Citation: Ying-Qun YANG, Chang-Hong LI, Wei LI, Tian-Yi YANG. Synthesis and Properties of Dinuclear Europium(Ⅲ) Complex Containing 2-Benzoylbenzoic Acid[J]. Chinese Journal of Structural Chemistry, ;2022, 41(3): 220324. doi: 10.14102/j.cnki.0254-5861.2011-3348 shu

Synthesis and Properties of Dinuclear Europium(Ⅲ) Complex Containing 2-Benzoylbenzoic Acid

Ying-Qun YANG ^{a, b,,} ,
Chang-Hong LI ^c,, ,
Wei LI ^{a, b,,} ,
Tian-Yi YANG ^b

a.
Key Laboratory of Functional Metal-organic Compounds of Hunan Province & Key Laboratory of Functional Organometallic Materials of Hunan Province College, Hengyang 421008, China
b.
Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, China
c.
School of Materials and Chemical Engineering, Hunan Institute of Technology, Hengyang 421002, China

Corresponding author: Ying-Qun YANG, yingqunyq@163.com Chang-Hong LI, lichanghong4444@126.com Wei LI, li_weihnxy@163.com
Received Date: 30 August 2021
Accepted Date: 1 November 2021

Fund Project: the Foundation of Key Laboratory of Functional Metal-organic Compounds of Hunan Province MO20K05Natural Science Foundation of Hunan Province 2019JJ60021Natural Science Foundation of Hunan Province 2019JJ50013the Scientific Research Found of Hunan Provincial Education Department of China 17A049

Figures(4)

