Citation: Yaoyao Chen, Changhao Gao, Tian Yang, Wenjing Li, Haojie Xu, Zhihua Sun. Research Advances of Ferroelectric Semiconductors of 2D Hybrid Perovskites toward Photoelectronic Applications[J]. Chinese Journal of Structural Chemistry, ;2022, 41(4): 220400. doi: 10.14102/j.cnki.0254-5861.2022-0013 shu

Research Advances of Ferroelectric Semiconductors of 2D Hybrid Perovskites toward Photoelectronic Applications

Yaoyao Chen ^{1, 2, †} ,
Changhao Gao ^{1, 2, †} ,
Tian Yang ^{1, 2} ,
Wenjing Li ^{1, 3} ,
Haojie Xu ^{1, 3} ,
Zhihua Sun ^{1, 2, 3,,}

1.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
2.
College of Chemistry, Fuzhou University, Fuzhou 350108, China
3.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Zhihua Sun, sunzhihua@fjirsm.ac.cn
Received Date: 19 January 2022
Accepted Date: 11 February 2022

Figures(12)

Ferroelectric materials, characterized by the switchable spontaneous polarization (P_s) through reversing the directions of external electric field, exhibit versatile physical attributes that have been extensively used for practical device applications. Two-dimensional (2D) organic-inorganic hybrid perovskites are recently emerging as a robust family of candidate ferroelectrics, termed ferroelectric semiconductors. In particular, the coexistence and/or coupling of ferroelectric polarization with their semiconducting properties enables new physical concepts, thus providing a potential platform for the development of new multifunctional optoelectronic devices. This review primarily describes the structural origin of symmetry breaking for generating ferroelectric orders in 2D hybrid perovskites, and then presents the combination of ferroelectric P_s with other semiconducting optoelectronic activities. Regarding the emergence of new photoelectric behaviors, the prospects for this 2D family of ferroelectric semiconductors are further discussed, along with their development tendency for the future photoelectronic device applications.
- ferroelectric materials,
- hybrid perovskites,
- semiconductor properties,
- two-dimensional
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沈阳化工大学材料科学与工程学院沈阳 110142