Citation: Hui-Chao GUAN, Xiao-Tong SONG, Gui-Bao LIU, Shu-Mei YUE. Syntheses, Crystal Structures and DNA-Binding Properties of Zn(II) and Mn(II) Complexes Based on Imidazole Derivatives and Carboxylic Acid[J]. Chinese Journal of Structural Chemistry, ;2022, 41(3): 220326. doi: 10.14102/j.cnki.0254-5861.2011-3363 shu

Syntheses, Crystal Structures and DNA-Binding Properties of Zn(II) and Mn(II) Complexes Based on Imidazole Derivatives and Carboxylic Acid

College of Chemistry, Changchun Normal University, Changchun 130032, China

Corresponding author: Shu-Mei YUE, 1620520613@qq.com
Received Date: 16 September 2021
Accepted Date: 19 October 2021

Figures(14)

Complexes [Zn(pbm)(5-hip)₃] (1), [Zn(pbm)(5-nip)₃] (2), [Mn(pbm)(H₃btc)₂(H₂O)] (3) and [Mn(pbm)(5-nip)₃] (4), where H₂HIPA = 5-hydroxyisophthalic acid, H₂nip = 5-nitroisophthalic acid, H₃btc = trimesic acid and pbm (pyridine benzene chelate material) = 2-(2-pyridyl)benzimidazole, were identified via single-crystal XRD analyses. 1, 2 and 4 pertain to the monoclinic space group C2/c, while 3 belongs to the triclinic space group P\begin{document}$ \overline 1 $\end{document}. The interplay of CT-DNA with those complexes was delineated using ultraviolet, fluorescence, and circular dichroism (CD) spectroscopy and viscosity measurements. Complexes 1, 2, 3 and 4 interact with CT-DNA in an electrostatic or grooving mode. We wish to offer a theory-wise foundation for developing anti-tumor medicines.
- single-crystal structures,
- spectroscopy,
- CT-DNA binding,
- 2-(2-pyridyl)benzimidazole
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