Citation: WU Qian, BI Hong-Mei, HAN Xiao-Jun. Research Progress of Electrochemical Detection of Heavy Metal Ions[J]. Chinese Journal of Analytical Chemistry, ;2021, 49(3): 330-340. doi: 10.19756/j.issn.0253-3820.201352 shu

Research Progress of Electrochemical Detection of Heavy Metal Ions

WU Qian ¹ ,
BI Hong-Mei ^2,, ,
HAN Xiao-Jun ^1,,

1.
State Key tate Key Laboratory of Urban Water Resource and Environment, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China;
2.
College of Biological and Food Engineering, Guangdong University of Petrochemical Technology, Maoming 525000, China

Corresponding author: BI Hong-Mei, HAN Xiao-Jun,
Received Date: 16 June 2020
Revised Date: 26 December 2020

Fund Project: National Key R&D Program of China (No. 2016YFC0401104), the Harbin Distinguished Young Scholars Fund (No. 2017RAYXJ024), State Key Laboratory of Urban Water Resource and Environment (No. 2020DX03), the Guangdong Provincial Natural Science Foundation (No. 2020A1515101522) and the Characteristic Innovation Projects of Universities in Guangdong Province (No. 2019KTSCX109).

Heavy metal ions are extremely harmful to human health and ecosystems. The establishment of fast, convenient, accurate and sensitive detection techniques for heavy metal ion has important theoretical and application significance for protecting human health and maintaining ecosystem balance. The electrochemical analytical method has many advantages such as high sensitivity, fast analysis speed, simple equipment, and portability in detecting heavy metal ions. The appropriate modification of the working electrode is an effective way to improve the detection sensitivity. A variety of organic and inorganic materials have been widely used to modify the working electrode for this purpose with great progresses. This article reviews recent progresses on electrochemical detection of heavy metal ions, focusing on the influence of the electrode modification of material (inorganic materials, organic materials and biological materials) on the ion detection range and sensitivity. The advantages, limitations and prospects of various modified materials are also briefly described.
- Heavy metal ions,
- Detection,
- Electrochemistry,
- Electrode modification,
- Review
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
44. [44]
45. [45]
46. [46]
47. [47]
48. [48]
49. [49]
50. [50]
51. [51]
52. [52]
53. [53]
54. [54]
55. [55]
56. [56]
57. [57]
58. [58]
59. [59]
60. [60]
61. [61]
62. [62]
63. [63]
64. [64]
65. [65]
66. [66]
67. [67]
68. [68]
69. [69]
70. [70]
71. [71]
72. [72]
73. [73]
74. [74]
75. [75]
76. [76]
77. [77]
78. [78]
79. [79]
80. [80]
81. [81]
82. [82]
83. [83]
84. [84]
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