Citation: Chang-Hong LI, Yu-Lin LI, Wei LI, Yun-Fei KUANG. Hydrothermal Synthesis, Crystal Structure and Properties of a New Binuclear Nickel(III) Complex with 3-(Pyridin-2-yl)-1, 2, 4-triazole[J]. Chinese Journal of Structural Chemistry, ;2021, 40(3): 363-368. doi: 10.14102/j.cnki.0254–5861.2011–2931 shu

Hydrothermal Synthesis, Crystal Structure and Properties of a New Binuclear Nickel(III) Complex with 3-(Pyridin-2-yl)-1, 2, 4-triazole

a.
School of Materials and Chemical Engineering, Hunan Institute of Technology, Hengyang 421002, China
b.
School of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, China

Corresponding author: Chang-Hong LI, lichanghong4444@126.com; li_weihnxy@163.com
Received Date: 30 June 2020
Accepted Date: 14 August 2020

Fund Project: the Natural Science Foundation of Hunan Province 2019JJ60021Industry and Research Key Project of Hengyang City 2019jhzx1093Industry and Research Key Project of Hengyang City 2018kKJ016

Figures(6)

A new binuclear nickel(II) complex Ni₂(HPT)₄(H₂O)₃ (1) has been hydrothermally synthesized with nickel hydroxide, 3, 4-pyridine dicarboxylic acid and 3-(pyridin-2-yl)-1, 2, 4-triazole (HPT) in the mixed solution (the volume ratio of methanol and water is 1:4). It crystallizes in tetragonal space group P4₂/n, with a = 20.844(1), b = 20.844(1), c = 7.2463(7) Å, V = 3148.2(5) Å³, D_c = 1.587 g/cm³, Z = 4, μ(MoKa) = 1.257, F(000) = 1544, the final GOOF = 1.043, R = 0.0437 and wR = 0.1297. The crystal structure shows that the whole molecule consists of two nickel ions which are bridged by four μ₂-η¹: η⁰-3-(pyridin-2-yl)-1, 2, 4-triazole anions. The coordination environment of Ni(II) ion is NiN₆, giving a distorted octahedral geometry. The thermal stability and fluorescent and magnetic properties of the complex were investigated.
- binuclear nickel(II) complex,
- thermal stability,
- fluorescent and magnetic properties
1. [1]
  Bharty, M. K.; Kushawaha, S. K.; Chaudhari, U. K.; Dani, R. K.; Maiti, B.; Butcher, R. J. Synthesis, structural characterization, electrochemical studies and DFT calculations on nickel(II) complexes of N-picolinoyl-N΄-benzothioylhydrazide and 5-(pyridine-4-yl)-2H-1, 2, 4-triazole-3-thione. Transit. Met. Chem. 2017, 42, 243–252. doi: 10.1007/s11243-017-0128-x
2. [2]
  Mohapatra, B.; Venkatesh, V.; Verma, S. Crystal engineering with 2-aminopurine containing a carboxylic acid pendant. Cryst. Growth Des. 2014, 14, 5042–5052. doi: 10.1021/cg501142v
3. [3]
  Wen, L. L.; Zhao, J. B.; Lv, K.; Wu, Y. H.; Deng, K. J.; Leng, X. K.; Li, D. F. Visible-light-driven photocatalysts of metal-organic frameworks derived from multi-carboxylic acid and imidazole-based spacer. Cryst. Growth Des. 2017, 12, 1603–1612.
4. [4]
  Yang, E. C.; Zhang, X. Y.; Wang, X. G.; Liu, Z. Y.; Zhao, Z. Y. Four manganese(II) 3-amino-1, 2, 4-triazole complexes incorporated with different polycarboxylate coligands: synthesis, structures and magnetism. Polyhedron 2013, 53, 208–214. doi: 10.1016/j.poly.2013.01.036
5. [5]
  Du, M.; Zhang, Z. H.; You, Y. P.; Zhao, X. J. R-Isophthalate (R = -H, -NO₂, and -COOH) as modular building blocks for mixed-ligand coordination polymers incorporated with a versatile connector 4-amino-3, 5-bis(3-pyridyl)-1, 2, 4-triazole. Cryst. Eng. Comm. 2008, 10, 306–321. doi: 10.1039/B711447H
6. [6]
  Pan, J.; Jiang, F. L.; Wu, M. Y.; Gai, Y. L. A series of d¹⁰ metal clusters constructed by 2, 6-bis[3-(pyrazin-2-yl)-1, 2, 4-triazolyl]pyridine: crystal structures and unusual luminescences. Cryst. Growth Des. 2014, 14, 5011–5018. doi: 10.1021/cg500574x
