Citation: WEI Ming-Si, GU Xiao-Yu, YUAN Ming, WANG Hui, HUANG Tian-Shu, LIU Jia-Qi, SHEN Ling-Ling, TAN Xiao-Jie. Rapid Characterization of Chemical Constituents in Curcuma Kwangsiensis by Ultra-performance Convergence Chromatography Coupled with Quadrupole Time-of-Flight Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry, ;2019, 47(7): 1114-1120. doi: 10.19756/j.issn.0253-3820.181720 shu

Rapid Characterization of Chemical Constituents in Curcuma Kwangsiensis by Ultra-performance Convergence Chromatography Coupled with Quadrupole Time-of-Flight Mass Spectrometry

1.
Guangxi Zhuang Autonomous Region Botanical Garden of Medicinal Plants, Nanning 530023, China;
2.
Waters Technologies(Shanghai) Limited Company, Shanghai 201206, China;
3.
Shimadzu(China) Corporation, Guangzhou 510010, China

Received Date: 18 November 2018
Revised Date: 18 April 2019

Fund Project: This work was supported by the Guangxi Science and Technology Development Program (No. GuiKeNeng14123006-10).

Rapid identification of chemical constituents responsible for defined bioactivities from traditional Chinese medicines (TCMs) is a great challenge. A strategy for rapid identification of the chemical ingredients from the extracts of the rhizoma of Curcuma kwangsiensis with supercritical fluid extraction (SFE) was proposed using ultra-performance convergence chromatography coupled with a quadrupole time-of-flight mass spectrometry (UPC²-QTOF-MS) combined with UNIFI library. In this study, a total of 47 chemical compounds which were separated in 7 min were tentatively identified, including 42 sesquiterpenes. There were 37 chemical constituents in 8 groups of isomers in the analysis. The strategy which can rapidly, effectively, and comprehensively screen and identify components from TCMs has potential application in TCMs analysis as an alternative method besides UPLC-QTOF-MS and GC-MS.
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1.
沈阳化工大学材料科学与工程学院沈阳 110142