Citation: Xiao-Jing LIU, E LIU, Zhuang-Yu LI, Fang-Fang JIAN. Synthesis, Crystal Structure and Property Studies on a Bipyridine Adduct of Nickel Xanthogenate[J]. Chinese Journal of Structural Chemistry, ;2021, 40(5): 588-594. doi: 10.14102/j.cnki.0254–5861.2011–2986 shu

Synthesis, Crystal Structure and Property Studies on a Bipyridine Adduct of Nickel Xanthogenate

Xiao-Jing LIU ^a ,
E LIU ^{a, b} ,
Zhuang-Yu LI ^a ,
Fang-Fang JIAN ^{a, c,,}

a.
School of Chemical Engineering and Pharmaceutics, Henan University of Science and Technology, Luoyang 471000, China
b.
School of Materials Science and Engineering & Center for Molecular Engineering and Applied Chemistry, Anhui University of Technology, Maanshan 243002, China
c.
Heke University Renewable Energy Co. LTD, Luoyang 471000, China

Corresponding author: Fang-Fang JIAN, ffj2013@163.com
Received Date: 21 September 2020
Accepted Date: 25 November 2020

Figures(8)

A new coordination polymer containing mixed ligands, namely [Ni(S₂COiBu)₂(DBPMF)·(CHCl₃)]_∞ (DBPMF = 2, 7-dibromo-9, 9-(4-pyridylmethyl)fluorine), has been synthesized and structurally characterized by elemental analysis and single-crystal X-ray diffractions. X-ray structural analysis reveals that each Ni atom is coordinated by two isobutyl xanthogenate molecules and two nitrogen atoms from two DBPMF ligands to form octahedral coordination geometry. DBPMF acts as a bridge to form a coordination polymer. Fluorescence property of this coordination polymer displays a broad emission band at λ = 413 nm. Thermal analysis shows that the solvent molecule CHCl₃ can be stabilized in the crystal structure until 140 ℃.
- DBPMF,
- coordination polymer,
- xantghogenate,
- crystal structure,
- fluorescence
1. [1]
  Zhao, H. K.; Yang, H. K.; Wang, X. G.; Ding, B.; Liu, Z. Y.; Zhao, X. J.; Yang, E. C. An unusual 2D polymeric Co(II) complex with 2, 6-diaminopurine: synthesis, crystal structure, and magnetic behavior. Inorg. Chem. Commun. 2019, 107, 107483. doi: 10.1016/j.inoche.2019.107483
2. [2]
  Wu, J. Y.; Yuan, P. T.; Hsiao, C. C.; Chang, H. K.; Liu, Y. C.; Hsu, L. J.; Chiang, M. H. Structural diversity in polymeric and discrete complexes constructed by divalent transition metals and unsymmetrical quasi semirigid pyridinecarboxylate isomers. J. Solid State Chem. 2019, 277, 701‒712. doi: 10.1016/j.jssc.2019.07.033
3. [3]
  Banasz, R.; Walesa-Chorab, M. Polymeric complexes of transition metal ions as electrochromic materials: synthesis and properties. Coord. Chem. Rev. 2019, 389, 1‒18. doi: 10.1016/j.ccr.2019.03.009
4. [4]
  Zheng, X. Z.; Huang, J. S.; Yao, Y. M.; Xu, X. Stoichiometric reactions and catalytic dehydrogenations of amine-boranes with calcium aryloxide. Chem. Commun. 2019, 62, 9152‒9155.
5. [5]
  Lu, S. Q.; Fang, K.; Liu, Y. Y.; Li, M. X.; Liu, S. J.; He, X. Multivariant synthesis, crystal structures and properties of four nickel coordination polymers based on flexible ligands. CrystEngComm. 2018, 34, 5045‒5055.
6. [6]
  Eichhofer, A.; Buth, G. 1-D polymeric iron(II) thiolato complexes: synthesis, structure, and properties of _∞¹[Fe(SR)₂] (R = Ph, Mes), _∞¹[Fe(NH₃)(SPh)(µ-SPh)] and _∞¹[(µ-SPh)Fe(NH₃)₂(µ-SPh)₂Fe(µ-SPh)]. Eur. J. Inorg. Chem. 2019, 5, 639‒646.
7. [7]
  Mahmoudi, H.; Valentini, F.; Ferlin, F.; Bivona, L. A.; Anastasiou, I.; Fusaro, L.; Aprile, C.; Marrocchi, A.; Vaccaro, L. A tailored polymeric cationic tag-anionic Pd(II) complex as a catalyst for the low-leaching Heck-Mizoroki coupling in flow and in biomass-derived GVL. Green Chem. 2019, 21, 355‒360. doi: 10.1039/C8GC03228A
8. [8]
  Proetto, M. T.; Sanning, J.; Peterlechner, M.; Thunemann, M.; Stegemann, L.; Sadegh, S.; Devor, A.; Gianneschi, N. C.; Strassert, C. A. Phosphorescent Pt(II) complexes spatially arrayed in micellar polymeric nanoparticles providing dual readout for multimodal imaging. Chem. Commun. 2019, 55, 501‒504. doi: 10.1039/C8CC06347H
9. [9]
  Blake, A. J.; Champness, N. R.; Hubberstey, P.; Li, W. S.; Withersby, M. A.; Schroder, M. Inorganic crystal engineering using self-assembly of tailored building-blocks. Coord. Chem. Rev. 1999, 183, 117‒138. doi: 10.1016/S0010-8545(98)00173-8
