0.1-40 and 0.1-40 μmol/L for dissolved Fe, Fe, Mn and sulfide, respectively. After the test of shallow sea, hydrostatic pressure and tank test, this analyzer was implemented on tool shed of Jiaolong deep manned submersible, and performed sea trial. Spectra and signal intensity changes of the maximum absorption wavelength were obtained in-situ at the depth of 3196 m. This compact automatic analyzer was suitable for deep sea in-situ determination of the chemical environment of hydrothermal vent habitats.
- In situ,
- Deep-sea analyzer,
- Continuous flow analysis,
- Iron,
- Manganese,
- Sulfide
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