Citation: Chang-Zheng TU, Yu-Ting YANG, Fan WANG, Jian-Ling WANG, Hong-Ju YIN, Fei-Xiang CHENG. Two Coordination Polymers Based on Pamoic Acid and (1,4-Bis(imidazol-1-yl)-butane: Synthesis, Structures and Properties[J]. Chinese Journal of Structural Chemistry, ;2021, 40(4): 473-481. doi: 10.14102/j.cnki.0254–5861.2011–2946 shu

Two Coordination Polymers Based on Pamoic Acid and (1,4-Bis(imidazol-1-yl)-butane: Synthesis, Structures and Properties

College of Chemistry and Environmental Science, Qujing Normal University, Qujing 655011, China

Corresponding author: Fei-Xiang CHENG, chengfx2019@163.com
Received Date: 27 July 2020
Accepted Date: 14 October 2020

Fund Project: the Shanghai Key Laboratory of Rare Earth Functional Materials, the project of teaching quality and teaching reform of Yunnan Province 2073010023the National Teaching Quality and Teaching Reform Project 201810684012the National Natural Science Foundation of China 81601602

Figures(10)

Two mixed-ligand compounds, namely [Mn₂(bimb)(PA)₂]_n (1) and [Zn(bimb)(PA)]_n (2) (H₂PA = pamoic acid, bimb = 1,4-bis(imidazol-1-yl)-butane) have been synthesized under the same solvothermal conditions. Compound 1 can be described as (4,4) topology based on the 4-connected [Mn₂(COO)₄] paddle-wheel units, which contains both rotaxane- and catenane-like motifs. For 2, the 2D wavy-like network interlocked with each other and resulted in a 2-fold interpenetrated 2D → 3D architecture. The structural differences of the two compounds are mainly due to the differences of metal ions and coordination modes of the PA^2- ligand. In addition, the magnetism and photoluminescent properties of them have also been explored.
- crystal structures,
- pamoic acid,
- luminescence,
- magnetic properties
1. [1]
  Chen, X.; Jiang, H.; Li, X.; Hou, B.; Gong, W.; Wu, X. W.; Han, X.; Zheng, F. F.; Liu, Y.; Jiang, J. W.; Cui, Y. Chiral phosphoric acids in metal-organic frameworks with enhanced acidity and tunable catalytic selectivity. Angew. Chem. Int. Ed. 2019, 58, 14748–14757. doi: 10.1002/anie.201908959
2. [2]
  Fan, W. D.; Yuan, S.; Wang, W. J.; Feng, L.; Liu, X. P.; Zhang, X. R.; Wang, X.; Kang, Z. X.; Dai, F. N.; Yuan, D. Q.; Sun, D. F.; Zhou, H. C. Optimizing multivariate metal-organic frameworks for efficient C₂H₂/CO₂ separation. J. Am. Chem. Soc. 2020, 142, 8728–8737. doi: 10.1021/jacs.0c00805
3. [3]
  Cao, C.; Liu, S. J.; Yao, S. L.; Zheng, T. F.; Chen, Y. Q.; Chen, J. L.; Wen, H. R. Spin-canted antiferromagnetic ordering in transition metal-organic frameworks based on tetranuclear clusters with mixed V- and Y-shaped ligands. Cryst. Growth Des. 2017, 17, 4757–4765. doi: 10.1021/acs.cgd.7b00682
4. [4]
  Yao, S. L.; Liu, S. J.; Tian, X. M.; Zheng, T. F.; Cao, C.; Niu, C. Y.; Chen, Y. Q.; Chen, J. L.; Huang, H.; Wen, H. R. A Zn(Ⅱ)-based metal-organic framework with a rare tcj topology as a turn-on fluorescent sensor for acetylacetone. Inorg. Chem. 2019, 58, 3578–3581. doi: 10.1021/acs.inorgchem.8b03316
5. [5]
  Liu, S. J.; Han, S. D.; Zhao, J. P.; Xu, J.; Bu, X. H. In-situ synthesis of molecular magnetorefrigerant materials. Coord. Chem. Rev. 2019, 394, 39–52. doi: 10.1016/j.ccr.2019.05.009
6. [6]
  Zhao, Y.; Hao, R. H. Structural diversity and photoluminescent properties of two zinc coordination polymers based on 5-i-propoxyisophthalate and flexible N-donor ligands. Inorg. Nano-Met. Chem. 2020, 1–7.