7. [7]
  Wu, X. X.; Wang, Y. Y.; Yang, P.; Xu, Y. Y.; Huo, J. Z.; Ying, B. D. Syntheses, structural variation, and characterization of a series of crystalline coordination compounds with 4-benzene-1, 2, 4-triazole: polymorph, incomplete spin transition, and single crystal-to-single crystal transformation. Cryst. Growth Des. 2014, 14, 477–490. doi: 10.1021/cg401141a
8. [8]
  Siwatch, R. K.; Yadav, D.; Mukherjee, G.; Rajaraman, G.; Nagendran, S. Synthesis of chalcogeno[3-(pyridyl)-1-azaallyl] germanium complexes. Inorg. Chem. 2014, 53, 5073–5079. doi: 10.1021/ic500116f
9. [9]
  Li, W.; Li, C. H.; Yang, Y. Q.; Li, H. F. Crystal structure, magnetic, fluorescent, electrochemical properties and thermal stability of a new copper(II) coordination polymer [Cu₂(C₅H₄NCOO)₂(C₇H₅N₄)₂]_n. Z. Naturfors-chung, Section B 2015, 70, 215–219. doi: 10.1515/znb-2014-0198
10. [10]
  Li, C. H.; Li, W.; Tan, X. W.; Li, Y. L. Hydrothermal synthesis, crystal structure and properties of one tetranuclear nickel(II) complex with 3-(2-pyridiyl)-1H-1, 2, 4-triazole (Hpt). Chin. J. Struct. Chem. 2018, 37, 1004–1008.
11. [11]
  Li, W.; Liu, Y.; Li, C. H.; Yang, Y. Q. Crystal structure, electrochemical and fluorescent properties of a new copper(II) coordination polymer with 2, 3-pyridinedi-carboxylic acid. Chin. J. Struct. Chem. 2019, 38, 1940–1946.
12. [12]
  Li, C. H.; Li, W.; Tan, X. W.; Li, Y. Y. Hydrothermal synthesis, crystal structure and properties of one tetranuclear nickel(II) complex with 3-(2-pyridiyl)-1H-1, 2, 4-triazole (Hpt). Chin. J. Struct. Chem. 2018, 37, 1004–1008.
13. [13]
  Fang, Z. Y.; Zhang, L.; Ma, J. P.; Zhao, L.; Wang, S. L.; Xie, N. H.; Liu, Y. Q.; Guo, X. Y.; Qin, J. Dinuclear cobalt and nickel complexes of a mercaptoacetic acid substituted 1, 2, 4-triazole ligand: syntheses, structures and urease inhibitory studies. Acta Cryst. Sect. C 2019, 75, 1658–1664. doi: 10.1107/S2053229619015602
14. [14]
  Zhang, Y. J.; Yin, L.; Li, J.; Hu, Z. B.; Ouyang, Z. W.; Song, Y.; Wang, Z. X. Synthesis, crystal structures, HF-EPR, and magnetic properties of six-coordinate transition metal (Co, Ni, and Cu) compounds with a 4-amino-1, 2, 4-triazole Schiff-base ligand. RSC Advanxes 2020, 10, 12833–12840. doi: 10.1039/C9RA10851C
15. [15]
  Liu, F. Y.; Zhou, D. M.; Zhao, X. L.; Kou, J. F. Complexes of nickel(II) and copper(II) with 1, 2, 4-triazole-3-carboxylic acid and of cobalt(III) with 3-amino-1, 2, 4-triazole-5-carboxylic acid. Acta Cryst. Sect. C 2017, 73, 1010–1029. doi: 10.1107/S2053229617012943
16. [16]
  (a) Wu, J. M.; Chen, Y.; Pan, L.; Wang, P. H.; Cui, Y.; Kong, D. C.; Wang, L.; Zhang, X. W.; Zou, J. J. Multi-layer monoclinic BiVO₄, with oxygen vacancies and V⁴⁺, species for highly efficient visible-light photoelectrochemical applications. Appl. Catal. B Environ. 2018, 221, 187–195. (b) Liu, M.; Yu, Y.; Zhang, W. A. A non-enzymatic hydrogen peroxide photoelectrochemical sensor based on BiVO₄ electrode. Electroanal. 2016, 29, 305–311.
17. [17]
  (a) Ratz, G. C.; Triazines, R. N. A new synthesis for 1, 2, 4-triazoles. J. Org. Chem. 1956, 21, 1037–1038. (b) Xu, Y. J.; McLaughlin, M.; Bolton, E. N.; Reamer, R. A. Practical synthesis of functionalized 1, 5-disubstituted 1, 2, 4-triazole derivatives. J. Org. Chem. 2010, 75, 8666–8669. doi: 10.1021/jo1017603
18. [18]
  (a) Sheldrick, G. M. Program for Bruker Area Detector Absorption Correction. University of Gottingen: Gottingen, Germany 2014. (b) Sheldrick, G. M. SHELXS-97, Program for Crystal Structure Solution. University of Gottingen: Gottingen, Germany 2014.