A new europium(Ⅲ) complex [Eu₂(C₁₄H₉O₃)₆(2, 2΄-bipy)₂]·(2, 2΄-bipy)₂ has been synthesized with 2-benzoylbenzoic acid and 2, 2΄-bipyridine as ligands. Crystal data: triclinic, space group P\begin{document}$ \overline 1 $\end{document}, with a = 13.5251(5), b = 13.9453(5), c = 15.3582(5) Å, α = 76.922(3)º, β = 79.740(3)º, γ = 64.248(4)º, V = 2530.83(18) Å³, D_c = 1.496 g/cm³, Z = 1, μ(MoKα) = 1.305 mm^-1, F(000) = 1156, the final R= 0.0340 and wR = 0.0638. The Eu(Ⅲ) ion is coordinated by eight atoms to give a distorted square antiprism coordination geometry. The complex exhibits antiferromagnetism in the temperature range of 300~2 K, and two intense fluorescence emission bands arising from the transitions of Eu³⁺: ⁵D₀ → ⁷F₁ (595 nm) and ⁵D₀ → ⁷F₂ (618 nm), respectively. In addition, the fluorescence sensing properties of the complex in CrO₄^2- solution were studied.
- europium(Ⅲ) complex,
- crystal structure,
- magnetic and fluorescent properties
1. [1]
  Kumar, M.; Li, L. Q.; Zaręba, J. K.; Tashi, L.; Sahoo, S. C.; Nyk, M.; Liu, S. J.; Sheik, H. N. Lanthanide contraction in action: structural variations in 13 lanthanide(Ⅲ) thiophene-2, 5-dicarboxylate coordination polymers (Ln = La~Lu, except Pm and Tm) featuring magnetocaloric effect, slow magnetic relaxation, and luminescence-lifetime-based thermometry. Cryst. Growth Des. 2020, 20, 6430–6452. doi: 10.1021/acs.cgd.0c00611
2. [2]
  Li, Y. J.; Chen, X. T.; Gong, Y. Photoluminescence of LaI₃ switched on and off by association and dissociation of non-luminescent tetrahydrofuran. Dalton Trans. 2021, 50, 3797–3800. doi: 10.1039/D1DT00162K
3. [3]
  Petrov, B. I.; Balashova, T. V.; Pochekutova, T. S.; Lazarev, N. M.; Kuzmichev, V. V. Temperature dependences of the saturated vapor pressure of lantanum complexes based on 2-(2-benzoxazol-2-yl)phenolate ligand. Russ. J. Gen. Chem. 2019, 89, 1822–1825. doi: 10.1134/S1070363219090159
4. [4]
  Yang, Y. Q.; Yang, Y.; Li, J. D.; Li, W. Synthesis and the fluorescent, magnetic and thermal stability properties of a new terbium(Ⅲ) complex Tb(C₂₀H₁₄O₃N)₃(C₁₂H₈N₂)(H₂O)·H₂O. Chin. J. Struct. Chem. 2019, 38, 2129–2134.
5. [5]
  Li, W.; Peng, G.; Lai, H.; Huang, G.; Li, C. H. Hydrothermal synthesis, crystal structure and luminescence property of a new binuclear cage-like samarium(Ⅲ) complex Sm₂(C₇H₄ClCOO)₆(C₁₂H₈N₂)₂(H₂O)₂. Chin. J. Struct. Chem. 2020, 39, 350–355.
6. [6]
  Wang, M. L.; Zhang, X. H.; Yin, H. Z.; Xu, K. The fluorescence terbium complex and its application in wavelength conversion membrane. Spectrosc. Spect. Anal. 2013, 33, 1009–1013.
7. [7]
  Song, Y. J.; Sun, J.; Yan, L. L.; Zhu, P.; Yu, W. S.; Li, J. Preparation and properties of Eu_0.5La_0.5(TTA)₃/PMMA temperature sensitive paint. J. Chin. Rare Earth Soc. 2013, 31, 55–57.
8. [8]
  Wang, H. S.; Wang, L.; Li, G. C.; Li, Y. Y.; Huang, B. J.; Wu, C. Z. Synthesis, structure and luminescent property of 1D complex [Tb(3, 5-pdc)(3, 5-Hpdc)(H₂O)(phen)]_n. Chin. J. Lumin. 2015, 36, 50–56. doi: 10.3788/fgxb20153601.0050
9. [9]
  Liu, M. J.; Ye, Z. Q.; Xin, C. L.; Yuan, J. L. Development of a ratiometric time-resolved luminescence sensor for pH based on lanthanide complexes. Anal. Chim. Acta 2013, 761, 149–156. doi: 10.1016/j.aca.2012.11.025
10. [10]
  Gupta, A.; Garg, M.; Singh, S.; Deep, A.; Sharma, A. L. Highly sensitive optical detection of escherichia coli using terbium based metal-organic framework. ACS Appl. Mater. Inter. 2020, 12, 48198–48205. doi: 10.1021/acsami.0c14312
11. [11]
  Yan, B.; Wang, Q. M. Two luminescent molecular hybrids composed of bridged Eu(Ⅲ)-β-diketone chelates covalently trapped in silica and titanate gels. Cryst. Growth Des. 2008, 8, 1484–1489. doi: 10.1021/cg0603725
12. [12]