7. [7]
  Zhao, Y.; Wang, R. L.; Wu, X. X.; Yang, C. D. A water-stable metal organic framework for the detection of explosives and antibiotics. Chin. J. Struct. Chem. 2019, 38, 991–998.
8. [8]
  Li, Z. S.; Li, X. Y.; Liu, J. W.; He, T.; Yue, K. F. Substituent and temperature effect on the assemblies of three lead(Ⅱ) coordination polymers based on asymmetrical biphenyl tritopic ligands. Z. Anorg. Allg. Chem. 2015, 641, 2570–2575. doi: 10.1002/zaac.201500621
9. [9]
  Gu, J. Z.; Cui, Y. H.; Liang, X. X.; Wu, J.; Lv, D. Y.; Kirillov, A. M. Structurally distinct metal-organic and H-bonded networks derived from 5-(6-carboxypyridin-3-yl)isophthalic acid: coordination and template effect of 4, 4′-bipyridine. Cryst. Growth Des. 2016, 16, 4658–4670. doi: 10.1021/acs.cgd.6b00735
10. [10]
  Dong, X. Y.; Si, C. D.; Fan, Y.; Hu, D. C.; Yao, X. Q.; Yang, Y. X.; Liu, J. C. Effect of N-donor ligands and metal ions on the coordination polymers based on a semirigid carboxylic acid ligand: structures analysis, magnetic properties, and photoluminescence. Cryst. Growth Des. 2016, 16, 2062–2073. doi: 10.1021/acs.cgd.5b01734
11. [11]
  Pinta, N. D.; Fidalgo, L.; Madariaga, G.; Lezama, L.; Cortés, R. Guest driven structural correlations in DPDS [di(4-pyridyl)disulfide]-based coordination polymers. Cryst. Growth Des. 2012, 12, 5069–5078. doi: 10.1021/cg3010135
12. [12]
  Yang, Y. T.; Tu, C. Z.; Miao J. J.; Li J. L.; Chen, G. Temperature-dependent hydrothermal synthesis of two distinct three-dimensional copper complexes. Chin. J. Struct. Chem. 2016, 35, 597–604
13. [13]
  Hu, H. Y.; Horton, J. K.; Gryk, M. R.; Prasad, R.; Naron, J. M.; Sun, D. A.; Hecht, S. M.; Wilson. S. H.; Mullen, G. P. Identification of small molecule synthetic inhibitors of DNA polymerase beta by NMR chemical shift mapping. J. Biol. Chem. 2004, 279, 39736–39744. doi: 10.1074/jbc.M402842200
14. [14]
  Jørgensen, M. Quantitative determination of pamoic acid in dog and rat serum by automated ion-pair solid-phase extraction and reversed-phase high-performance liquid chromatography. Chromatogr. B 1998, 716, 315–323. doi: 10.1016/S0378-4347(98)00273-4
15. [15]
  Du, M.; Li, C. P.; Zhao, X. J.; Yu, Q. Interplay of coordinative and supramolecular interactions in engineering unusual crystalline architectures of low-dimensional metal-pamoate complexes under co-ligand intervention. CrystEngComm. 2007, 9, 1011–1028. doi: 10.1039/b707853f
16. [16]
  He, Y. P.; Yuan, L. B.; Chen, G. H.; Lin, Q. P.; Wang, F.; Zhang, L.; Zhang, J. Water-soluble and ultrastable Ti₄L₆ tetrahedron with coordination assembly function. J. Am. Chem. Soc. 2017, 139, 16845–16851. doi: 10.1021/jacs.7b09463
17. [17]
  He, Y. P.; Chen, G. H.; Yuan, L. B.; Zhang, L.; Zhang, J. Ti₄(embonate)₆ cage-ligand strategy on the construction of metal-organic frameworks with high stability and gas sorption properties. Inorg. Chem. 2020, 59, 964–967. doi: 10.1021/acs.inorgchem.9b03075
18. [18]
  Chen, G. H.; He, Y. P.; Zhang, S. H.; Zhang, J. Syntheses, crystal structures and fluorescent properties of two metal-organic frameworks based on pamoic acid. J. Solid State Chem. 2019, 270, 335–338. doi: 10.1016/j.jssc.2018.11.027
19. [19]
  Shi, X. M.; Li, M. X.; He, X.; Liu, H. J.; Shao, M. Crystal structures and properties of four coordination polymers constructed from flexible pamoic acid. Polyhedron 2010, 29, 2075–2080. doi: 10.1016/j.poly.2010.04.004
20. [20]
  Wang, S. N.; Peng, Y. Q.; Wei, X. L.; Zhang, Q. F.; Wang, D. Q.; Dou, J. M.; Li, D. C.; Bai, J. F. Temperature-dependent supramolecular isomerism in three zinc coordination polymers with pamoic acid and 1, 4-bis(imidazol-1-ylmethyl)-benzene. CrystEngComm. 2011, 13, 5313–5316. doi: 10.1039/c1ce05463e
21. [21]
  Yang, Y. T.; Tu, C. Z.; Yin, H. J.; He, C. X.; Zhao, Q.; Cheng, F. X. Synthesis, structures, and properties of five metal-organic frameworks based on oxidized 3, 3'-azodibenzoic acid and different N-donor ligands. Eur. J. Inorg. Chem. 2019, 4582–4591.
