Citation: Ying-Hao MI, Ming-Xue YANG, Xiao-Fei KUANG, Can-Zhong LU. A Terbium(III)-organic Coordination Polymer: Synthesis, Characterization and Its Luminescence[J]. Chinese Journal of Structural Chemistry, ;2022, 41(2): 220207. doi: 10.14102/j.cnki.0254-5861.2011-3277 shu

A Terbium(III)-organic Coordination Polymer: Synthesis, Characterization and Its Luminescence

Ying-Hao MI ^{a, b} ,
Ming-Xue YANG ^a ,
Xiao-Fei KUANG ^a,, ,
Can-Zhong LU ^{a, c,,}

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Xiao-Fei KUANG, xfkuang@fjirsm.ac.cn Can-Zhong LU, czlu@fjirsm.ac
Received Date: 4 June 2021
Accepted Date: 22 July 2021

Fund Project: the Strategic Priority Research Program of the Chinese Academy of Sciences XDB20000000the Key Research Program of Frontier Science, CAS QYZDJ-SSW-SLH033the National Natural Science Foundation of China 52073286the National Natural Science Foundation of China 21875252the National Natural Science Foundation of China 21701177the Natural Science Foundation of Fujian Province 2006L2005

Figures(4)

A new 3D terbium(III) metal-organic network [Tb(HIMDC)(HCOO)(H₂O)]_n (complex 1) has been synthesized by Tb³⁺ ions coordinated with 4, 5-imidazole dicarboxylic acid (H₃IMDC) and formic acid under solvothermal conditions with the mixed solvents of N, N-dimethylformamide (DMF) and H₂O. The unambiguous structural determination has been confirmed by single-crystal X-ray diffraction combined with elemental analysis, infrared (IR) spectrum, thermogravimetric analysis (TGA) and powder X-ray diffraction (PXRD). Complex 1 crystallizes in orthorhombic Fdd2 space group with a = 22.295(2), b = 24.097(3), c = 6.7256(6) Å, V = 3613.3 Å³, Z = 16, D_c = 2.765 g/cm³, F(000) = 2816, μ = 7.855 mm^-1, the final R = 0.0173 (I ≥ 2σ(I)), wR = 0.0416 (all data) and GOOF = 1.068. In complex 1, the Tb³⁺ ions are connected by HIMDC^2- anions into 2D metal-organic layers which are further extended into a three-dimensional (3D) architecture through formic acid functional motif. In addition, complex 1 shows intense and characteristic green luminescence.
- coordination polymer,
- crystal structure,
- photoluminescence
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