19. [19]
  Li, C. H.; Tan, X. W.; Li, W.; Yang, Y. Q. Hydrothermal synthesis, crystal structure and thermal stability of a binuclear copper(II) complex with 3-(pyridin-2-yl)-1, 2, 4-triazole. Chin. J. Struct. Chem. 2011, 30, 289–292.
20. [20]
  Chen, X. M.; Cai, J. W. Principle and Practice of Single Crystal Structural Analysis. 1st Ed., Beijing, Science press 2004.
21. [21]
  (a) Yuan, S.; Zhang, Y. J.; Hou, J. Y.; Liu, Q. L.; Li, D. P.; Li, Y. X. Syntheses, crystal structures and luminescent properties of two Schiff base complexes. Chin. J. Struct. Chem. 2016, 35, 965–972. (b) Li, J. Rare Earth Luminescent Materials and Their Applications. Chemical Industry Press. China 2003, 170–172.
22. [22]
  Feng, X.; Ma, L. F.; Wang, L. Y.; Zhao, J. S. A unique tetranuclear nickel(II) complex containing pyridine-2-carboxaldehyde derivative bearing an intramolecular acetato: synthesis, crystal structure and magnetic property. Inorg. Chem. Comm. 2011, 14, 584–589. doi: 10.1016/j.inoche.2011.01.030
23. [23]
  Ma, L. F.; Li, X. Q.; Wang, L. Y.; Hou, H. W. Syntheses and characterization of nickel(II) and cobalt(II) coordination polymers based on 5-bromoisophthalate anion and bis(imidazole) ligands. Cryst. Eng. Comm. 2011, 13, 4625–4634. doi: 10.1039/c1ce05308f
24. [24]
  (a) Yan, J. J.; Li, C. H.; Li, W.; Yang, Z. T.; Li, L.; Liu, H. B. Hydrothermal synthesis, crystal structure and properties of a new copper coordination polymer [Cu₂I(C₇H₅N₄)₂]_n with 3-(2-pyridiyl)-1, 2, 4-triazole ligand. Chin. J. Struct. Chem. 2019, 38, 1823–1827. (b) Li, C. H.; Li, W.; Hu, H. X.; Hu, B. N. Hydrothermal synthesis, crystal structure, thermal stability and magnetic properties of dinuclear copper(II) complex. Chin. J. Struct. Chem. 2015, 34, 1553–1557.
1. [1]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
2. [2]
  Tong WANG , Xuefang ZHU , Qi GAO , Hongbo ZHANG , Chao REN , Lixia GE . Luminescence and thermal stability of Tb³⁺-Eu³⁺ doped glass-ceramics containing Na_8.12Y_1.293Si₆O₁₈ crystal phase. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2237-2250. doi: 10.11862/CJIC.20250137
3. [3]
  Dan PENG , Hao WANG , Yanyan WANG , Hongpeng YOU , Wuping LIAO . Synthesis and fluorescent properties of a one-dimensional Tb-calixarene complex as a luminescent thermometer material. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1859-1866. doi: 10.11862/CJIC.20250128
4. [4]
  Zihe SONG , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Crystal structure, thermal analysis, and luminescence properties of six heterocyclic lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 181-192. doi: 10.11862/CJIC.20250126
5. [5]
  Guizhi Zhu , Junrui Tan , Longfei Tan , Qiong Wu , Xiangling Ren , Changhui Fu , Zhihui Chen , Xianwei Meng . Growth of CeCo-MOF in dendritic mesoporous organosilica as highly efficient antioxidant for enhanced thermal stability of silicone rubber. Chinese Chemical Letters, 2025, 36(1): 109669-. doi: 10.1016/j.cclet.2024.109669
6. [6]
  Shi Li , Wenshuai Zhao , Yong Qi , Wenbin Niu , Wei Ma , Bingtao Tang , Shufen Zhang . Hydrogen bonding induced ultra-highly thermal stability of azo dyes for color films. Chinese Chemical Letters, 2025, 36(9): 110653-. doi: 10.1016/j.cclet.2024.110653
7. [7]
  Song-Lin Tian , Li-Na Song , Li-Min Chang , Wan-Qiang Liu , De-Hui Guan , Ji-Jing Xu . A magnetic/thermal coupling assisted lithium-oxygen battery based on magnetic heating effect of single atom-Co/MoS₂ cathode. Chinese Chemical Letters, 2026, 37(8): 111349-. doi: 10.1016/j.cclet.2025.111349
