Citation: Yu-Jie YIN, Wang-Jian FANG, Shu-Qin LIU, Jun CHEN, Jian-Jun ZHANG, Ai-Yun NI. A New Bio-metal-organic Framework: Synthesis, Crystal Structure and Selectively Sensing of Fe(Ⅲ) Ion in Aqueous Medium[J]. Chinese Journal of Structural Chemistry, ;2021, 40(11): 1456-1460. doi: 10.14102/j.cnki.0254–5861.2011–3180 shu

A New Bio-metal-organic Framework: Synthesis, Crystal Structure and Selectively Sensing of Fe(Ⅲ) Ion in Aqueous Medium

School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China

Corresponding author: Shu-Qin LIU, shuqinliu@163.com Jian-Jun ZHANG, zhangjj@dlut.edu.cn
Received Date: 16 March 2021
Accepted Date: 28 May 2021

Fund Project: the National Natural Science Foundation of China 21871038

Figures(5)

A new two-dimensional (2D) bio-metal-organic framework based on trinuclear cluster units, [Zn₃(adeninate)₂(CH₃COO)₄]∙DMF (Zn–A), was synthesized by the self-assembly of biomolecule adenines with zinc ions. Topological analysis reveals its 4⁴ connected layer structure. Remarkably, Zn–A bears high sensitivity and selectivity detection ability of iron ion with the limit of detection being 4.0 × 10^-6 mol/L.
- supramolecule,
- crystal structure,
- bio-metal-organic framework,
- Fe³⁺ ion,
- sensing
1. [1]
  Xu, H.; Gao, J.; Qian, X.; Wang, J.; He, H.; Cui, Y.; Yang, Y.; Wang, Z.; Qian, G. Metal-organic framework nanosheets for fast-response and highly sensitive luminescent sensing of Fe³⁺. J. Mater. Chem. A 2016, 4, 10900−10905. doi: 10.1039/C6TA03065C
2. [2]
  Shi, Y.; Liu, X.; Shan, Y.; Zhang, X.; Kong, W.; Lu, Y.; Tan, Z.; Li, X. L. Naked-eye repeatable off-on-off and on-off-on switching luminescence of copper(Ⅰ)-1H-imidazo[4, 5-f][1, 10]phenanthroline complexes with reversible acid-base responses. Dalton Trans. 2019, 48, 2430−2441. doi: 10.1039/C8DT04538K
3. [3]
  Jiang, X. F.; Han, S. D.; Wang, A. N.; Pan, J.; Wang, G. M. The tri(imidazole)-derivative moiety: a new category of electron acceptors for the design of crystalline hybrid photochromic materials. Chem. Eur. J. 2021, 27, 1410−1415. doi: 10.1002/chem.202004411
4. [4]
  Feng, X.; Feng, Y. Q.; Guo, N.; Sun, Y. L.; Zhang, T.; Ma, L. F.; Wang, L. Y. Series d-f heteronuclear metal-organic frameworks: color tunability and luminescent probe with switchable properties. Inorg. Chem. 2017, 56, 1713−1721. doi: 10.1021/acs.inorgchem.6b02851
5. [5]
  Ma, Y. J.; Hu, J. X.; Han, S. D.; Pan, J.; Li, J. H.; Wang, G. M. Manipulating on/off single-molecule magnet behavior in a Dy(Ⅲ)-based photochromic complex. J. Am. Chem. Soc. 2020, 142, 2682−2689. doi: 10.1021/jacs.9b13461
6. [6]
  Ju, P.; Liu, X. C.; Zhang, E. S. A novel 3D Zn-based luminescence metal-organic framework: synthesis, structure and fluorescence enhanced sensing of ammonia vapor in air. Chin. J. Struct. Chem. 2020, 39, 1458−1464.
7. [7]
  Feng, X.; Li, R.; Wang, L.; Ng, S. W.; Qin, G.; Ma, L. A series of homonuclear lanthanide coordination polymers based on a fluorescent conjugated ligand: syntheses, luminescence and sensor for pollutant chromate anion. CrystEngComm. 2015, 17, 7878−7887. doi: 10.1039/C5CE01454A
8. [8]
  An, J.; Geib, S. J.; Rosi, N. L. Cation-triggered drug release from a porous zinc-adeninate metal-organic framework. J. Am. Chem. Soc. 2009, 131, 8376−7. doi: 10.1021/ja902972w
9. [9]
  Sheldrick, G. M. SHELXL-2014/7: Program for the Solution of Crystal Structures. University of Göttingen, Göttingen 2014.
10. [10]
  Spek, A. L. Platon squeeze: a tool for the calculation of the disordered solvent contribution to the calculated structure factors. Acta Crystallogr., Sect. C: Struct. Chem. 2015, 71, 9−18. doi: 10.1107/S2053229614024929
11. [11]
  Li, B.; Fang, W. J.; Liu, S. Q.; Zhao, H.; Zhang, J. J. Two novel coordination polymers with (6, 3) topology constructed by an imidazole-containing isophthalic ligand: syntheses, structures and luminescence properties. Chin. J. Struct. Chem. 2020, 39, 110−117.
12. [12]
  Li, M. Y.; Fang, W. J.; Liu, S. Q.; Ni, J.; Zhang, J. J. Two new Zn(Ⅱ)/Cd(Ⅱ) one-dimensional coordination polymers based on naphthalimide dicarboxylic ligand. Chin. J. Struct. Chem. 2019, 38, 1807−1813.
13. [13]
