Citation: LI Jing, LIU Lu, GUO Hui-Qin, LIN Li-Ke, HU Si-Yu, RUAN Jia-Jian, LIU Wan-Sha, YAN Liu-Shui, LI Ke-Xin. An Upconversion Fluorescent Method for Rapid Detection of Perfluorooctane Sulfonate in Water Samples Based on Fluorine-Fluorine Interaction[J]. Chinese Journal of Analytical Chemistry, ;2019, 47(3): 380-387. doi: 10.19756/j.issn.0253-3820.181639 shu

An Upconversion Fluorescent Method for Rapid Detection of Perfluorooctane Sulfonate in Water Samples Based on Fluorine-Fluorine Interaction

LI Jing ^1,3, ,
LIU Lu ² ,
GUO Hui-Qin ^1,3 ,
LIN Li-Ke ^1,3 ,
HU Si-Yu ² ,
RUAN Jia-Jian ² ,
LIU Wan-Sha ² ,
YAN Liu-Shui ^1,3 ,
LI Ke-Xin ^1,3

1.
School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, China;
2.
School of International Education, Nanchang Hangkong University, Nanchang 330063, China;
3.
Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, Nanchang 330063, China

Received Date: 12 October 2018
Revised Date: 2 January 2019

Fund Project: This work was supported by the National Natural Science Foundation of China (Nos. 21665018, 21366024), the Natural Science Foundation of Jiangxi Province (No. 20181BAB203014), the Foundation of Jiangxi Educational Committee (No.GJJ160724) and the Jiangxi Postgraduate Innovation Fund (No.YC2018-S361).

