Citation: Hongdong Li, Yue Pan, Jianping Lai, Lei Wang, Shouhua Feng. Strong High Entropy Alloy-Support Interaction Enables Efficient Electrocatalytic Water Splitting at High Current Density[J]. Chinese Journal of Structural Chemistry, ;2022, 41(8): 220800. doi: 10.14102/j.cnki.0254-5861.2022-0125 shu

Strong High Entropy Alloy-Support Interaction Enables Efficient Electrocatalytic Water Splitting at High Current Density

Hongdong Li ¹ ,
Yue Pan ¹ ,
Jianping Lai ^1,, ,
Lei Wang ^{1, 2,,} ,
Shouhua Feng ¹

1.
Key Laboratory of Eco-chemical Engineering, Taishan Scholar Advantage and Characteristic Discipline Team of Eco-chemical Process and Technology, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
2.
Shandong Engineering Research Center for Marine Environment Corrosion and Safety Protection, College of Environment and Safety Engineering, Qingdao University of Science and Technology, Qingdao 266042, China

Corresponding author: Jianping Lai, jplai@qust.edu.cn Lei Wang, inorchemwl@126.com
Received Date: 16 May 2022
Accepted Date: 26 May 2022
Available Online: 2 June 2022

Figures(5)

In electrocatalysis, the stability issue between catalyst and support still needs great attention. Here, a series of high-entropy alloy nanoparticles (HEA-NPs) embedded in carbon cloth (CC) were synthesized by using the scalable strategy-microwave heating. Among them, PtRhCoNiCu/CC exhibits outstanding hydrogen evolution reaction (HER) activity (19 and 170 mV overpotential at 10 and 1000 mA cm^-2) and stability (150 h), outperforming other recently reported HEAs catalysts. IrRuCoNiCu/CC displays superior oxygen evolution reaction (OER) activity (166 and 354 mV overpotential at 10 and 1000 mA cm^-2) and stability (150 h), and shows a lower overpotential than recently reported HEA catalysts. In water splitting, IrRuCoNiCu/CC(+)//PtRhCoNiCu/CC(-) electrolyzer achieves 500 mA cm^-2 (1000 mA cm^-2) high current density at 1.76 V (1.88 V) and exhibits excellent stability, which is one of the best catalysts currently. Therefore, the novel supported HEA catalyst with high stability is expected to be a promising candidate material for industrialized water splitting.
- high entropy alloy,
- metal-support interactions,
- microwave heating,
- water splitting,
- activity and durability
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沈阳化工大学材料科学与工程学院沈阳 110142