Citation: Feng-Ge Wang, Xin Liu, Qian-Xi Lv, Bin Liu, Yong-Ming Chai, Bin Dong. Transition Metal Boride-Based Materials for Electrocatalytic Water Splitting[J]. Chinese Journal of Structural Chemistry, ;2022, 41(9): 220900. doi: 10.14102/j.cnki.0254-5861.2022-0117 shu

Transition Metal Boride-Based Materials for Electrocatalytic Water Splitting

Feng-Ge Wang ¹ ,
Xin Liu ¹ ,
Qian-Xi Lv ¹ ,
Bin Liu ^1,, ,
Yong-Ming Chai ¹ ,
Bin Dong ^1,,

1.
State Key Laboratory of Heavy Oil Processing, College of Chemistry and Chemical Engineering, China University of Petroleum (East China), Qingdao 266580, China

Author Bio: Feng-Ge Wang received her B.Eng. degree in Chemical Engineering and Process from Weifang University in 2020. She is currently a master's student in the research group of Associate Professors Dong Bin and Liu Bin at China University of Petroleum (East China). Her research interests focus on nanostructures for electrocatalysis
Xin Liu received her B.Eng. degree in Chemical Engineering and Technology from Qingdao University of Science and Technology in 2021. She is currently a master's student in chemical engineering at China University of Petroleum (East China). Her research interest covers electrocatalytic nanostructures
Qian-Xi Lv received his B.S. degree in Chemistry from China University of Petroleum (East China) in 2022. He is currently a M.S. student in Prof. Bin Dong's group at China University of Petroleum (East China). His research direction is electrolytic water catalyst
Dr. Bin Liu received his B.Eng. degree in Chemical Engineering and Process from China University of Petroleum (East China) in 2007, and Ph.D. degree in Chemical Engineering and Technology from China University of Petroleum (East China) in 2012. He is currently an associate professor at University of Petroleum (East China). His research interests include green petroleum refining process, clean oil hydrogenation catalyst and process, biomass efficient catalytic hydrogenation conversion, new energy catalytic conversion and waste green resource utilization
Prof. Yong-Ming Chai received his Ph.D. from China University of Petroleum (East China) in 2008. Now he is a professor in State Key Laboratory of Heavy Oil Processing, College of Chemistry and Chemical Engineering, China University of Petroleum (East China). He was doing research as a visiting scholar in Marquette University from 2015.03 to 2016.03. His research interests are catalyst of hydrodesulfurization process of heavy oil and transition metal-based electrocatalysts
Dr. Bin Dong received his B.S. and Ph.D. from Lanzhou University in 2002 and 2008, respectively. He was doing research as a visiting scholar in Marquette University from 2014.03 to 2015.03. Now Dr. Dong is an Associate Professor in College of Chemistry and Chemical Engineering, China University of Petroleum (East China). His research interests mainly focus on the transition metal-based functional materials for energy conversion and storage including electrocatalysis and photoelectrocatalysis for small molecules
Corresponding author: Bin Liu, liubin@upc.edu.cn Bin Dong, dongbin@upc.edu.cn
Received Date: 10 May 2022
Accepted Date: 19 May 2022
Available Online: 26 May 2022

Figures(13)

Electrocatalytic water splitting to produce hydrogen is an eco-friendly way to achieve sustainable utilization of renewable energy.The industrial application of water electrolysis, which is severely limited by slow kinetic reactions on electrode surfaces, requires the development of highly reactive, low-cost and stable electrocatalytic materials. Transition metal borides/borates have recently emerged as promising electrocatalytic materials for catalyzing hydrogen/oxygen evolution reactions (HER/OER) in inexpensive electrolyzers. However, so far, there has been little comprehensive summary of transition metal borides/borates. Here, this review provides the latest research progress on transition metal borides/borates for electrocatalytic water splitting. The structural characteristics of transition metal borides/borates and their synthesis methods in recent years are discussed. Then, the theoretical and experimental progress of transition metal borides including single-metal borides, multi-metal borides, borate derived and other nanocomposites containing boron (boron-doped nanocomposites/substrate with boron) in electrocatalytic reaction and the role of boron in regulating electrocatalytic performance are further emphasized. Finally, the potential challenges and future prospects of transition metal borides/borates in electrocatalysis are presented.
- transition metal borides/borates,
- electrocatalysts,
- hydrogen evolution reaction (HER),
- oxygen evolution reaction (OER),
- overall water splitting
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