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Citation: Chang-Hong LI, Yun-Fei KUANG, Wei LI, Yu-Lin LI. Hydrothermal Synthesis, Crystal Structure and Properties of a New Binuclear Cage-like Yttrium(III) Complex Y2(TMBA)6(phen)2[J]. Chinese Journal of Structural Chemistry, ;2020, 39(11): 2016-2020. doi: 10.14102/j.cnki.0254–5861.2011–2827 shu

Hydrothermal Synthesis, Crystal Structure and Properties of a New Binuclear Cage-like Yttrium(III) Complex Y2(TMBA)6(phen)2

  • a.

    School of Materials and Chemical Engineering, Hunan Institute of Technology, Hengyang 421002, China

  • b.

    School of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, China

  • Corresponding author: Chang-Hong LI, lichanghong4444@126.com Wei LI, li_weihnxy@163.com
    • Li Chang-Hong and Kuang Yun-Fei made equal contributions to this work
  • Received Date: 30 March 2020
    Accepted Date: 13 May 2020

    Fund Project: Natural Science Foundation of Hunan Province 2019JJ60021Industry and Research Key Project of Hengyang City 2019jhzx1093Industry and Research Key Project of Hengyang City 2018kKJ016

Figures(5)

  • A new binuclear cage-like yttrium(III) complex Y2(TMBA)6(phen)2 (1) with yttrium nitrate, 2, 4, 6-trimethylbenzoic acid (TMBA) and 1, 10-phenanthroline (phen) was synthesized. It crystallizes in the triclinic space group P\begin{document}$ \overline 1 $\end{document} with a = 11.9086(15), b = 12.4843(17), c = 14.2101(18) Å, α = 104.977(4), β = 111.750(4), γ = 95.874(5)º, V = 1848.8(4) Å3, Dc = 1.363 g/cm3, Z = 1, μ(MoKa) = 1.627, F(000) = 788, the final GOOF = 1.039, R = 0.0353 and wR = 0.0826. The whole molecule consists of two yttrium ions bridged by four 2, 4, 6-trimethylbenzoic acid anions. The Y(III) ion is coordinated by eight atoms to give a distorted square antiprism coordination geometry. The TG analysis and fluorescent properties of 1 were studied.
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