Citation: Dan ZHAO, Ting-Ting GUO, Yan-Yan AN, Juan-Zhi YAN. A Novel 3D Cd^II-CP Based on a Bi-functional (N-/O-Sites) Triazole-modified Carboxyl Ligand: Structure, Topology and Photoluminescence[J]. Chinese Journal of Structural Chemistry, ;2022, 41(2): 220208. doi: 10.14102/j.cnki.0254-5861.2011-3341 shu

A Novel 3D Cd^II-CP Based on a Bi-functional (N-/O-Sites) Triazole-modified Carboxyl Ligand: Structure, Topology and Photoluminescence

Taiyuan University, Taiyuan 030032, China

Corresponding author: Juan-Zhi YAN, 631977511@qq.com
Received Date: 25 August 2021
Accepted Date: 4 November 2021

Fund Project: the NNSFC 21671124

Figures(6)

With triazole-modified derivative as link, one new framework [Cd₅(μ₅-HL^2-)₂(μ₄-L^3-)₂(H₂O)₁₀]·2H₂O (1, H₃L = 2-(1, 2, 4-triazol-1-yl)benzene-1, 3, 5-tricarboxylic acid) has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, powder X-ray diffraction and elemental analysis. Complex 1 exhibits a 3D (3, 4, 6)-connected net cross-linked by binuclear [Cd₂(COO)₅]^- cluster and mononuclear Cd(II) geometry via HL^2-/L^3- ligands. It crystallizes in triclinic system, space group P\begin{document}$ \overline 1 $\end{document} with a = 7.7411(11), b = 9.8813(15), c = 20.177(3) Å, α = 85.547(4)°, β = 80.603(4)°, γ = 67.976(3)°, V = 1411.3(4) Å³, Z = 1, M_r = 1876.89 g/mol, D_c = 2.208 mg/m³, μ = 1.97 mm^-1, F(000) = 918, GOOF = 1.03, the final R = 0.0869 and wR = 0.1950 for 3127 observed reflections with I > 2σ(I). The solid photoluminescent behaviour of 1 has been further functionally investigated.
- triazole,
- Cd(II) complex,
- crystal structure,
- fluorescence property
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A Novel 3D CdII-CP Based on a Bi-functional (N-/O-Sites) Triazole-modified Carboxyl Ligand: Structure, Topology and Photoluminescence

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通讯作者: 陈斌, bchen63@163.com

A Novel 3D Cd^II-CP Based on a Bi-functional (N-/O-Sites) Triazole-modified Carboxyl Ligand: Structure, Topology and Photoluminescence