22. [22]
  Yang, Y. T.; Tu, C. Z.; Xu, L. L.; Yan, B. L.; Wang, F. Flexible bis(benzimidazole)-based ligands directed the structure characteristics of coordination polymers based on diphenic acid Co-ligands: syntheses, structures and properties. Chin. J. Struct. Chem. 2019, 38, 155–164.
23. [23]
  Tu, C. Z.; Wang, W. H.; Guo, B.; Miao, J. J.; Yang, Y. T. A novel example of Mn-compound showing rotaxane-like motif. J. Qujing Normal Univ. 2014, 33, 19–22.
24. [24]
  Li, S. L.; Lan, Y. Q.; Ma, J. F.; Yang, J.; Wei, G. H.; Zhang, L. P.; Su, Z. M. Structures and luminescent properties of seven coordination polymers of zinc(Ⅱ) and cadmium(Ⅱ) with 3, 3′, 4, 4′-benzophenone tetracarboxylate anion and bis(imidazole). Cryst. Growth Des. 2008, 8, 675–684. doi: 10.1021/cg7009385
25. [25]
  Wen, L. L.; Lu, Z. D.; Lin, J. G.; Tian, Z. F.; Zhu, H. Z.; Meng, Q. J. Syntheses, structures, and physical properties of three novel metal-organic frameworks constructed from aromatic polycarboxylate acids and flexible imidazole-based synthons. Cryst. Growth Des. 2007, 7, 93–99. doi: 10.1021/cg0604982
26. [26]
  Sheldrick, G. M. SHELXS-97, Program for X-ray Crystal Structure Solution. University of Göttingen, Germany 1997.
27. [27]
  Sheldrick, G. M. SHELXL-97, Program for the Refinement of Crystal Structures from Diffraction Data. University of Göttingen, Germany 1997.
28. [28]
  Luo, F.; Yang, Y. T.; Che, Y. X.; Zheng, J. M. An unusual metal-organic framework showing both rotaxane- and cantenane-like motifs. CrystEngComm. 2008, 10, 981–982. doi: 10.1039/b805025b
29. [29]
  Yi, F. Y.; Sun, Z. M. Solvent-controlled syntheses, structure, and magnetic properties of trinuclear Mn(Ⅱ)-based metal-organic frameworks. Cryst. Growth Des. 2012, 12, 5693–5700. doi: 10.1021/cg3011844
30. [30]
  Zhao, Y.; Chang, X. H.; Liu, G. Z.; Ma, L. F.; Wang, L. Y. Five Mn(Ⅱ) coordination polymers based on 2, 3', 5, 5'-biphenyl tetracarboxylic acid: syntheses, structures, and magnetic properties. Cryst. Growth Des. 2015, 15, 966–974. doi: 10.1021/cg501768f
31. [31]
  Ma, L. F.; Wang, L. Y.; Du, M. A novel 3D Mn(Ⅱ) coordination polymer involving 4, 4'-dipyridylsulfide and 4, 4'-dipyridyltrisulfide obtained by in situ ligand formation from 4, 4′-dipyridyldisulfide. CrystEngComm. 2009, 11, 2593–2596. doi: 10.1039/b914827m
32. [32]
  Gou, L.; Wu, Q. R.; Hu, H. M.; Qin, T.; Xue, G. L.; Yang, M. L.; Tang, Z. X. An investigation of the positional isomeric effect of terpyridine derivatives: self-assembly of novel cadmium coordination architectures driven by N-donor covalence and π⋯π non-covalent interactions. Polyhedron 2008, 27, 1517–1526. doi: 10.1016/j.poly.2008.01.024
33. [33]
  Han, Z. X.; Wang J. J.; Hu, H. M.; Chen, X. L.; Wu, Q. R.; Li, D. S.; Shi, Q. Z. Effects of the size of aromatic chelate ligands and d¹⁰ metal ions on the structures of dicarboxylate complexes: from dinuclear molecule to helical chains and 2D network. J. Mol. Struct. 2008, 891, 364–369. doi: 10.1016/j.molstruc.2008.04.010
1. [1]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
2. [2]
  Wanting CHEN , Chufei MIAO , Yan LIU , Bobi ZHENG , Xiaoyu ZHENG , Han XU , Jumei TIAN . Syntheses, characterization, and luminescence properties of Yb(Ⅲ)-based one-dimensional chain coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1672-1680. doi: 10.11862/CJIC.20250013
3. [3]
  Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269
