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Citation: Jian-Chao SHI, Hao WANG, Rui-Juan ZHANG, Dan ZHAO. A New Borate-phosphate Compound CsNa2Lu2(BO3)(PO4)2: Crystal Structure and Tb3+ Doped Luminescence[J]. Chinese Journal of Structural Chemistry, ;2022, 41(2): 220214. doi: 10.14102/j.cnki.0254-5861.2011-3284 shu

A New Borate-phosphate Compound CsNa2Lu2(BO3)(PO4)2: Crystal Structure and Tb3+ Doped Luminescence

  • a.

    College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000, China

  • b.

    School of Physics and Electronic Information Engineering, Henan Polytechnic University, Jiaozuo 454000, China

  • Corresponding author: Hao WANG, wanghao@hpu.edu.cn Dan ZHAO, iamzd1996@163.com
  • Received Date: 10 June 2021
    Accepted Date: 14 August 2021

    Fund Project: the National Natural Science Foundation of China 21201056

Figures(6)

  • Composite borate-phosphate compounds have always attracted much attention for their structure diversity and interesting properties. In this work, a new borate-phosphate CsNa2Lu2(BO3)(PO4)2 (CNLBP) was found for the first time and its structure was characterized by single-crystal X-ray diffraction method. It crystallizes in orthorhombic system, space group Cmcm with a = 6.8750(5), b = 14.6919(1), c = 10.5581(7) Å, V = 1066.44(1) Å3, Z = 4, Mr = 777.58, Dc = 4.843 g/cm3, F(000) = 1368, μ(MoKα) = 22.20 mm-1, R(F2 > 2σ(F2)) = 0.0173 and wR(F2) = 0.0367. The structure of CNLBP features a chain framework of [Lu2(BO3)(PO4)2]∞ that delimits 1D tunnels filled by Na+ and Cs+ ions. Phosphors CNLBP: xTb (x = 0, 0.1, 0.2, 0.4, 0.6, 0.8, 1.0) were prepared, and it can emit bright green light under near-UV excitation due to the 5D4→7Fj (j = 6, 5, 4, 3) transition of Tb3+. Due to the large separation of Lu3+ ions in CNLBP structure lattice, the optimal concentration of Tb3+ is 80%, and concentration quenching occurs only for the full Tb3+ concentration.
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