Citation: Rui-Xue ZHUGE, Peng-Chao SHI, Teng ZHANG. MOF-Conductive Polymer Composite Film as Electrocatalyst for Oxygen Reduction in Acidic Media[J]. Chinese Journal of Structural Chemistry, ;2022, 41(3): 220306. doi: 10.14102/j.cnki.0254-5861.2011-3350 shu

MOF-Conductive Polymer Composite Film as Electrocatalyst for Oxygen Reduction in Acidic Media

Rui-Xue ZHUGE ^{a, b} ,
Peng-Chao SHI ^{b, c} ,
Teng ZHANG ^{b, c,,}

a.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
University of the Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Teng ZHANG, zhangteng@fjirsm.ac.cn
Received Date: 1 September 2021
Accepted Date: 18 November 2021

Fund Project:

Figures(4)

A metal-organic framework (MOF)-conductive polymer composite film was constructed from PCN-222(Fe) nanoparticles and PEDOT: PSS solution by simple drop-casting approach. The composite film was tested as an electrocatalytic device for oxygen reduction reaction (ORR). The combination of PCN-222(Fe) MOF particles and conductive PEDOT matrix facilitates electron transfer in the composite material and improves the ORR performance of PCN-222(Fe). Levich plot and H₂O₂ quantification experiment show that PCN-222(Fe)/PEDOT: PSS film mainly catalyzes two-electron oxygen reduction and produces H₂O₂.
- metal-organic frameworks (MOFs),
- conductive polymer,
- porphyrin,
- oxygen reduction reaction (ORR),
- electrocatalysis
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