Citation: Wanlin Zhou, Jingjing Jiang, Weiren Cheng, Hui Su, Qinghua Liu. In-Situ Synchrotron Radiation Infrared Spectroscopic Identification of Reactive Intermediates over Multiphase Electrocatalytic Interfaces[J]. Chinese Journal of Structural Chemistry, ;2022, 41(10): 221000. doi: 10.14102/j.cnki.0254-5861.2022-0083 shu

In-Situ Synchrotron Radiation Infrared Spectroscopic Identification of Reactive Intermediates over Multiphase Electrocatalytic Interfaces

1.
National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029, China

Author Bio: Wanlin Zhou received her B.S. degree from the Northeastern University in June 2018. She is currently studying for her Ph.D. degree at University of Science and Technology of China (USTC). Her current research focuses on the design and characterization of electrocatalysts for industrial energy storage and conversion technologies. She specializes in tracing the local structure evolution and catalytic dynamics of heterogeneous catalytic interfaces by using in-situ synchrotron radiation XAS and FTIR techniques
Jingjing Jiang received her B.S. degree from the Anhui University in June 2021. She is currently studying for a doctorate at University of Science and Technology of China under the supervision of Prof. Shiqiang Wei and Prof
Weiren Cheng received his Ph.D. degree from the University of Science and Technology of China (USTC) in June 2015, and is a member of National Synchrotron Radiation Laboratory, USTC, and a foreign researcher in Hokkaido University, Japan, now. He currently interests in the design and synthesis of advanced functional nanomaterials for energy-related applications as well as the understanding of their catalytic mechanisms by in-situ synchrotron techniques
Hui Su received his B.S. degree from the Hefei University of Technology in June 2015 and Ph.D. degree from the University of Science and Technology of China (USTC) in June 2020, and is a member of National Synchrotron Radiation Laboratory, USTC. His current research focuses on engineering nanoscale catalysts at the atomic scale to enable high efficiency renewable energy conversion, and probing and understanding of nanoscale catalysts dynamic structure evolution at solid-liquid interface for reaction kinetics studies by operando synchrotron radiation XAS & FTIR techniques
Qinghua Liu is currently a doctoral supervisor of National Synchrotron Radiation Laboratory, University of Science and Technology of China (USTC). He received his Ph.D. in 2009 from USTC and subsequently performed research work on renewable energy conversion and synchrotron radiation experimental techniques. His current research interests focus on the synthesis and characterization of advanced energy functional nanomaterials for photocatalytic, electrochemical, and photoelectrochemical applications and the development of advanced in situ/operando synchrotron radiation experimental techniques and their applications in energy storage and reaction mechanisms
Corresponding author: Hui Su, suhui@ustc.edu.cn Qinghua Liu, qhliu@ustc.edu.cn
Received Date: 12 April 2022
Accepted Date: 30 April 2022
Available Online: 12 May 2022

Figures(7)

A comprehensive understanding of the microscopic reaction mechanisms at the gas-solid-liquid electrochemical interfaces is urgently required for the development of advanced electrocatalysts applied in burgeoning sustainable energy conversion systems. In-situ synchrotron radiation Fourier transform infrared (SR-FTIR) spectroscopy is one of the most powerful techniques for investigating the evolving dynamics of reactive intermediates during electrocatalytic reactions. In this review, we methodically summarize the recent progress in the research of dynamic mechanisms for valuable electrocatalytic reactions based on in-situ SR-FTIR methodology. Moreover, the merits and drawbacks of SR-FTIR spectroscopy, the design principles of infrared beam setups and in-situ cells, as well as the in-situ measurement criteria are also discussed in detail. Lastly, the potential challenges and opportunities in this field are prudently stated. This review is expected to stimulate a broad interest in the material science and electrochemistry communities for exploring the dynamic mechanisms of prominent catalysis at the atomic/molecular level by using SR-based spectroscopy.
- synchrotron radiation,
- infrared spectroscopy,
- in-situ,
- reaction dynamics
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