8. [8]
  Mohamed Saber Lassoued , Faizan Ahmad , Yanzhen Zheng . Film thickness effect on 2D lead-free hybrid double perovskite properties: Band gap, photocurrent and stability. Chinese Chemical Letters, 2025, 36(4): 110477-. doi: 10.1016/j.cclet.2024.110477
9. [9]
  Gao-Sheng Zhu , Zhen-Hang Xu , Shao-Zhan Lan , Long Li , Yan-Ying Zheng , Lu Zhang , Qiao-Xia Shang , Bao-Yi Yu , Chong-Chen Wang . Sustainable fungicide delivery via imazalil-functionalized nano-coordination polymer carriers: Enhanced stability, environmental safety, and pH-responsive properties. Chinese Chemical Letters, 2026, 37(2): 111428-. doi: 10.1016/j.cclet.2025.111428
10. [10]
  Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269
11. [11]
  Ya-Ping Liu , Zhi-Rong Gui , Zhen-Wen Zhang , Sai-Kang Wang , Wei Lang , Yanzhu Liu , Qian-Yong Cao . A phenylphenthiazide anchored Tb(Ⅲ)-cyclen complex for fluorescent turn-on sensing of ClO⁻. Chinese Chemical Letters, 2025, 36(2): 109769-. doi: 10.1016/j.cclet.2024.109769
12. [12]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
13. [13]
  Hongyu Tang , Dongming Liu , Jinfu Huang , Liang Zhang , Yang Tang , Bin Huang , Yanwei Li , Shunhua Xiao , Yiling Sun , Renheng Wang . Excellent structural stability and electrochemical properties of LiNi_0.9Co_0.05Mn_0.05O₂ material by surface Ni²⁺ anchoring and Cs⁺ doping. Chinese Chemical Letters, 2025, 36(6): 109987-. doi: 10.1016/j.cclet.2024.109987
14. [14]
  Shanyan Huang , Bi Luo , Zixun Zhang , Qi Wang , Guihui Yu , Xudong Bu , Zheng Huang , Xiaowei Wang , Wei-Li Song , Jiafeng Zhang , Shuqiang Jiao . Effect of crystal morphology of nickel-rich cathode materials on electrochemical stability and ion transport kinetics of sulfide-based all-solid-state batteries. Chinese Chemical Letters, 2026, 37(3): 110729-. doi: 10.1016/j.cclet.2024.110729
15. [15]
  Xianzheng Zhang , Yana Chen , Zhiyong Ye , Huilin Hu , Ling Lei , Feng You , Junlong Yao , Huan Yang , Xueliang Jiang . Magnetic field-assisted microbial corrosion construction iron sulfides incorporated nickel-iron hydroxide towards efficient oxygen evolution. Chinese Journal of Structural Chemistry, 2024, 43(1): 100200-100200. doi: 10.1016/j.cjsc.2023.100200
16. [16]
  Shuangying Li , Qingxiang Zhou , Zhi Li , Menghua Liu , Yanhui Li . Sensitive measurement of silver ions in environmental water samples integrating magnetic ion-imprinted solid phase extraction and carbon dot fluorescent sensor. Chinese Chemical Letters, 2024, 35(5): 108693-. doi: 10.1016/j.cclet.2023.108693
17. [17]
  Zhaodong WANG . In situ synthesis, crystal structure, and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 597-604. doi: 10.11862/CJIC.20240268
18. [18]
  Jiaxin LU , Yifu QIAO , Xing QIANG , Yong GAO , Ziya LIU , Manying ZHANG . Silver-doped antimicrobial fluorescent carbon dots: Dual properties of metal ion detection and antibacterial. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 398-412. doi: 10.11862/CJIC.20250207
19. [19]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
20. [20]
  Yingjian Shang , Xuefeng Zhao , Tao Wu , Yanhui He , Xing Guo , Hongwei Si , Lijuan Jiao , Erhong Hao , Wei Miao . A stereochemically stable double-helical trinuclear bis(tridipyrrin) complex exhibiting near-infrared chiroptical properties. Chinese Journal of Structural Chemistry, 2025, 44(12): 100722-100722. doi: 10.1016/j.cjsc.2025.100722

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(1780)
HTML views(68)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142