As a typical of emerging persistent organic pollutant, perfluorooctane sulfonate (PFOS) and its salt cause ecosystem pollution due to their properties of environmental persistence, genetic toxicity, bio-accumulation and long-range transportation. In this study, NaYF₄:Yb,Er upconversion luminescence particle which had low toxicity, high photostability and good water solubility were prepared, and then modified by N,O-bis(trimethylsilyl) trifluoroacetamide (BSTFA) to obtain NaYF₄:Yb,Er@SiO₂-BSTFA. The luminescent material was used as fluorescence probe to interact with PFOS and a new method for fluorescent analysis of PFOS in water was hence established. In Britton-Robinson(BR, pH 6.30) buffer solution, PFOS can rapidly combine with NaYF₄:Yb,Er@SiO₂-BSTFA by fluorine-fluorine interaction, resulting in the fluorescence quenching of NaYF₄:Yb,Er@SiO₂-BSTFA in some extent. The study shows that the reduced fluorescence intensity at 545 nm are in proportional to the concentration of PFOS in the range of 3-100 nmol/L(R²=0.9985), with a detection limit (3σ) of 2.43 nmol/L. The proposed method for detection of PFOS showed obvious advantages compared with those methods reported in the literatures. The selectivity and interference experiments results indicated that the fluorescence probe had good selective response to PFOS in the presence of other common ions and PFOS analogues in water. The method was successfully applied to the determination of PFOS in real water samples with RSD ≤ 9.8% (n=5) and the recovery was 85.8%-118.6%.
- Fluorine-fluorine interaction,
- Upconversion fluorescence,
- Perfluorooctane sulfonate,
- Rapid detection
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
1. [1]
  Yang YANG , Pengcheng LI , Zhan SHU , Nengrong TU , Zonghua WANG . Plasmon-enhanced upconversion luminescence and application of molecular detection. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 877-884. doi: 10.11862/CJIC.20230440
2. [2]
  Jinghan ZHANG , Guanying CHEN . Progress in the application of rare-earth-doped upconversion nanoprobes in biological detection. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2335-2355. doi: 10.11862/CJIC.20240249
3. [3]
  Benhua Wang , Chaoyi Yao , Yiming Li , Qing Liu , Minhuan Lan , Guipeng Yu , Yiming Luo , Xiangzhi Song . 一种基于香豆素氟离子荧光探针的合成、表征及性能测试——“科研反哺教学”在有机化学综合实验教学中的探索与实践. University Chemistry, 2025, 40(6): 201-209. doi: 10.12461/PKU.DXHX202408070
4. [4]
  Di Yang , Jiayi Wei , Hong Zhai , Xin Wang , Taiming Sun , Haole Song , Haiyan Wang . Rapid Detection of SARS-CoV-2 Using an Innovative “Magic Strip”. University Chemistry, 2024, 39(4): 373-381. doi: 10.3866/PKU.DXHX202312023
5. [5]
  Lixing ZHANG , Yaowen WANG , Xu HAN , Junhong ZHOU , Jinghui WANG , Liping LI , Guangshe LI . Research progress in the synthesis of fluorine-containing perovskites and their derivatives. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1689-1701. doi: 10.11862/CJIC.20250007
6. [6]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
7. [7]
  Shahua Huang , Xiaoming Guo , Lin Lin , Guangping Chang , Sheng Han , Zuxin Zhou . Application of “Integration of Industry and Education” in Engineering Chemistry: Improvement of the Pesticide Fipronil Production. University Chemistry, 2024, 39(3): 199-204. doi: 10.3866/PKU.DXHX202309064
8. [8]
  Xiaofeng Xia , Jielian Zhu . Innovative Comprehensive Experimental Design: Synthesis of 6-Fluoro-N-benzoyl Tetrahydroquinoline. University Chemistry, 2024, 39(10): 344-352. doi: 10.12461/PKU.DXHX202405063
9. [9]
  Tingting Yu , Si Chen , Lianglong Sun , Tongtong Shi , Kai Sun , Xin Wang . Comprehensive Experimental Design for the Photochemical Synthesis, Analysis, and Characterization of Difluoropyrroles. University Chemistry, 2024, 39(11): 196-203. doi: 10.3866/PKU.DXHX202401022
10. [10]
  Min Gu , Huiwen Xiong , Liling Liu , Jilie Kong , Xueen Fang . Rapid Quantitative Detection of Procalcitonin by Microfluidics: An Instrumental Analytical Chemistry Experiment. University Chemistry, 2024, 39(4): 87-93. doi: 10.3866/PKU.DXHX202310120
11. [11]
  Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two Sm^Ⅲ₄ complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258
12. [12]
  Dan LUO , Xingcheng LIU , Dong LI , Tong CHANG . Metal-support interaction effects on CO activation over Co_n/SiO₂ catalysts. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2337-2344. doi: 10.11862/CJIC.20250003
13. [13]
  Yang Chen , Peng Chen , Yuyang Song , Yuxue Jin , Song Wu . Application of Chemical Transformation Driven Impurity Separation in Experiments Teaching: A Novel Method for Purification of α-Fluorinated Mandelic Acid. University Chemistry, 2024, 39(6): 253-263. doi: 10.3866/PKU.DXHX202310077
14. [14]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098
15. [15]
  Huiying Xu , Minghui Liang , Zhi Zhou , Hui Gao , Wei Yi . Application of Quantum Chemistry Computation and Visual Analysis in Teaching of Weak Interactions. University Chemistry, 2025, 40(3): 199-205. doi: 10.12461/PKU.DXHX202407011
16. [16]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
17. [17]
  Yingpeng ZHANG , Xingxing LI , Yunshang YANG , Zhidong TENG . A pyrazole-based turn-off fluorescent probe for visual detection of hydrazine. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1301-1308. doi: 10.11862/CJIC.20250064
18. [18]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Liu Fei . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-0. doi: 10.3866/PKU.WHXB202408004
19. [19]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
20. [20]
  Lin LI , Le CHEN , Lingjie HOU , Jiaqi JING , Jiayu DING , Tao ZHOU , Ruiping ZHANG . Smartphone-assisted fluorescent silver nanoclusters as ratiometric sensor for visual colorimetric detection of sulfide. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2261-2271. doi: 10.11862/CJIC.20250130

Get Citation

PDF

XML

Metrics

PDF Downloads(24)
Abstract views(1309)
HTML views(165)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142