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Citation: Dong YANG, Rong-Chuan ZHUANG, Jin-Xiao MI, Ya-Xi HUANG. Two Alkali Metal Germanophosphates Na3[Ge(OH)(PO4)2]·2H2O and Li2Na[GeO(HPO4)(PO4)]: Crystal Structures and Thermal Stability[J]. Chinese Journal of Structural Chemistry, ;2021, 40(1): 114-124. doi: 10.14102/j.cnki.0254–5861.2011–2773 shu

Two Alkali Metal Germanophosphates Na3[Ge(OH)(PO4)2]·2H2O and Li2Na[GeO(HPO4)(PO4)]: Crystal Structures and Thermal Stability

  • a.

    Fujian Key Laboratory of Advanced Materials (Xiamen University), Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005, China

  • b.

    State Key Laboratory of Comprehensive Utilization of Low-grade Refractory Gold Ores, Shanghang 364200, China

  • Corresponding author: Ya-Xi HUANG, yaxihuang@xmu.edu.cn
  • Received Date: 19 February 2020
    Accepted Date: 8 May 2020

    Fund Project: the National Natural Science Foundation of China 21201144

Figures(6)

  • Two new alkali metal germanophosphates, namely, Na3[Ge(OH)(PO4)2]·2H2O and Li2Na[GeO(HPO4)(PO4)], have been prepared by solvothermal method, and their crystal structures were determined by single-crystal X-ray diffraction. The title two compounds crystalize in the same orthorhombic space group Pbcm (No. 57) and feature similar chain-like structure which is built from zig-zag GeO6 octahedral thread loop branched by PO4 tetrahedra. For Na3[Ge(OH)(PO4)2]·2H2O, a = 10.1650(9), b = 13.1975(12), c = 6.9751(7) Å, V = 935.73(15) Å3, Z = 4, R = 0.0356 and wR = 0.1109; and for Li2Na[GeO(HPO4)(PO4)], a = 6.9855(5), b = 14.5809(18), c = 6.6620(5) Å, V = 678.56(11) Å3, Z = 4, R = 0.0286, and wR = 0.0762. The partial substitution of Na ions by Li ions not only significantly influences the total structural features and the water molecule contents, but also impacts on their thermal stabilities. Li2Na[GeO(HPO4)(PO4)] is thermally stable up to 400 ℃, whereas only 150 ℃ for Na3[Ge(OH)(PO4)2]·2H2O.
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