10. [10]
  Biradha, K.; Seward, C.; Zaworotko, M. J. Helical coordination polymers with large chiral cavities. Angew. Chem. Int. Ed. 1999, 38, 492‒495. doi: 10.1002/(SICI)1521-3773(19990215)38:4<492::AID-ANIE492>3.0.CO;2-#
11. [11]
  Zaworotko, M. J. From disymmetric molecules to chiral polymers: a new twist for supramolecular synthesis? Angew. Chem. Int. Ed. 1998, 37, 1211‒1213. doi: 10.1002/(SICI)1521-3773(19980518)37:9<1211::AID-ANIE1211>3.0.CO;2-C
12. [12]
  Mislin, G.; Graft, E.; Hosseini, M. W.; Cian, A. D.; Kyritsakas, N.; Fischer, J. Synthesis and structural analysis of an infinite linear coordination network formed by the self-assembly of tetracyanocalix[4]arene ligands and silver cations. Chem. Commun. 1998, 22, 2545‒2546.
13. [13]
  Kaes, C.; Hosseini, M. W.; Rickard, C. E. F.; Skelton, B. W.; White, A. H. Synthesis and structural analysis of a helical coordination polymer formed by the self-assembly of a 2, 2΄-bipyridine-based exo-ditopic macrocyclic ligand and silver cations. Angew. Chem., Int. Ed. 1998, 37, 920‒922. doi: 10.1002/(SICI)1521-3773(19980420)37:7<920::AID-ANIE920>3.0.CO;2-O
14. [14]
  Gu, J. Z.; Cui, Y. H.; Liang, X. X.; Wu, J.; Lv, D. Y.; Kirillov, A. M. Structurally distinct metal-organic and H-bonded networks derived from 5-(6-carboxypyridin-3-yl)isophthalic acid: coordination and template effect of 4, 4΄-bipyridine. Cryst. Growth Des. 2016, 46, 4658‒4670.
15. [15]
  Tian, X. Y.; Hu, A. Y.; Yuan, A. H.; Chen, D.; Yang, D.; Yang, F. L. Syntheses, crystal structures, and thermal expansion properties of three-dimensional cyanide-bridged compounds Zn(4, 4΄-bpy)(H₂O)₂M(CN)₄ (4, 4΄-bpy = 4, 4΄-bipyridine; M = Ni, Pd, Pt). Z. Anorg. Und Allg. Chem. 2015, 641, 2340‒2343. doi: 10.1002/zaac.201500271
16. [16]
  Yang, H. L.; Chen, F.; Zhang, D.; He, X.; Zhang, X. Q. Syntheses, crystal structures, thermal stabilities and fluorescence properties of silver(I) and cadmium(II) complexes based on 1, 2, 4-benzenetricarboxylic acid and 2, 2΄-bipyridine. Chin. J. Inorg. Chem. 2019, 35, 1579‒1585.
17. [17]
  Rosales-Vazquez, L. D.; Valdes-Garcia, J.; Bazany-Rodriguez, I. J.; German-Acacio, J. M.; Martinez-Otero, D.; Vilchis-Nestor, A. R.; Morales-Luckie, R.; Sanchez-Mendieta, V.; Dorazco-Gonzalez, A. A sensitive photoluminescent chemosensor for cyanide in water based on a zinc coordination polymer bearing ditert-butyl-bipyridine. Dalton Trans. 2019, 48, 12407‒12420. doi: 10.1039/C9DT01861A
18. [18]
  Ma, Y. J.; Han, S. D.; Pan, J.; Mu, Y.; Li, J. H.; Wang, G. M. An inorganic-organic hybrid framework from the assembly of an electron-rich diphosphonate and electron-deficient tripyridyl moiety. J. Mater. Chem. C 2018, 6, 9341‒9344. doi: 10.1039/C8TC02903B
19. [19]
  Charles, R. M.; Taylor, N. S.; Mercado, A. A.; Frost, C. E.; Yokley, T. W.; Eckenhoff, W. T.; Schley, N. D.; DeYonker, N. J.; Brewster, T. P. Systematic evaluation of the electronic effect of aluminum-containing ligands in iridium-aluminum and rhodium-aluminum bimetallic complexes. Dalton Trans. 2020, 37, 13029‒13043.
20. [20]
  Hawes, C. S.; Ó Máille, G. M.; Byrne, K.; Schmitt, W.; Gunnlaugsson, T. Tetraarylpyrrolo[3, 2-b]pyrroles as versatile and responsive fluorescent linkers in metal-organic frameworks. Dalton Trans. 2018, 47, 10080‒10092. doi: 10.1039/C8DT01784K
21. [21]
  Sheldrick, G. M. SHELXTL, v5 Reference Manual, Siemens Analytical X-ray Systems, Madison: WI 1997.
22. [22]
  Feng, X.; Ma, L. F.; Wang, L. Y.; Zhao, J. S. A unique tetranuclear nickel(II) complex containing pyridine-2-carboxaldehyde derivative bearing an intramolecular acetato: synthesis, crystal structure and magnetic property. Inorg. Chem. Commun. 2011, 14, 584‒589. doi: 10.1016/j.inoche.2011.01.030
23. [23]
  Jian, F. F.; Qin, Y. Q.; Zhang, J.; Zhao, P. S. Synthesis, crystal structure and property studies on a tetrachlorocuprate salt of an organic cation. Bull. Korean Chem. Soc. 2008, 29, 1412‒1414. doi: 10.5012/bkcs.2008.29.7.1412
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