Citation: Jie-Fen HUANG, Yi-Hao CHEN, Zhen-Hua LIANG, Sheng-Run ZHENG, Jun CAO. Structure and Properties of a Cd(II) Metal-organic Framework Based on a Newly Designed Heterotopic Tripodal N-Donor Ligand[J]. Chinese Journal of Structural Chemistry, ;2022, 41(2): 220207. doi: 10.14102/j.cnki.0254-5861.2011-3274 shu

Structure and Properties of a Cd(II) Metal-organic Framework Based on a Newly Designed Heterotopic Tripodal N-Donor Ligand

a.
School of Chemistry, South China Normal University, Guangzhou 510006, China
b.
School of Materials Science and Hydrogen Energy & Guangdong Key Laboratory for Hydrogen Energy Technologies, Foshan University, Foshan, Guangdong 528000, China

Corresponding author: Sheng-Run ZHENG, zhengsr@scnu.edu.cn Jun CAO, caojunbnu@mail.bnu.edu.cn
Received Date: 17 June 2021
Accepted Date: 2 September 2021

Fund Project: the Natural Science Foundation of China 22073032

Figures(7)

In this paper, a Cd(II) metal-organic framework (MOF), Cd-DIBT (HDIBT = 5-(3΄, 5΄-di(1H-imidazol-1-yl)-[1, 1΄-biphenyl]-4-yl)-1H-tetrazole), has been constructed based on a newly designed heterotopic tripodal ligand containing both imidazolyl and pyrazolyl groups. The Cd-DIBT exhibits a new three-dimensional (3, 3, 9)-connected trinodal network topology with point symbol of (4²·6)(4³)₂(4⁸·6¹⁵·8¹²·10) (namely scnu) based on binuclear secondary building blocks (SBUs). Staggered 1D channels were observed in such framework and was estimated to have 5487 Å³ potential solvent area (56%). The stability study reveals that the framework is unstable and easily transforms into amorphous MOF after the removal of guest molecules. In addition, the Cd-DIBT shows a ligand-centered luminescence.
- heterotopic tripodal ligand,
- metal-organic framework,
- topology,
- crystal structure
1. [1]
  Karmakar, A.; Prabakaran, V.; Zhao, D.; Chua, K. J. A review of metal-organic frameworks (MOFs) as energy-efficient desiccants for adsorption driven heat-transformation applications. Appl. Energy 2020, 269, 115070. doi: 10.1016/j.apenergy.2020.115070
2. [2]
  Li, Y.; Zou, B.; Xiao, A.; Zhang, H. Advances of metal-organic frameworks in energy and environmental applications. Chin. J. Chem. 2017, 35, 1501–1511. doi: 10.1002/cjoc.201700151
3. [3]
  Cao, X.; Tan, C.; Sindoro, M.; Zhang, H. Hybrid micro-/nano-structures derived from metal-organic frameworks: preparation and applications in energy storage and conversion. Chem. Soc. Rev. 2017, 46, 2660–2677. doi: 10.1039/C6CS00426A
4. [4]
  Gimenez-Marques, M.; Hidalgo, T.; Serre, C.; Horcajada, P. Nanostructured metal-organic frameworks and their bio-related applications. Coord. Chem. Rev. 2016, 307, 342–360. doi: 10.1016/j.ccr.2015.08.008
5. [5]
  Wang, D.; Jana, D.; Zhao, Y. Metal-organic framework derived nanozymes in biomedicine. Accounts Chem. Res. 2020, 53, 1389–1400. doi: 10.1021/acs.accounts.0c00268
6. [6]
  Ma, X.; Chai, Y.; Li, P.; Wang, B. Metal-organic framework films and their potential applications in environmental pollution control. Accounts Chem. Res. 2019, 52, 1461–1470. doi: 10.1021/acs.accounts.9b00113
7. [7]
  Zhang, J. P.; Zhang, Y. B.; Lin, J. B.; Chen, X. M. Metal azolate frameworks: from crystal engineering to functional materials. Chem. Rev. 2012, 112, 1001–1033. doi: 10.1021/cr200139g
8. [8]
  Yoshioka, S.; Inokuma, Y.; Duplan, V.; Dubey, R.; Fujita, M. X-ray structure analysis of ozonides by the crystalline sponge method. J. Am. Chem. Soc. 2016, 138, 10140. doi: 10.1021/jacs.6b05817
9. [9]
  Kumar, S.; Liu, S.; Mohan, B.; Zhang, M.; Tao, Z.; Wan, Z.; You, H.; Sun, F.; Li, M.; Ren, P. Fluorine-containing triazole-decorated silver(I)-based cationic metal-organic framework for separating organic dyes and removing oxoanions from water. Inorg. Chem. 2021, 60, 7070–7081. doi: 10.1021/acs.inorgchem.0c03688
10. [10]
  Yang, X.; Yan, C.; Li, Z.; Li, X.; Yu, Q.; Sang, T.; Gai, Y.; Zhang, Q.; Xiong, K. Viologen-based cationic metal-organic framework for efficient Cr₂O₇^2- adsorption and dye separation. Inorg. Chem. 2021, 60, 5988–5995. doi: 10.1021/acs.inorgchem.1c00404
11. [11]
