Citation: Lei Xie, Chaoqin Huang, Zhaofeng Liang, Hongbing Wang, Zheng Jiang, Fei Song. In-Situ HP-STM and Operando EC-STM Studies of Heterogeneous Catalysis at Interfaces[J]. Chinese Journal of Structural Chemistry, ;2022, 41(10): 221002. doi: 10.14102/j.cnki.0254-5861.2022-0136 shu

In-Situ HP-STM and Operando EC-STM Studies of Heterogeneous Catalysis at Interfaces

Lei Xie ^1,, ,
Chaoqin Huang ^{2, 3} ,
Zhaofeng Liang ¹ ,
Hongbing Wang ^{2, 3} ,
Zheng Jiang ^{1, 2, 3} ,
Fei Song ^{1, 2, 3,,}

1.
Shanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201204, China
2.
Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201000, China
3.
University of Chinese Academy of Sciences, Beijing 101000, China

Author Bio: Lei Xie received her PhD degree in materials science and technology from Tongji University in 2019. Afterwards, she became an engineer at Shanghai Advanced Research Institute, Chinese Academy of Sciences. Her research interest focuses on the characterization of physical and chemical properties of surfaces, especially by scanning tunneling microscopy

Fei Song received his PhD degree in Condensed Matter Physics from Zhejiang University and Aarhus University in 2009. He then moved to Norwegian and the Netherlands for postdoctoral research. He became an independent research fellow at Shanghai Institute of Applied Physics, Chinese Academy of Sciences in 2015, and is now a full professor at Shanghai Synchrotron Radiation Facility. His research interest is mainly focused on novel nanostructures characterization and manipulation at surface and interface
Corresponding author: Lei Xie, xiel@sari.ac.cn Fei Song, songf@sari.ac.cn
Received Date: 25 May 2022
Accepted Date: 13 June 2022
Available Online: 17 June 2022

Figures(14)

Heterogeneous catalysis taking place at solid interfaces plays a crucial role not only in industrial chemical production, energy conversion but also in fundamental research. The dynamic evolution of surface morphology and composition requires full understanding especially under realistic reaction conditions. To this end, conventional scanning tunneling microscopy (STM) has been integrated with high pressure cell and electrochemical cell, forming high pressure (HP) STM and electrochemical (EC) STM for the in-situ/operando characterization at solid-gas and solid-liquid interfaces with atomic resolution, respectively. In this review, we attempt to give a brief introduction to the development and working principle of these two techniques and subsequently summarize several representative progresses in recent days. The dynamic changes in active sites, surface reconstruction, absorbates alteration and products formation are directly characterized in a combination with other surface sensitive technologies. The correlation between surface structures and catalytic performance as well as the underlying mechanism can thus be unraveled, which provides insights into the rational design and optimization of catalysts.
- HP-STM,
- EC-STM,
- heterogeneous catalysis,
- in-situ,
- operando,
- interfaces
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