Citation: Li-Xin LI, Chen CHEN, Zi-Hao LI, Fei-Fei WANG, Yun LIU, Zhi-Guo YI. Controllable Synthesis, Polar Behavior and Photoelectric Properties of BiOCl Microplates[J]. Chinese Journal of Structural Chemistry, ;2022, 41(3): 220307. doi: 10.14102/j.cnki.0254-5861.2011-3352 shu

Controllable Synthesis, Polar Behavior and Photoelectric Properties of BiOCl Microplates

Li-Xin LI ^{a, b} ,
Chen CHEN ^b ,
Zi-Hao LI ^a ,
Fei-Fei WANG ^a,, ,
Yun LIU ^c,, ,
Zhi-Guo YI ^b,,

a.
Key Laboratory of Optoelectronic Material and Device, Department of Physics, Shanghai Normal University, Shanghai 200444, China
b.
State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201800, China
c.
Research School of Chemistry, The Australian National University, Canberra, ACT 2600, Australia

Corresponding author: Fei-Fei WANG, f_f_w@sohu.com Yun LIU, yliu@rsc.anu.edu.au Zhi-Guo YI, zhiguo@mail.sic.ac.cn
Received Date: 3 September 2021
Accepted Date: 10 November 2021

Fund Project: the National Natural Science Foundation of China 51872311the National Natural Science Foundation of China 51902331the National Natural Science Foundation of China 11974250the Shanghai International Science and Technology Cooperation Fund Project 18520723200the Science and Technology Commission of Shanghai Municipality 19070502800the Science and Technology Commission of Shanghai Municipality 19ZR1464900the Frontier Science Key Project of the Chinese Academy of Sciences QYZDB-SSW-JSC027

Figures(5)

Bismuth oxychloride (BiOCl) square microplates were prepared via a facile hydrothermal method. The X-ray diffraction patterns of the samples reveal a tetragonal BiOCl phase, and the scanning electron microscopy images show plate-like structures with large lateral size of 3~6 μm and thickness in the range of 100~300 nm. The effects of surfactant, reaction temperature and duration on the morphology of BiOCl powders are systematically investigated. The polar behavior of a BiOCl single-crystalline microplate is examined by using piezoresponse force microscopy evidenced over 80 pm displacement under 40 V bias voltage. In addition, the photoelectric performance of the BiOCl microplates is evaluated by using electrochemical workstation with three-electrode system, and large photocurrent densities (over 0.5 μA/cm²) and fast photoresponse (0.7~1.1 s) are detected by applying both 365 nm monochromatic light and sunlight illumination. The surface potential changes of BiOCl microplate under different light condition, characterized by in-situ Kelvin probe force microscopy, further verify the separation ability of the photo-induced charge carriers. These findings would be beneficial for further design photocatalytic and piezocatalytic materials.
- bismuth oxychloride,
- photoelectric,
- microplate,
- hydrothermal method
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