Citation: Yu Zhang, Shan-Shan Liu, Bo Li, Hanqi You, Longxi Zhang, Zhenyi Zhang, Hong-Ying Zang, Qi Zheng, Weimin Xuan. Sulfonate-Functionalized Polyoxovanadate-Based Metal-Organic Polyhedra for Enhanced Proton Conduction via the Synergy of Linker and Metal Cluster Vertex[J]. Chinese Journal of Structural Chemistry, ;2022, 41(8): 220801. doi: 10.14102/j.cnki.0254-5861.2022-0127 shu

Sulfonate-Functionalized Polyoxovanadate-Based Metal-Organic Polyhedra for Enhanced Proton Conduction via the Synergy of Linker and Metal Cluster Vertex

Yu Zhang ^{1, †} ,
Shan-Shan Liu ^{1, †} ,
Bo Li ^{2, †} ,
Hanqi You ¹ ,
Longxi Zhang ¹ ,
Zhenyi Zhang ³ ,
Hong-Ying Zang ^2,, ,
Qi Zheng ^4,, ,
Weimin Xuan ^1,,

1.
College of Chemistry, Chemical Engineering and Biotechnology & State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Shanghai 201620, China
2.
Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education at Universities of Jilin Province, Faculty of Chemistry, Northeast Normal University, Changchun 130024, China
3.
Bruker (Beijing) Scientific Technology Co., Ltd 9F, Building No.1, Lane 2570, Hechuan Rd, Minhang District, Shanghai 200233, China
4.
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China

Corresponding author: Hong-Ying Zang, zanghy100@nenu.edu.cn Qi Zheng, qi.zheng@dhu.edu.cn Weimin Xuan, weiminxuan@dhu.edu.cn
Received Date: 18 May 2022
Accepted Date: 12 June 2022
Available Online: 20 June 2022

Figures(4)

Metal-organic polyhedra (MOPs) have emerged as novel porous platforms for proton conduction, however, the concerted employment of both linker and metal cluster vertex is rarely applied for the fabrication of MOPs-based high conducting materials. Herein we report the synthesis of sulfonate-functionalized polyoxovanadate-based MOPs for enhanced proton conduction via the synergistic effect from linker and metal cluster node. MOPs 1 and 2 exhibit octahedral cage configuration constructed from {V₅O₉Cl} vertex and 5-sulfoisophthalate linker. Owing to the ordered packing of octahedral cages along three axes, 3D interpenetrated open channels that are lined with high-density sulfonates are thus formed within 2. Coupled with the proton-conductive {V₅O₉Cl} vertexs as well as protonated counterions, an extensive H-bonded network is therefore generated for facile proton transfer. 2 exhibits high proton conductivity of 3.02×10^-2 S cm^-1 at 65 ℃ under 90% RH, recording the highest value for MOPs pellet sample. This value is enhanced ~1 order of magnitude compared with that of carboxylate-functionalized analogue 3, clearly illustrating the advantage of combining linker and metal cluster node for enhanced proton conduction. This work will further promote the exploitation of high proton conductive MOPs-based materials by the synergy design strategy.
- metal-organic polyhedra,
- proton conduction,
- polyoxovanadate,
- synergistic effect
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沈阳化工大学材料科学与工程学院沈阳 110142