Citation: Chen Sun, Kuo Liu, Jian Zhang, Qian Liu, Xijun Liu, Lili Han. In Situ Transmission Electron Microscopy and Three-Dimensional Electron Tomography for Catalyst Studies[J]. Chinese Journal of Structural Chemistry, ;2022, 41(10): 221005. doi: 10.14102/j.cnki.0254-5861.2022-0187 shu

In Situ Transmission Electron Microscopy and Three-Dimensional Electron Tomography for Catalyst Studies

Chen Sun ^{1, 2} ,
Kuo Liu ^{1, 2} ,
Jian Zhang ³ ,
Qian Liu ⁴ ,
Xijun Liu ⁵ ,
Lili Han ^2,,

1.
College of Chemistry, Fuzhou University, Fuzhou 350116, China
2.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
3.
Key Laboratory of Spin Electron and Nanomaterials of Anhui Higher Education Institutes, Suzhou University, Suzhou 234000, China
4.
Institute for Advanced Study, Chengdu University, Chengdu 610106 China
5.
MOE Key Laboratory of New Processing Technology for Non-Ferrous Metals and Materials, and Guangxi Key Laboratory of Processing for Non-Ferrous Metals and Featured Materials, School of Resource, Environments and Materials, Guangxi University, Nanning 530004, China

Author Bio: Chen Sun received his B.Eng. degree from School of Chemistry and Chemical Engineering, Shandong University of Technology in 2020. He is a master candidate in College of Chemistry of Fuzhou University, and joint cultivation in the Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences. His current research interests include obtaining three-dimensional structural and chemical information of nanocatalytic materials by electron tomography
Kuo Liu received his B.Eng. degree from College of Materials Science and Engineering, Qingdao University of Science and Technology in 2020. He is candidate in College of Chemistry of Fuzhou University, and joint cultivation in the Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences. His current research interests include thermal catalytic materials observed by in situ transmission electron microscopy
Jian Zhang received his Ph.D. degree from Northeastern University in 2022. His current research interests include: (1) the synthesis of non-noble metal-based catalysts for electrochemical applications in water splitting; (2) the structural evolution of catalysts under in situ heating
Qian Liu received her Ph.D. in the Faculty of Materials and Energy, Southwest University in 2018. She is currently a researcher in the Institute for Advanced Study, Chengdu University. Her research interests are in the synthesis of crystalline materials, electrocatalysts for water electrolysis and ammonia production
Xijun Liu received his Ph.D. degree from College of Science, Beijing University of Chemical Technology in 2014. Then, he joined the School of Materials Science and Engineering of Tianjin University of Technology. Currently, he is a fulltime professor at School of Resource, Environments and Materials of Guangxi University. His current scientific interests focus on nanomaterials, heterogeneous catalysis, and materials design for catalysts and energy conversion/storage
Lili Han received her Ph.D. degree from Tianjin University in 2016. Then, she was appointed by Tianjin University of Technology. From 2018 to 2019, she is a research associate at Brookhaven National Laboratory, USA. From 2019 to 2021, she is a postdoc at University of California, Irvine, USA. From 2021 to now, she is a professor, PI, and group leader at Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, China. Her research focuses on transmission electron microscopy, electron tomography, nanocatalysis, and single-atom electrocatalysis
Corresponding author: Lili Han, llhan@fjirsm.ac.cn
Received Date: 16 August 2022
Accepted Date: 13 September 2022
Available Online: 20 September 2022

Figures(13)

An in-depth understanding of the catalytic reaction mechanism is the key to designing efficient and stable catalysts. In situ transmission electron microscope (TEM) is the most powerful tool to visualize and analyze the microstructures of catalysts during catalysis. In situ TEM combined with three-dimensional (3D) electron tomography (ET) reconstruction technique enables interrogations of catalysts' structural dynamics and chemical changes in high temporal and spatial dimensions. In this review, we discuss and summarize the recent advances in in situ TEM together with 3D ET for catalyst studies. Topics include the latest research progress of in situ TEM imaging as well as 3D visualization and quantitative analysis of catalysts. We also pay particular attention to artificial intelligence (AI)-enhanced smart 3D ET. These include deep learning (DL)-based data compression and storage for the analysis of large TEM data, recovery of wedge-shaped information lost in 3D ET reconstructions, and DL models for reducing residual artifacts in 3D reconstructed images. Finally, the challenges and development prospects of current in situ TEM and 3D ET research are discussed.
- in situ TEM,
- catalyst,
- electron tomography,
- 3D reconstruction,
- artificial intelligence,
- machine learning
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沈阳化工大学材料科学与工程学院沈阳 110142