Citation: WANG Yi, GU Yuan-Ting, DING Zhu-Hong, CHEN Si-Qi, XIAO Shi-Yun, YU Yi-Hong, DU Bo-Feng, SONG Yu-Ting. Identification and Analysis of Quercetin and Its Glycosides in Rosa Roxburghii by Ultra High Performance Liquid Chromatography-Tandem High Resolution Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry, ;2020, 48(7): 955-961. doi: 10.19756/j.issn.0253-3820.191338 shu

Identification and Analysis of Quercetin and Its Glycosides in Rosa Roxburghii by Ultra High Performance Liquid Chromatography-Tandem High Resolution Mass Spectrometry

1.
School of Wine and Food Engineering, Guizhou University, Rosa Roxburghii Engineering Technology Research Center, National Forestry Bureau, Key Laboratory of Storage and Processing of Agricultural and Animal Products in Guizhou Province, Guiyang 550025, China;
2.
Bijie Vocational and Technical College, Bijie 551700, China

Received Date: 17 June 2019
Revised Date: 23 March 2020

Fund Project: This work was supported by the National Natural Science Foundation of China (No. 31860446), the Guizhou Science and Technology Foundation (Guizhou Science and Technology Foundation [2019] 1104) and the Guizhou Science and Technology Plan Project (Guizhou Science and Technology Platform Talents [2018] 5781).

The ultra high preformance liquid chromatography-tandem high resolution mass spectrometry was used to find out the possible composition of quercetin and its bound glycosides in Rosa roxburghii. The quercetin and its glycosides of Rosa roxburghii were analyzed by standard chromatographic time control, relative molecular weight, second order mass spectrometry fragments, and so on. The results showed that one quercetin and nine nuclear structural substances containing quercetin were identified from Rosa roxburghii. The chemical composition of quercetin, quercetin-3-rhamnoside, quercetin-3-O-glucopyranoside, quercetin-3-O-rhamnoside, quercetin-3-O-rhamnoside, Quercetin-3-O-[6"-O-(3-hydroxy-3-methylglutaryl)-β-D-galactoside], quercetin-3-O-glucose-rhamnoside, Amongthem, quercetin-3-rhamnoside, quercetin-3-O-glucopyranoside, quercetin-3-O-[6"-O-(3-hydroxy-3-methylglutaryl)-β-D-galactoside] were found in Rosa roxburghii for the first time. According to the ion fragments, the pyrolysis pathway of quercetin glycosides was inferred, which enriched the basic research results of Rosa roxburghii resources, and provided a theoretical reference for the structure identification of quercetin and the subsequent rational development of the drug and food utilization value of quercetin glycosides of Rosa roxburghii.
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沈阳化工大学材料科学与工程学院沈阳 110142