4. [4]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
5. [5]
  Yanfen PENG , Xinyue WANG , Tianbao LIU , Xiaoshuo WU , Yujing WEI . Syntheses and luminescence of four Cd(Ⅱ)/Zn(Ⅱ) complexes constructed by 1,3‐bis(4H‐1,2,4‐triazole)benzene. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1416-1426. doi: 10.11862/CJIC.20250018
6. [6]
  Xiaofen GUAN , Yating LIU , Jia LI , Yiwen HU , Haiyuan DING , Yuanjing SHI , Zhiqiang WANG , Wenmin WANG . Synthesis, crystal structure, and DNA-binding of binuclear lanthanide complexes based on a multidentate Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2486-2496. doi: 10.11862/CJIC.20240122
7. [7]
  Huaihao CHEN , Lingwen ZHANG , Yukun CHEN , Jianjun ZHANG . A water-stable metal-organic framework probe for Al³⁺/Ga³⁺/In³⁺ detection. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2601-2608. doi: 10.11862/CJIC.20250184
8. [8]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
9. [9]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
10. [10]
  Zihe SONG , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Crystal structure, thermal analysis, and luminescence properties of six heterocyclic lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 181-192. doi: 10.11862/CJIC.20250126
11. [11]
  Yukun CHEN , Kexin FENG , Bolun ZHANG , Wentao SONG , Jianjun ZHANG . Syntheses, crystal structures, and diametrically opposed mechanically-stimulated luminescence response of two Mg(Ⅱ) metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1227-1234. doi: 10.11862/CJIC.20240448
12. [12]
  Zihao XU , Lirong GUO , Jinzhong GU . Syntheses, crystal structures, and catalytic properties of zinc(Ⅱ) and cadmium(Ⅱ) coordination polymers constructed from a dicarboxylate ligand. Chinese Journal of Inorganic Chemistry, 2026, 42(5): 1063-1072. doi: 10.11862/CJIC.20250345
13. [13]
  Zhenghua ZHAO , Yufeng LIU , Qing ZHANG , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of zinc(Ⅱ), nickel(Ⅱ) and cadmium(Ⅱ) complexes constructed from a terphenyl-tricarboxylate ligand. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 170-180. doi: 10.11862/CJIC.20250161
14. [14]
  Xuebin XU , Jie CHEN , Gaofeng WANG , Shaofei SONG . Crystal structures and luminescent properties of two isostructural Zn(Ⅱ) complexes constructed from L-tert-leucine Schiff bases ligands. Chinese Journal of Inorganic Chemistry, 2026, 42(6): 1312-1320. doi: 10.11862/CJIC.20250354
15. [15]
  Jimin HOU , Mengyang LI , Chunhua GONG , Shaozhuang ZHANG , Caihong ZHAN , Hao XU , Jingli XIE . Synthesis, structures, and properties of metal-organic frameworks based on bipyridyl ligands and isophthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 549-560. doi: 10.11862/CJIC.20240348
16. [16]
  Yuanpeng Ye , Longfei Yao , Guofeng Liu . Engineering circularly polarized luminescence through symmetry manipulation in achiral tetraphenylpyrazine structures. Chinese Journal of Structural Chemistry, 2025, 44(2): 100460-100460. doi: 10.1016/j.cjsc.2024.100460
17. [17]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
18. [18]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
19. [19]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
20. [20]
  Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two Sm^Ⅲ₄ complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(1701)
HTML views(71)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142