  Xin, H.; Shi, M.; Zhang, X. M.; Li, F. Y.; Bian, Z. Q.; Ibrahim, K.; Liu, F. Q.; Huang, C. H. Carrier-transport, photoluminescence, and electroluminescence properties comparison of a series of terbium complexes with different structures. Chem. Mater. 2003, 15, 3728–3733. doi: 10.1021/cm0344414
13. [13]
  Li, D. P.; Feng, Y. L.; Chen, Z. M.; Kuang, D. Z.; Zhang, C. H.; Yang, Y. Q.; Li, W. Synthesis, crystal structure of a binuclear terbium complex with 2, 4, 6-trimethylbenzoic acid and 1, 10-phenanthroline. Chin. J. Inorg. Chem. 2006, 22, 2097–2100.
14. [14]
  Bala, M.; Kumar, S.; Devi, R.; Taxak, V. B.; Boora, P.; Khatkar, S. P. Synthesis, NMR, photoluminescence studies and intramolecular energy transfer process of europium(Ⅲ) complexes. J. Fluorine Chem. 2015, 178, 6–13. doi: 10.1016/j.jfluchem.2015.06.011
15. [15]
  Tian, L.; Chen, L.; Xia, W. Q.; Shen, S. H.; Zhang, X. Synthesis and crystal structure of a novel quaternary binuclear europium complex. Chem. Res. 2007, 18, 9–11.
16. [16]
  Fu, F.; Chen, S. P.; Ren, Y. X.; Gao, S. L. Single crystal structures and fluorescence property of a series of lanthanide coordination polymers incorporating isophthalate. Acta Chim. Sinica 2008, 66, 1663–1668.
17. [17]
  Shen, C. Q.; Yan, T. L.; Wang, Y. T.; Ye, Z. J.; Xu, C. J.; Zhou, W. J. Synthesis, structure and luminescence properties of binary and ternary complexes of lanthanide (Eu³⁺, Sm³⁺ and Tb³⁺) with salicylic acid and 1, 10-phenanthroline. J. Lumin. 2017, 184, 48–54. doi: 10.1016/j.jlumin.2016.12.018
18. [18]
  Li, Y. Q.; Ju, Y. L.; Zhang, Y. B.; Wang, C. Y.; Zhang, T. T.; Li, X. Synthesis, crystal structure and characterization of two terbium complexes with bromobenzoic acid. Chin. J. Inorg. Chem. 2007, 23, 969–974.
19. [19]
  Shen, P. P.; Ren, N.; Zhang, J. J.; Geng, L. N.; Wang, S. P.; Shi, S. K. Crystal structures, luminescent and thermal properties of lanthanide complexes with 3, 4-dimethylbenzoic acid and 2, 2'-bipyridine. J. Therm. Anal. Calorim. 2018, 131, 1699–1707. doi: 10.1007/s10973-017-6643-3
20. [20]
  Yang, Y. Q.; Li, W.; Yang, P. F.; Kuang, Y. F. Synthesis, structure and properties of a new terbium(Ⅲ) complex Tb₂(C₁₅H₁₁O₃)₆(phen)₂. Chin. J. Struct. Chem. 2020, 39, 1087–1092.
21. [21]
  Yang, Y. Q.; Tuo, L. Y.; Li, W. Synthesis, structure and properties of a new terbium(Ⅲ) complex Tb₂(C₁₅H₁₁O₃)₆(2, 2'-bipy)₂. Chin. J. Struct. Chem. 2020, 39, 1331–1336.
22. [22]
  Yang, Y. Q.; Zhang, S. H.; Tan, H. B.; Fu, L. X. Crystal structure, and sagnetic and fluorescence properties of a new terbium(Ⅲ) complex, [Tb(L)₃(2, 2'-bipy)(DMF)]·(2, 2'-bipy). Z. Naturforsch. 2013, 68b, 1269–1272.
23. [23]
  Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Crystallogr. Sect. C 2015, 71, 3−8.
24. [24]
  Sun, H. M.; Liu, M. C.; Fu, X. F.; Xin, T. T.; Wang, Y. B.; Wang, S.; Wang, J.; Diao, Y. Y.; Yang, F. F.; Zhang, T. Solvothermal synthesis and conformation probe of novel europium complex of bronsted acidic ionic liquid: 1, 3-bis(1-carboxylatoethyl)imidazolium bromide. Z. Anorg. Allg. Chem. 2021, 647, 1–10. doi: 10.1002/zaac.202170011
25. [25]
  Binnemans, K. Interpretation of europium(Ⅲ) spectra. Coord. Chem. Rev. 2015, 295, 1–45. doi: 10.1016/j.ccr.2015.02.015
26. [26]
  Kong, F. R.; Huang, R.; Wang, D.; Li, J. Preparation and luminescent properties of europium(Ⅲ) complexes with silane-modified phthaloyl phloride and 1, 10-phenanthroline. Chin. Rare Earths 2019, 40, 1–7.
27. [27]
  Ramya, A. R.; Reddy, M. L. P.; Cowley, A. H.; Vasudevan, K. V. Synthesis, crystal structure, and photoluminescence of homodinuclear lanthanide 4-(dibenzylamino)benzoate compounds. Inorg. Chem. 2010, 49, 2407–2415. doi: 10.1021/ic902257u
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