  Desai, A. V.; Manna, B.; Karmakar, A.; Sahu, A.; Ghosh, S. K. A water-stable cationic metal-organic framework as a dual adsorbent of oxoanion pollutants. Angew. Chem. Int. Ed. 2016, 55, 7811–7815. doi: 10.1002/anie.201600185
12. [12]
  Feng, Y.; Cai, S. L.; Gao, Y.; Zheng, S. R. Construction of coordination polymers based on a rigid tripodal nitrogen-containing heterotopic ligand that designed by mixed-donors strategy. J. Solid State Chem. 2018, 265, 64–71. doi: 10.1016/j.jssc.2018.05.031
13. [13]
  Deng, S. Q.; Mo, X. J.; Zheng, S. R.; Jin, X.; Gao, Y.; Cai, S. L.; Fan, J.; Zhang, W. G. Hydrolytically stable nanotubular cationic metal-organic framework for rapid and efficient removal of toxic oxo-anions and dyes from water. Inorg. Chem. 2019, 58, 2899–2909. doi: 10.1021/acs.inorgchem.9b00104
14. [14]
  Deng, S. Q.; Miao, Y. L.; Tan, Y. L.; Fang, H. N.; Li, Y. T.; Mo, X. J.; Cai, S. L.; Fan, J.; Zhang, W. G.; Zheng, S. R. An anionic nanotubular metal-organic framework for high-capacity dye adsorption and dye degradation in darkness. Inorg. Chem. 2019, 58, 13979–13987. doi: 10.1021/acs.inorgchem.9b01959
15. [15]
  Wang, G. Q.; Huang, J. F.; Huang, X. F.; Deng, S. Q.; Zheng, S. R.; Cai, S. L.; Fan, J.; Zhang, W. G. A hydrolytically stable cage-based metal-organic framework containing two types of building blocks for the adsorption of iodine and dyes. Inorg. Chem. Front. 2021, 8, 1083–1092. doi: 10.1039/D0QI01257B
16. [16]
  Jin, G. X.; Wang, J.; Liu, J. Y.; Ma, J. P.; Dong, Y. B. Visual recognition and removal of C₂H₂ from C₂H₄/C₂H₂ mixtures by a CuI-MOF. Inorg. Chem. 2018, 57, 6218–6221. doi: 10.1021/acs.inorgchem.8b00971
17. [17]
  CrysAlis RED, Oxford Diffraction Ltd., Version 1.171. 29.2.
18. [18]
  Sheldrick, G. M. SHELXT-integrated space-group and crystal structure determination. Acta Crystallogr., Sect. A: Found. Adv. 2015, 71, 3−8.
19. [19]
  Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Crystallogr., Sect. C: Struct. Chem. 2015, 71, 3−8. doi: 10.1107/S2053229614024218
20. [20]
  Spek, A. L. Single-crystal structure validation with the program PLATON. J. Appl. Cryst. 2003, 36, 7–13. doi: 10.1107/S0021889802022112
21. [21]
  Blatov, V. A.; Shevchenko, A. P. TOPOS 4.0 Samara State University, Russia 1999.
22. [22]
  Fonseca, J.; Gong, T.; Jiao, L.; Jiang, H. L. Metal-organic frameworks (MOFs) beyond crystallinity: amorphous MOFs, MOF liquids and MOF glasses. J Mater. Chem. A 2021, 9, 10562–10611. doi: 10.1039/D1TA01043C
23. [23]
  Feng, L.; Wang, K. Y.; Day, G. S.; Ryder, M. R.; Zhou, H. C. Destruction of metal-organic frameworks: positive and negative aspects of stability and lability. Chem. Rev. 2020, 120, 13087–13133. doi: 10.1021/acs.chemrev.0c00722
24. [24]
  Ma, Q.; Jin, H.; Li, Y. Tuning the adsorption selectivity of ZIF-8 by amorphization. Chem. Eur. J. 2020, 26, 13137–13141. doi: 10.1002/chem.202001249
25. [25]
  Bennett, T. D.; Cheetham, A. K. Amorphous metal-organic frameworks. Accounts Chem. Res. 2014, 47, 1555–1562. doi: 10.1021/ar5000314
26. [26]
  Huang, T. H.; Zhu, S. L.; Xiong, X. L.; Li, J. D.; Yang, H.; Huang, X.; Huang, X. R.; Zhang, K. Synthesis, structural characterization and photoluminescent properties of 2D multilayer Cu⁺ coordination polymers via C–H⋯π and π⋯π interactions. J. Mol. Struct. 2017, 1143, 431–437. doi: 10.1016/j.molstruc.2017.04.035
27. [27]
  Shi, Z.; Pan, Z.; Jia, H.; Chen, S.; Qin, L.; Zheng, H. Zn(II)/Cd(II) terephthalate coordination polymers incorporating bi-, tri-, and tetratopic phenylamine derivatives: crystal structures and photoluminescent properties. Cryst. Growth Des. 2016, 16, 2747–2755. doi: 10.1021/acs.cgd.6b00056
28. [28]
  Li, Z. H.; He, L.; Guo, Y. J.; Luo, M. B.; Lin, Q. P. A stable luminescent MOF constructed by bis-(4-pyridyl)thiazolo[5, 4-d]thiazole containing multi-electron donor-acceptor core. Chin. J. Struct. Chem. 2021, 40, 610–614.
29. [29]
  Cai, H.; Li, N.; Li, Y.; An, D. M. Solvothermal synthesis and characterization of two Cd(II) coordination polymers with isomeric multi-carboxylate ligands. Chin. J. Struct. Chem. 2021, 40, 637–645.
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