  Dong, J. P.; Li, B.; Jin, Y. J.; Wang, L. Y. Efficient detection of Fe(Ⅲ) and chromate ions in water using two robust lanthanide metal-organic frameworks. CrystEngComm. 2021, 23, 1677−1683. doi: 10.1039/D0CE01802C
1. [1]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
2. [2]
  Zhihui ZONG , Zijie ZHAO , Lei HUANG , Zhicheng PAN , Shan WANG , Lili LIANG , Huaqing LIU , Enli ZHANG . Synthesis, crystal structures, and antitumor activity of two metal complexes of imidazolyl acylhydrazones. Chinese Journal of Inorganic Chemistry, 2026, 42(5): 1048-1062. doi: 10.11862/CJIC.20250330
3. [3]
  Yukun CHEN , Kexin FENG , Bolun ZHANG , Wentao SONG , Jianjun ZHANG . Syntheses, crystal structures, and diametrically opposed mechanically-stimulated luminescence response of two Mg(Ⅱ) metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1227-1234. doi: 10.11862/CJIC.20240448
4. [4]
  Ran ZHUANG , Xinru WANG , Ruwei SHEN , Dunru ZHU . Syntheses, crystal structures and Hirshfeld surface analyses of three 3-pyridazinyl-substituted triaryltriazoles and their Cu(Ⅱ) complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(8): 1712-1722. doi: 10.11862/CJIC.20260136
5. [5]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
6. [6]
  Zihe SONG , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Crystal structure, thermal analysis, and luminescence properties of six heterocyclic lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 181-192. doi: 10.11862/CJIC.20250126
7. [7]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
8. [8]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
9. [9]
  Ruiyan CHEN , Yanping HE , Jian ZHANG . Synthesis and third-order nonlinear optical property of Ti₄L₆ cage-based metal-organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2149-2156. doi: 10.11862/CJIC.20250177
10. [10]
  Xuetian WANG , Jijiang WANG , Long TANG , Erlin YUE , Xiao WANG , Yuqi ZHANG . A three-dimensional zinc(Ⅱ) metal-organic framework based on nitrogen-containing ligands for the detection of 2,4-dinitrophenylhydrazine and tetracycline. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 861-871. doi: 10.11862/CJIC.20250294
11. [11]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
12. [12]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
13. [13]
  Yingyue ZHANG , Liuqing KANG , Yating YANG , Xiaofen GUAN , Wenmin WANG . Crystal structure and antibacterial activity of two Gd₂ complexes based on polydentate Schiff-base ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1867-1877. doi: 10.11862/CJIC.20250100
14. [14]
  Wenya DING , Fangfei XU , Jiayu GU , Xinran CHEN , Kai CHEN . Synthesis and crystal structure of three cucurbit[6]uril-cadmium supramolecular assemblies. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 808-816. doi: 10.11862/CJIC.20260012
15. [15]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
16. [16]
  Lihang LAN , Yanyong SHA , Lina YANG , Wentao DAI , Daozhen SHEN , Wenlong LIU , Hongjiang LIU , Qi LIU . A one-dimensional cadmium-based coordination polymer as cathode material of lithium-ion battery. Chinese Journal of Inorganic Chemistry, 2026, 42(8): 1751-1762. doi: 10.11862/CJIC.20260039
17. [17]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
18. [18]
  Jiarong ZHU , Xiaohua ZHANG , Xinting XIONG , Xuliang NIE , Xiuying SONG , Miaomiao ZHANG , Dayong PENG , Xiuguang YI . Crystal structure, Hirshfeld surface analysis, and antifungal activity of five complexes based on 2,5-bis(carboxymethoxy)terephthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2358-2370. doi: 10.11862/CJIC.20250150
19. [19]
  Jing FENG , Renshu WANG , Hu WANG , Hailong LIU . Co(Ⅱ) and Ni(Ⅱ) complexes of 3,3-diphenylpropionic acid and 2,2′-dipyridylamine: Structures and biological activities. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 617-631. doi: 10.11862/CJIC.20250265
20. [20]
  Jiaojiao CHEN , Gaiyan GUO , Hua YANG , Shuo LIU , Lulu DONG , Xiaoli CHEN , Huali CUI , Jijiang WANG . Syntheses, structures, fluorescence properties, and applications of two Cd-based metal-organic framework materials based on polycarboxylic acids. Chinese Journal of Inorganic Chemistry, 2026, 42(8): 1763-1778. doi: 10.11862/CJIC.20250359

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(1703)
HTML views(57)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142